全文获取类型
收费全文 | 2220篇 |
免费 | 99篇 |
国内免费 | 742篇 |
专业分类
安全科学 | 172篇 |
废物处理 | 136篇 |
环保管理 | 160篇 |
综合类 | 1220篇 |
基础理论 | 389篇 |
污染及防治 | 686篇 |
评价与监测 | 79篇 |
社会与环境 | 59篇 |
灾害及防治 | 160篇 |
出版年
2024年 | 1篇 |
2023年 | 42篇 |
2022年 | 118篇 |
2021年 | 102篇 |
2020年 | 59篇 |
2019年 | 71篇 |
2018年 | 79篇 |
2017年 | 104篇 |
2016年 | 112篇 |
2015年 | 141篇 |
2014年 | 159篇 |
2013年 | 226篇 |
2012年 | 179篇 |
2011年 | 188篇 |
2010年 | 151篇 |
2009年 | 121篇 |
2008年 | 145篇 |
2007年 | 120篇 |
2006年 | 105篇 |
2005年 | 77篇 |
2004年 | 65篇 |
2003年 | 74篇 |
2002年 | 61篇 |
2001年 | 59篇 |
2000年 | 59篇 |
1999年 | 79篇 |
1998年 | 61篇 |
1997年 | 56篇 |
1996年 | 49篇 |
1995年 | 49篇 |
1994年 | 27篇 |
1993年 | 38篇 |
1992年 | 31篇 |
1991年 | 24篇 |
1990年 | 14篇 |
1989年 | 3篇 |
1988年 | 5篇 |
1987年 | 1篇 |
1984年 | 3篇 |
1981年 | 2篇 |
1958年 | 1篇 |
排序方式: 共有3061条查询结果,搜索用时 46 毫秒
211.
添加天然沸石和石灰对土壤镉形态转化的影响 总被引:12,自引:0,他引:12
采用土壤培养实验,研究镉污染土壤中添加沸石、石灰及两者配施对土壤pH值和土壤镉形态变化的影响。结果表明,土壤pH值随沸石用量的增加而增加,随培养时间呈现先增加后下降并逐渐趋于稳定的趋势,但均高于对照。高剂量石灰的处理对土壤pH的影响最大,与对照相比土壤pH提高了3.33个单位。在土壤5~50 d培养过程中,石灰处理的土壤交换态镉含量呈现先逐渐降低而后略有升高的趋势,其余处理均呈下降趋势。培养50 d后,高剂量的沸石、石灰及高剂量沸石与石灰配施处理的土壤交换态镉含量从5 d时的67.54、61.95和55.56 mg/kg降低至54.65、49.93和45.96mg/kg。相关分析表明,不同培养时期交换态镉含量与土壤pH值呈负相关关系。在10个处理中,L2Z3(石灰2 g/kg土和沸石60 g/kg土)组合处理效果最好,使土壤交换态镉含量下降了34.68%,碳酸盐结合态镉含量上升了4.30%,铁锰氧化结合态镉含量上升了16.97%,有机结合态镉含量上升了1.31%,残渣态镉含量上升了12.11%。 相似文献
212.
213.
Li R. Gao Dan. Xia Hai Z. Tian Hai J. Zhang Li D. Liu Yi W. Wang 《Journal of environmental science and health. Part. B》2013,48(5):322-330
Organochlorine pesticides (OCPs) were analyzed in 26 surface sediment samples from the Liaohe River basin, and the distributions of and potential environmental risks posed by OCPs in the basin were evaluated. Eighteen OCPs listed in the Stockholm Convention were determined using isotope-dilution gas chromatography–high resolution mass spectrometry. This is the first study of hexachlorobenzene (HCB) in the Liaohe River basin sediments. The total OCP concentrations were 0.39–68.06 ng g?1 dry weight. The total α-, β-, γ-, and δ-hexachlorocyclohexane (HCH), the total dichlorodiphenyltrichloroethane (DDT – p,p′-dichlorodiphenyldichloroethane (DDD), p,p′-dichlorodiphenyldichloroethylene (DDE), o,p'-DDT, and p,p′-DDT), and the HCB concentrations in the sediment samples were 0.1–28.48 ng g?1 (mean 4.01 ng g?1), 0.08–6.52 ng g?1 (mean 3.07 ng g?1), and 0.18–24.8 ng g?1 (mean 4.38 ng g?1), respectively. The HCB concentrations were higher than the concentrations of the other OCPs, and the HCHs and HCB together were the dominant OCPs. β-HCH was the most abundant HCH isomer. The concentrations of DDTs and other OCPs were relatively low, and the (DDE+DDD)/DDT ratios (>0.5) and DDD/DDE ratios (<1) indicated that no recent DDT inputs had occurred in the Liaohe River system. The main sources of HCHs were probably the historical production and agricultural use of HCH in the study area. The DDT and HCH concentrations were generally below or similar to the concentrations that have been found in other parts of the world. An ecotoxicological evaluation indicated that HCHs in surface sediments pose slight risks to human and ecological health in the Liaohe River basin. 相似文献
214.
Bin Xu Tingyao Gao Chenyan Hu Jiekuan Shi 《Journal of the Air & Waste Management Association (1995)》2013,63(6):714-718
Abstract This paper introduces a new allocation method on discharge loading of each function zone in a total emission control region. The wind frequency, the position of each district, and the pollutant’s influence area were taken into account in this new method. The concept of “average downwind distance” was brought forward in this paper. The method here is more reasonable than the original method of area distribution, which was proposed by the “A-value” method in regulation of total emissions in China, by means of the simulation of annual average concentration in the total emission control region. 相似文献
215.
