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201.
202.
Transport of ammonium perfluorooctanoate in environmental media near a fluoropolymer manufacturing facility 总被引:1,自引:0,他引:1
In order to understand better the pathways for transport of ammonium perfluorooctanoate (APFO) from a point source, a focused investigation of environmental media (water and soil) near a fluoropolymer manufacturing facility (Site) was undertaken. Methods were developed and validated at 2 microg kg(-1) [the limit of quantitation (LOQ)] in soil, and at 50 ng l(-1) in water. Environmental media were sampled from a public water supply well field located north of the Site, across a river. The data suggest that APFO air emissions from the Site are transported to the well field, deposited onto the soil, and then migrate downward with precipitation into the underlying aquifer. 相似文献
203.
Although alkanes are relatively less reactive to chemical oxidation compared to alkenes, the chemical oxidation of alkanes has not been adequately explored in the context of environmental remediation efforts. Laboratory-scale column experiments were therefore conducted with soil artificially contaminated by diesel fuel as a surrogate for alkanes of environmental relevance. Particular attention was paid to saturated hydrocarbons refractory to volatilization. Reaction conditions involve 1485mgkg(-1) of the initial concentration of diesel range organics (DRO) and a constant ozone concentration of 119+/-6mgl(-1) at the flow rate of 50mlmin(-1). The observed removal of DRO reached 94% over 14h of continuous ozone injection. Ozone oxidation demonstrated effective removal of non-volatile DRO in the range of C(12)-C(24). Each alkane compound displayed comparable degradation kinetics, suggesting virtually no selectivity of ozone reactions with alkanes in soil. A pseudo-first order kinetic model closely simulated the removal kinetics, yielding a reaction rate constant of 0.213 (+/-0.021)h(-1) and a half-life of 3.3 (+/-0.3)h under the experimental conditions used in this study. An estimate of ozone demand was 32mg of O(3) (mgDRO)(-1). 相似文献
204.
Addressing landscape-level threats to stream fishes such as habitat and hydrological alterations requires adequate watershed-level
species inventories. Where watershed-level ichthyofaunal surveys are prohibitively expensive, existing (historical) data sources
may provide an option for compiling species lists. However, it is critical that managers consider potential biases or limitations
of species lists compiled from existing data. Here we assess the suitability of species lists compiled from existing data
sources for making watershed-level fish management and conservation decisions. For nine Great Lakes watersheds, we developed
existing species lists by compiling all available federal and state agency and museum fish survey data. We then compared the
size and species composition of existing species lists to current species lists compiled from intensive field surveys, conducted
in 2002, of the same watersheds. Species lists compiled from commonly available existing data sources, such as state and federal
agency and museum data, missed many species detected during our 2002 field surveys. In most watersheds, more than 10 species
were missed (range 5–21) on existing lists. Sampling over multiple years and seasons increased the size of both current (field)
and existing species lists. Existing species lists compiled from surveys conducted over multiple years and seasons included
an average of 15 species not captured during the 2002 field surveys. However, such multiyear existing datasets are rare and
not available for many watersheds. In addition, species lists compiled from older existing surveys (e.g., before 1984) did
not accurately represent current species composition of the watersheds and our results indicate several apparent misidentifications
or errors on these lists. Lastly, while most game species were detected on existing lists, migratory species and recently
introduced species were commonly missed on these lists. We conclude with recommendations for using existing data for watershed-level
stream fish management and conservation decisions. 相似文献
205.
