Comparison of several packings for CO2 chemical absorption in a packed column

CO₂ capture and storage has gained widespread attention as an option for reducing greenhouse gas emissions. Chemical absorption and stripping of CO₂ with hot potassium carbonate (K₂CO₃) solutions has been used in the past, however potassium carbonate solutions have a low CO₂ absorption efficiency. Various techniques can be used to improve the absorption efficiency of this system with one option being the addition of promoters to the solvent and another option being an improvement in the mass transfer efficiency of the equipment. This study has focused on improving the efficiency of the packed column by replacing traditional packings with newer types of packing which have been shown to have enhanced mass transfer performance. Three different packings (Super Mini Rings (SMRs), Pall Rings and Mellapak) have been studied under atmospheric conditions in a laboratory scale column for CO₂ absorption using a 30 wt% K₂CO₃ solution. It was found that SMR packing resulted in a mass transfer coefficient approximately 20% and 30% higher than that of Mellapak and Pall Rings, respectively. Therefore, the height of packed column with SMR packing would be substantially lower than with Pall Rings or Mellapak. Meanwhile, the pressure drop using SMR was comparable to other packings while the gas flooding velocity was higher when the liquid load was above 25 kg m⁻² s⁻¹. Correlations for predicting flooding gas velocities and pressure drop were fitted to the experimental data, allowing the relevant parameters to be estimated for use in later design.     

Dopamine release by the green alga <Emphasis Type="Italic">Ulvaria obscura</Emphasis> after simulated immersion by incoming tides

Ulvaria obscura, a prominent component of green tide blooms in Washington, is unique among macroalgae because it contains dopamine. To examine dopamine release by U. obscura following simulated low tides, we conducted 6 field experiments in which algae were emersed for 75 min and then immersed in filtered seawater (FSW). Dopamine was measured in algal tissues prior to emersion and 3 h after immersion and in seawater for 3 h following immersion. In our experiments, algae released 7–100% of their tissue dopamine, resulting in average seawater concentrations of 3–563 μM. In 5 of 6 experiments, seawater dopamine concentrations were highest immediately after immersion, and then decreased over time. The percentages of dopamine released were not correlated with tissue dopamine concentrations, but were positively correlated with solar radiation during emersion. The release of dopamine, which is both cytotoxic and genotoxic, may explain the negative effects of U. obscura exudates on marine organisms.     

The introduction of Littorina littorea to British Columbia, Canada: potential impacts and the importance of biotic resistance by native predators

Although the establishment and spread of non-indigenous species depends upon survival in the face of novel environmental conditions and novel biological interactions, relatively little attention has been focused on the specific role of native predators in limiting invasion success. The European common periwinkle, Littorina littorea, was recently introduced to the Pacific coast of Canada and provides a case study of an introduction into an area with an important predator guild (sea stars) that is functionally minor in the invader’s native habitat. Here, we assess the likelihood of establishment, spread, and negative ecological impact of this introduced gastropod, with an emphasis on the role of native sea stars as agents of biotic resistance. Size frequency distributions and local market availability suggest that L. littorea was most likely introduced via the live seafood trade. Non-native hitchhikers (e.g., the trematode Cryptocotyle lingua) were found on/in both market and field specimens. Laboratory studies and field observations confirmed that L. littorea can survive seasonal low salinity in Vancouver, British Columbia. Periwinkles also readily consumed native Ulva, suggesting that periwinkles could impact native communities via herbivory or resource competition. Unlike native gastropods, however, L. littorea lacked behavioural avoidance responses to Northeast Pacific predatory sea stars (Pisaster ochraceus and Pycnopodia helianthoides), and sea star predation rates on L. littorea were much higher than predation rates on native turban snails (Chlorostoma funebralis) in common garden experiments. We therefore expect periwinkle establishment in British Columbia to be limited to areas with low predator density, as is seen in its field distribution to date. We caution that this conclusion may understate the importance of the L. littorea introduction if it also serves as a vector for additional non-indigenous species such as C. lingua.     

南极陆生线虫Plectus murrayi对铜的敏感性及其培养和毒性试验程序的开发

南极生态系统特定的环境质量指导值和修复目标是进行南极污染场地风险评估和修复的必需条件。南极土壤生物的生态毒理学测试是确定可靠的污染物效应阈值浓度的基础。本研究描述了针对生活在土壤颗粒间隙水中的南极特有的土壤线虫Plectus murrayi的最佳培养技术和水生毒性实验程序。毒性试验持续时间较长,用于揭示该物种的生理学和生活史特征。Plectus murrayi对水溶性铜的敏感性表现其卵孵化率的效应浓度（EC50）为139 μg/L。首次以卵的形式接触水溶性铜的孵化幼体不如在孵化的J2期初次接触铜的幼体敏感,这表明该卵具有潜在的保护作用。幼体对铜的敏感性随着暴露时间的延长而增加, 21天和28天的半数致死浓度（LC50s）分别为478 μg/L和117 μg/L。本研究描述了应用于南极土壤污染物对环境相关测试物种的风险评估新方法,并首次估算了南极陆生微型无脊椎动物对毒物的敏感性。     