Ning Gao Amy E. Gildemeister Kira Krumhansl Katherine Lafferty Philip K. Hopke Eugene Kim 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1607-1620
Abstract This study is a part of an ongoing investigation of the types and locations of emission sources that contribute fine particulate air contaminants to Underhill, VT. The air quality monitoring data used for this study are from the Interagency Monitoring of Protected Visual Environments network for the period of 2001–2003 for the Underhill site. The main source-receptor modeling techniques used are the positive matrix factorization (PMF) and potential source contribution function (PSCF). This new study is intended as a comparison to a previous study of the 1988–1995 Underhill data that successfully revealed a total of 11 types of emission sources with significant contributions to this rural site. This new study has identified a total of nine sources: nitrate-rich secondary aerosol, wood smoke, East Coast oil combustion, automobile emission, metal working, soil/dust, sulfur-rich aerosol type I, sulfur-rich aerosol type II, and sea salt/road salt. Furthermore, the mass contributions from the PMF identified sources that correspond with sampling days with either good or poor visibility were analyzed to seek possible correlations. It has been shown that sulfur-rich aerosol type I, nitrate aerosol, and automobile emission are the most important contributors to visibility degradation. Soil/dust and sea salt/road salt also have an added effect. 相似文献
216.
Vegetation type and density exhibited a considerable patchy distribution at very local scales in the Yellow River Delta, due to the spatial variation of soil salinity and water scarcity. We proposed that soil respiration is affected by the spatial variations in vegetation type and soil chemical properties and tested this hypothesis in three different vegetation patches (Phragmites australis, Suaeda heteroptera and bare soil) in winter (from November 2010 to April 2011). At diurnal scale, soil respiration all displayed single-peak curves and asymmetric patterns in the three vegetation patches; At seasonal scale, soil respiration all declined steadily until February, and then increased to a peak in next April. But, the magnitude of soil respiration showed significant differences among the three sites. Mean soil respiration rates in winter were 0.60, 0.45 and 0.17 μmol CO(2) m(-2) s(-1) for the Phragmites australis, Suaeda heteroptera and bare soil, respectively. The combined effect of soil temperature and soil moisture accounted for 58-68 % of the seasonal variation of winter soil respiration. The mean soil respiration revealed positive and linear correlations with total N, total N and SOC storages at 0-20 cm depth, and plant biomass among the three sites. We conclude that the patchy distribution of plant biomass and soil chemical properties (total C, total N and SOC) may affect decomposition rate of soil organic matter in winter, thereby leading to spatial variations in soil respiration. 相似文献
217.
Jin Hua Li Shu Mei Jiao Rong Qing Gao Richard D. Bardgett 《Environmental management》2012,50(6):1193-1203
Plant–soil interactions are known to influence a wide range of ecosystem-level functions. Moreover, the recovery of these functions is of importance for the successful restoration of soils that have been degraded through intensive and/or inappropriate land use. Here, we assessed the effect of planting treatments commonly used to accelerate rates of grassland restoration, namely introduction of different legume species Medicago sativa, Astragalus adsurgens, Melilotus suaveolens, on the recovery of soil microbial communities and carbon and nitrogen contents in abandoned fields of the Loess Plateau, China. The results showed effects were species-specific, and either positive, neutral or negative depending on the measure and time-scale. All legumes increased basal respiration and metabolic quotient and had a positive effect on activity and functional diversity of the soil microbial community, measured using Biolog EcoPlate. However, soil under Astragalus adsurgens had the highest activity and functional diversity relative to the other treatments. Soil carbon and nitrogen content and microbial biomass were effectively restored in 3–5?years by introducing Medicago sativa and Astragalus adsurgens into early abandoned fields. Soil carbon and nitrogen content were retarded in 3–5?years and microbial biomass was retarded in the fifth year by introducing Melilotus suaveolens. Overall, the restoration practices of planting legumes can significantly affect soil carbon and nitrogen contents, and the biomass, activity, and functional diversity of soil microbial community. Therefore, we propose certain legume species could be used to accelerate ecological restoration of degraded soils, hence assist in the protection and preservation of the environment. 相似文献
218.
219.
采用室内模拟实验方法,研究环境因子(温度、pH、扰动强度、供气量)对底泥释放COD的影响。结果表明,水温升高能加速底泥中有机质的释放;上覆水在弱酸至中性条件下底泥释放有机质最低;扰动上覆水体会加快有机质的释放。 相似文献
220.
Gao J Powers K Wang Y Zhou H Roberts SM Moudgil BM Koopman B Barber DS 《Chemosphere》2012,89(1):96-101
Adsorption of natural organic matter (NOM) on nanoparticles can have dramatic impacts on particle dispersion resulting in altered fate and transport as well as bioavailability and toxicity. In this study, the adsorption of Suwannee River humic acid (SRHA) on silver nanoparticles (nano-Ag) was determined and showed a Langmuir adsorption at pH 7 with an adsorption maximum of 28.6 mg g−1 nano-Ag. It was also revealed that addition of <10 mg L−1 total organic carbon (TOC) increased the total Ag content suspended in the aquatic system, likely due to increased dispersion. Total silver content decreased with concentrations of NOM greater than 10 mg TOC L−1 indicating an increase in nanoparticle agglomeration and settling above this concentration. However, SRHA did not have any significant effect on the equilibrium concentration of ionic Ag dissolved in solution. Exposure of Daphnia to nano-Ag particles (50 μg L−1 and pH 7) produced a linear decrease in toxicity with increasing NOM. These results clearly indicate the importance of water chemistry on the fate and toxicity of nanoparticulates. 相似文献