Chantigny MH Rochette P Angers DA Bittman S Buckley K Massé D Bélanger G Eriksen-Hamel N Gasser MO 《Journal of environmental quality》2010,39(5):1545-1553
Treatment of liquid swine manure (LSM) offers opportunities to improve manure nutrient management. However, N2O fluxes and cumulative emissions resulting from application of treated LSM are not well documented. Nitrous oxide emissions were monitored following band-incorporation of 100 kg N ha(-1) of either mineral fertilizer, raw LSM, or four pretreated LSMs (anaerobic digestion; anaerobic digestion + flocculation: filtration; decantation) at the four-leaf stage of corn (Zea mays L.). In a clay soil, a larger proportion of applied N was lost as N2O with the mineral fertilizer (average of 6.6%) than with LSMs (3.1-5.0%), whereas in a loam soil, the proportion of applied N lost as N2O was lower with the mineral fertilizer (average of 0.4%) than with LSMs (1.2-2.4%). Emissions were related to soil NO3 intensity in the clay soil, whereas they were related to water-extractable organic C in the loam soil. This suggests that N2O production was N limited in the clay soil and C limited in the loam soil, and would explain the interaction found between N sources and soil type. The large N2O emission coefficients measured in many treatments, and the contradicting responses among N sources depending on soil type, indicate that (i) the Intergovernmental Panel on Climate Change (IPCC) default value (1%) may seriously underestimate N2O emissions from fine-textured soils where fertilizer N and manure are band-incorporated, and (ii) site-specific factors, such as drainage conditions and soil properties (e.g., texture, organic matter content), have a differential influence on emissions depending on N source. 相似文献
206.
Lability of polycyclic aromatic hydrocarbons in the rhizosphere 总被引:2,自引:0,他引:2
Remediation of soils containing high concentrations of polycyclic aromatic hydrocarbons (PAHs) seldom results in complete removal of contaminants, but residual toxicity often is reduced. In this study, soil from a former manufactured gas plant site was treated for 12 months by phytoremediation and then tested for total PAHs, Tenax-TA extractable ("labile") PAHs, aqueous soluble PAHs (PAH(wp)) , and biotoxicity assessed by earthworms survival, nematode mortality, emergence of lettuce seedlings, and microbial respiration. Prior to phytoremediation, the soil had toxic impacts on all bioassays (except the nematodes), and 12 months of remediation decreased this response. Change in labile PAHs was a predictor for change in total PAH for 3- and 4-ring compounds but not for the 5- and 6-ring. Decreases in labile PAHs were correlated (r(2)>or=0.80) with toxicity in the bioassays except microbial respiration. PAH(wp) was correlated only with nematode toxicity prior to remediation but with none of the tests after remediation. Total PAHs were not correlated with any of the bioassay tests. Tenax-TA appears to have potential for predicting residual toxicity in remediated soils and is superior to total concentrations for that application. 相似文献
207.
Influence of a soil enzyme on iron-cyanide complex speciation and mineral adsorption 总被引:1,自引:0,他引:1
Cyanide is commonly found as ferrocyanide [Fe(II)(CN)(6)](-4) and in the more mobile form, ferricyanide [Fe(III)(CN)(6)](-3) in contaminated soils and sediments. Although soil minerals may influence ferrocyanide speciation, and thus mobility, the possible influence of soil enzymes has not been examined. In a series of experiments conducted under a range of soil-like conditions, laccase, a phenoloxidase enzyme derived from the fungi Trametes versicolor, was found to exert a large influence on iron-cyanide speciation and mobility. In the presence of laccase, up to 93% of ferrocyanide (36-362ppm) was oxidized to ferricyanide within 4h. No significant effect of pH (3.6 and 6.2) or initial ferrocyanide concentration on the extent or rate of oxidation was found and ferrocyanide oxidation did not occur in the absence of laccase. Relative to iron-cyanide-mineral systems without laccase, ferrocyanide adsorption to aluminum hydroxide and montmorillonite decreased in the presence of laccase and was similar to or somewhat greater than that of ferricyanide without laccase. Laccase-catalyzed conversion of ferrocyanide to ferricyanide was extensive though up to 33% of the enzyme was mineral-bound. These results demonstrate that soil enzymes can play a major role in ferrocyanide speciation and mobility. Biotic soil components must be considered as highly effective oxidation catalysts that may alter the mobility of metals and metal complexes in soil. Immobilized enzymes should also be considered for use in soil metal remediation efforts. 相似文献
208.
Katherine R. M. Mackey Tanya Rivlin Arthur R. Grossman Anton F. Post Adina Paytan 《Marine Biology》2009,156(8):1531-1546
The spring bloom in seasonally stratified seas is often characterized by a rapid increase in photosynthetic biomass. To clarify
how the combined effects of nutrient and light availability influence phytoplankton composition in the oligotrophic Gulf of
Aqaba, Red Sea, phytoplankton growth and acclimation responses to various nutrient and light regimes were recorded in three
independent bioassays and during a naturally-occurring bloom. We show that picoeukaryotes and Synechococcus maintained a “bloomer” growth strategy, which allowed them to grow quickly when nutrient and light limitation were reversed.