So animal a human ..., or the moral relevance of being an omnivore

It is argued that the question of whether or not one is required to be or become a strict vegetarian depends, not upon a rule or ideal that endorses vegetarianism on moral grounds, but rather upon whether one's own physical, biological nature is adapted to maintaining health and well-being on a vegetarian diet. Even if we accept the view that animals have rights, we still have no duty to make ourselves substantially worse off for the sake of other rights-holders. Moreover, duties to others, such as fetuses and infants, may require one to consume meat or animal products. Seven classes of individuals who are not required to be or become vegetarians are identified and their examption is related to nutritional facts; these classes comprise most of the earth's population. The rule of vegetarianism defines a special or provisional duty rather than any general or universal rule, since its observance it based upon the biological capacities of individual humans whose genetic constitution and environment makes them suitably herbivorous. It is also argued that generalizing the vegetarian ideal as a social goal for all would be wrongful because it fails to consider the individual nutritional needs of humans at various stages of life, according to biological differences between the sexes, and because it would have the eugenic effect of limiting the adaptability of the human species. The appeal to the natural interests of omnivores will not justify any claim that humans may eat amounts of meat or animal products in excess of a reasonable safety margin since animals have rights-claims against us.     

WATERSHED CONFIGURATION AND GEOGRAPHIC INFORMATION SYSTEM PARAMETERIZATION FOR SPUR MODEL HYDROLOGIC SIMULATIONS1

ABSTRACT: A grid cell geographic information system (GIS) is used to parameterize SPUR, a quasi-physically based surface runoff model in which a watershed is configured as a set of stream segments and contributing areas. GIS analysis techniques produce various watershed configurations by progressive simplification of a stream network delineated from digital elevation models (DEM). We used three watershed configurations: ≥ 2nd, ≥ 4th, and ≥ 13th Shreve order networks, where the watershed contains 28, 15, and 1 channel segments with 66, 37, and 3 contributing areas, respectively. Watershed configuration controls simulated daily and monthly sums of runoff volumes. For the climatic and topographic setting in southeastern Arizona the ≥ 4th order configuration of the stream network and contributing areas produces results that are typically as good as the ≥ 2nd order network. However both are consistently better than the ≥ 13th order configuration. Due to the degree of parameterization in SPUR, model simulations cannot be significantly improved by increasing watershed configuration beyond the ≥ 4th order network. However, a range of Soil Conservation Service curve numbers derived from rainfall/runoff data can affect model simulations. Higher curve numbers yield better results for the ≥ 2nd order network while lower curve numbers yield better results for the ≥ 4th order network.     

A probabilistic approach to obtaining limiting estimates of radionuclide concentration in biota

The US Department of Energy has developed a graded approach for evaluating radiation doses to biota. Limiting concentrations of radionuclides in water, soil, and sediment were derived for twenty-three radionuclides. Four organism types (aquatic animals, riparian animals, terrestrial animals, and terrestrial plants) were selected as the basis for method development. While environmental transfer data needed for deriving biota tissue concentrations are available for aquatic animals and terrestrial plants, less information is available for terrestrial and riparian organisms. Two methods were applied and examined for their ability to provide estimates of organism:soil or organism:water concentration factors in lieu of measured data. The kinetic/allometric approach combined with a parameter uncertainty analysis provides a needed method to estimate concentration factors across multiple species with limited input data.     

Environmental Accountability: Who's Kidding Whom?

International declarations and charters have been produced to encourage and support higher education institutions (HEIs) to address their environmental responsibilities. This paper discusses the results of a critical examination of a range of international HEIs that have signed the global environmental Talloires Declaration. It also assesses the Talloires Secretariat (University Leaders for a Sustainable Future, ULSF) and the extent to which this has been a primary stimulus. An international survey was undertaken and the results presented in a discursive format in order to highlight key driving forces, barriers, and opportunities for environmental responsibility in HEIs. Analysis reveals that they occur on two distinct and evolving levels: the macro national framework level and the micro institutional framework level. Survey responses revealed that none of the HEIs have an embedded institutional environmental culture and most did not have all the micro institutional mechanisms in place for an integrated university-wide environmental response. Many of the institutional barriers to environmental responsibility occurred as a result of this lack of strategy. The most significant institutional opportunity cited was enthusiastic individuals, particularly those at senior management or directorate level, and these individuals were found to be a key driving force. Results also showed that environmental reporting along the lines developed by the private sector is a flexible mechanism that can stimulate progress internally and externally and can be cost effectively disseminated via the World Wide Web. Moreover the survey results indicate that ULSF is not currently a primary stimulus for institution wide action.