Study on the Thermo-Mechanical and Biodegradable Properties of Shellac Films Grafted with Acrylic Monomers by Gamma Radiation

Shellac (SL) films were prepared by casting and were grafted with various acrylic monomers of different functionalities using gamma radiation. Different formulations of shellac with varying concentrations (3, 5 and 7%) of these acrylic monomers such as 2-hydroxyethyl methacrylate (HEMA), 2-ethylhexyl acrylate (EHA) and 1,4-butanediol diacrylate (BDDA) in methanol were prepared. The pure shellac and other treated films were then irradiated under gamma radiation (Co-60) at different doses (0.5–5 kGy) at a dose rate of 3.5 kGy/h where 1 Gy = 1 J/kg = 100 rads. The mechanical properties like tensile strength (TS) and elongation at break (Eb) of the prepared films were studied. The mechanical properties of the irradiated shellac films demonstrated superior values. Among the formulations, shellac grafted with BDDA (SL-g-BDDA) showed the highest TS and Eb values which were 543 and 168% higher than those of raw shellac films, respectively. The water uptake behavior of raw and treated films was also studied. The raw film showed 11% water uptake but HEMA containing film showed 67%. In the soil burial test, HEMA containing shellac film was rapidly degraded than other raw, EHA and BDDA grafted films. Thermal properties indicated that grafting of acrylic monomers decreased the melting temperature of the pure shellac films.     

Fusing probability density function into Dempster–Shafer theory of evidence for the evaluation of water treatment plant

The evaluation of the status of a municipal drinking water treatment plant (WTP) is important. The evaluation depends on several factors, including, human health risks from disinfection by-products (R), disinfection performance (D), and cost (C) of water production and distribution. The Dempster–Shafer theory (DST) of evidence can combine the individual status with respect to R, D, and C to generate a new indicator, from which the overall status of a WTP can be evaluated. In the DST, the ranges of different factors affecting the overall status are divided into several segments. The basic probability assignments (BPA) for each segment of these factors are provided by multiple experts, which are then combined to obtain the overall status. In assigning the BPA, the experts use their individual judgments, which can impart subjective biases in the overall evaluation. In this research, an approach has been introduced to avoid the assignment of subjective BPA. The factors contributing to the overall status were characterized using the probability density functions (PDF). The cumulative probabilities for different segments of these factors were determined from the cumulative density function, which were then assigned as the BPA for these factors. A case study is presented to demonstrate the application of PDF in DST to evaluate a WTP, leading to the selection of the required level of upgradation for the WTP.     

A Multilevel Approach to Manual Lifting in Manufacturing Industries

Musculoskeletal injuries are often the consequences of wrong postural configurations used during Manual Materials Handling (MMH). This eventually leads to a large payout of worker’s compensation and loss of production time. A simulated study of back injury risks has been carried out on seven selected manufacturing industries to identify and evaluate harmful working postures. For each MMH task, Ovako Working Posture Analyzing System (OWAS) codes have been identified with the help of motion study pictures. Also, Chaffin's biomechanical model was used to calculate L5/S1 load compression values on the spine during MMH activities. The multilevel approach adopted was a combination of OWAS and Chaffin’s biomechanical model. The application of a digitizer enabled us to identify the coordinates and it made a subsequent evaluation of the angles of each body link possible.     

Thermally induced formation of PCDD and PCDF from tri- and tetrachlorobenzene in dielectric fluids

The thermal behavior of dilute (5000-50 ppm) solutions of tri- and tetrachlorobenzene in mineral oil, silicone oil, and tetrachloroethylene (TCE) has been investigated. Although pyrolyses or combustion of neat chlorobenzenes readily forms significant yields of PCDDs/PCDFs, corresponding treatment of dilute solutions was generally non-productive. This result is consistent with the proposition that, under the conditions studied, the rate-limiting step for PCDD/PCDF formation is bimolecular in chlorobenzene. In contrast, earlier studies of PCBs implied a rate-limiting step that was unimolecular in chloroaromatics. Combustion of dilute solutions of chlorobenzenes in tetrachloroethylene did produce detectable concentrations of PCDF; this result reflects combination of chlorobenzene and TCE- or TCE-derived species.     

Impact of climatic conditions on irrigation water requirements and hydraulic characteristics of modern irrigation systems

Irrigation system performance regards as a function of climatic conditions. The present study was carried out to study this phenomenon. Sugar beet and sesame corps were cultivated during two agricultural seasons of 2017/2018 and 2018/2019 irrigated with drip and sprinkler systems. The drip and sprinkler systems performance was evaluated in terms of hydraulic characteristics added to irrigation water requirements. The recorded monthly values were compared to the traditional estimation method. The results revealed that irrigation system efficiency was increased by increasing ambient temperature for the drip irrigation system, and vice versa was noticed with the sprinkler irrigation system. Emission uniformity and application efficiency of emitters were increased by increasing ambient temperature. While the sprinkler flow rate and distribution uniformity were decreased by increasing ambient temperature. For drip irrigation system, the average total amount of irrigation water requirements using traditional estimation for sugar beet (2372 m³/fed) was less than the actual calculated (2439 m³/fed), while for sesame crop, the traditional estimation method (2556 m³/fed) was higher than actual calculated (2477 m³/fed). Using a sprinkler system, the average total amount of irrigation water requirements by the traditional estimation (2689 and 2897 m³/fed) was less than the actual calculated (2709 and 3044 m³/fed) for sugar beet and sesame crops, respectively. So, it is important to consider the effects of climatic conditions through the agricultural season.

     

Evidence for contact sex recognition pheromone of the Asian longhorned beetle,<Emphasis Type="Italic"> Anoplophora glabripennis</Emphasis> (Coleoptera: Cerambycidae)

Field observations of the Asian longhorned beetle (Anoplophora glabripennis) mating behavior in China suggested that a female-produced contact pheromone was almost certainly involved in sex recognition. Gas chromatography–mass spectrometry (GC-MS) analysis of A. glabripennis adults' whole body cuticular extracts indicates that a series of long-chain hydrocarbons comprise the cuticular waxes of both sexes. Although for the most part the GC profiles are similar for the two sexes, five monounsaturated compounds were consistently more abundant in samples from females than in those from males. These compounds were identified as (Z)-9-tricosene, (Z)-9-pentacosene, (Z)-7-pentacosene, (Z)-9-heptacosene, and (Z)-7-heptacosene in the approximate ratio of 1:2:2:8:1, respectively. Antennal and palpi contact to a polypropylene micro-centrifuge tube coated with a synthetic mixture of the five compounds stimulated copulatory behavior in males.Electronic Supplementary Material  Supplementary material is available for this article if you access the article at . A link in the frame on the left on that page takes you directly to the supplementary material.     

The bangladesh cyclone of 1991: why so many people died

Living with natural disasters has become a way of life in Bangladesh. On the night of 29 April 1991 a severe cyclonic storm, accompanied by tidal surges up to 30 feet high, battered the coastal areas of Bangladesh for 3–4 hours. Thousands of people were killed and property worth billions of dollars was destroyed. After the cyclone, several studies, using epidemiological and anthropological methods, looked at the impact of the cyclone. It was estimated that over 67,000 people lost their lives. Women, children and the elderly were much more at risk and so were those from the socio-economically disadvantaged section of the population. Cyclone shelters were few in relation to need but proved very helpful in saving lives. At least 20 per cent more deaths would have occurred in the absence of these shelters. The article documents impressive improvements in Bangladesh's-ability to cope and makes recommendations for the future.