During the bloom picoeukaryotes and Synechococcus appeared to have higher P requirements relative to N, and were responsible for the majority of photosynthetic biomass accumulation.
Following stratification events, populations limited by light showed rapid photoacclimation (based on analysis of cellular
fluorescence levels and photosystem II photosynthetic efficiency) and community composition shifts without substantial changes
in photosynthetic biomass. The traditional interpretation of “bloom” dynamics (i.e., as an increase in photosynthetic biomass)
may therefore be confined to the upper euphotic zone where light is not limiting, while other acclimation processes are more
ecologically relevant at depth. Characterizing acclimation processes and growth strategies is important if we are to clarify
mechanisms that underlie productivity in oligotrophic regions, which account for approximately half of the global primary
production in the ocean. This information is also important for predicting how phytoplankton may respond to global warming-induced
oligotrophic ocean expansion. 相似文献
209.
Matt W. Hayward Alex Callen Benjamin L. Allen Guy Ballard Femke Broekhuis Cassandra Bugir Rohan H. Clarke John Clulow Simon Clulow Jennifer C. Daltry Harriet T. Davies-Mostert Peter J. S. Fleming Andrea S. Griffin Lachlan G. Howell Graham I. H. Kerley Kaya Klop-Toker Sarah Legge Tom Major Ninon Meyer Robert A. Montgomery Katherine Moseby Daniel M. Parker Stéphanie Périquet John Read Robert J. Scanlon Rebecca Seeto Craig Shuttleworth Michael J. Somers Cottrell T. Tamessar Katherine Tuft Rose Upton Marcia Valenzuela-Molina Adrian Wayne Ryan R. Witt Wolfgang Wüster 《Conservation biology》2019,33(4):760-768
Compassionate conservation focuses on 4 tenets: first, do no harm; individuals matter; inclusivity of individual animals; and peaceful coexistence between humans and animals. Recently, compassionate conservation has been promoted as an alternative to conventional conservation philosophy. We believe examples presented by compassionate conservationists are deliberately or arbitrarily chosen to focus on mammals; inherently not compassionate; and offer ineffective conservation solutions. Compassionate conservation arbitrarily focuses on charismatic species, notably large predators and megaherbivores. The philosophy is not compassionate when it leaves invasive predators in the environment to cause harm to vastly more individuals of native species or uses the fear of harm by apex predators to terrorize mesopredators. Hindering the control of exotic species (megafauna, predators) in situ will not improve the conservation condition of the majority of biodiversity. The positions taken by so-called compassionate conservationists on particular species and on conservation actions could be extended to hinder other forms of conservation, including translocations, conservation fencing, and fertility control. Animal welfare is incredibly important to conservation, but ironically compassionate conservation does not offer the best welfare outcomes to animals and is often ineffective in achieving conservation goals. Consequently, compassionate conservation may threaten public and governmental support for conservation because of the limited understanding of conservation problems by the general public. 相似文献
210.
Katherine Seto Grantly R. Galland Alice McDonald Angela Abolhassani Kamal Azmi Hussain Sinan Trent Timmiss Megan Bailey Quentin Hanich 《Ambio》2021,50(1):242
Resource allocation is a fundamental and challenging component of common pool resource governance, particularly transboundary fisheries. We highlight the growing importance of allocation in fisheries governance, comparing approaches of the five tuna Regional Fisheries Management Organizations (tRFMOs). We find all tRFMOs except one have defined resources for allocation and outlined principles to guide allocation based on equity, citizenship, and legitimacy. However, all fall short of applying these principles in assigning fish resources. Most tRFMOs rely on historical catch or effort, while equity principles rarely determine dedicated rights. Further, the current system of annual negotiations reduces certainty, trust, and transparency, counteracting many benefits asserted by rights-based management proponents. We suggest one means of gaining traction may be to shift conversations from allocative rights toward weighting of principles already identified by most tRFMOs. Incorporating principles into resource allocation remains a major opportunity, with important implications for current and future access to fish.Electronic supplementary materialThe online version of this article (10.1007/s13280-020-01371-3) contains supplementary material, which is available to authorized users. 相似文献