Occurrence of boscalid and other selected fungicides in surface water and groundwater in three targeted use areas in the United States

Although the use of the insecticide γ-hexachlorocyclohexane (HCH) is now prohibited in many countries because of its hazardousness, stockpiles of γ-HCH still exist. In this study, we subjected γ-HCH to mechanochemical (MC) treatment with a planetary ball mill in the presence of CaO to investigate the feasibility of using this method for the treatment of γ-HCH stockpiles. We confirmed the degradation of γ-HCH and investigated the degradation mechanism. The major intermediates were identified to be 1,3,4,5,6-pentachlorocyclohexene (γ-PCCH) and chlorobenzenes (CBzs). Analysis of the steric structure of γ-HCH and identification of the degradation intermediates suggested that successive dehydrochlorination led to the formation of trichlorobenzenes. Products of further degradation (dichlorobenzenes, monochlorobenzene, and benzene) were also detected. Surprisingly, methane and ethane were also detected, which suggests cleavage of the C-C bonds of the cyclohexane ring and hydrogenation. All of the chlorine atoms in the γ-HCH could be transformed into inorganic chloride compounds by the MC treatment with CaO. Our results indicate that γ-HCH can be completely dechlorinated by MC treatment.     

The impact of the congestion charging scheme on ambient air pollution concentrations in London

On 17th February 2003, a congestion charging scheme (CCS), operating Monday–Friday, 07:00–18:00, was introduced in central London along with a programme of traffic management measures. We investigated the potential impact of the introduction of the CCS on measured pollutant concentrations (oxides of nitrogen (NO_X, NO and NO₂), particles with a median diameter less than 10 microns (PM₁₀), carbon monoxide (CO) and ozone (O₃)) measured at roadside and background monitoring sites across Greater London. Temporal changes in pollution concentrations within the congestion charging zone were compared to changes, over the same time period, at monitors unlikely to be affected by the CCS (the control zone) and in the boundary zone between the two. Similar analyses were done for CCS hours during weekends (when the CCS was not operating).Based on the single roadside monitor with the CCS Zone, it was not possible to identify any relative changes in pollution concentrations associated with the introduction of the scheme. However, using background monitors, there was good evidence for a decrease in NO and increases in NO₂ and O₃ relative to the control zone. There was little change in background concentrations of NO_X. There was also evidence of relative reductions in PM₁₀ and CO. Similar changes were observed during the same hours in weekends when the scheme was not operating.The causal attribution of these changes to the CCS per se is not appropriate since the scheme was introduced concurrently with other traffic and emissions interventions which might have had a more concentrated effect in central London. This study provides important pointers for study design and data requirements for the evaluation of similar schemes in terms of air quality. It also shows that results may be unexpected and that the overall effect on toxicity may not be entirely favourable.     

Globally regional life cycle analysis of automotive lithium-ion nickel manganese cobalt batteries

Electric vehicles based on lithium-ion batteries (LIB) have seen rapid growth over the past decade as they are viewed as a cleaner alternative to conventional fossil-fuel burning vehicles, especially for local pollutant (nitrogen oxides [NO_x], sulfur oxides [SO_x], and particulate matter with diameters less than 2.5 and 10 μm [PM_2.5 and PM₁₀]) and CO₂ emissions. However, LIBs are known to have their own energy and environmental challenges. This study focuses on LIBs made of lithium nickel manganese cobalt oxide (NMC), since they currently dominate the United States (US) and global automotive markets and will continue to do so into the foreseeable future. The effects of globalized production of NMC, especially LiNi_1/3Mn_1/3Co_1/3O₂ (NMC111), are examined, considering the potential regional variability at several important stages of production. This study explores regional effects of alumina reduction and nickel refining, along with the production of NMC cathode, battery cells, and battery management systems. Of primary concern is how production of these battery materials and components in different parts of the world may impact the battery’s life cycle pollutant emissions and total energy and water consumption. Since energy sources for heat and electricity generation are subject to great regional variation, we anticipated significant variability in the energy and emissions associated with LIB production. We configured Argonne National Laboratory’s Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET®) model as the basis for this study with key input data from several world regions. In particular, the study examined LIB production in the US, China, Japan, South Korea, and Europe, with details of supply chains and the electrical grid in these regions. Results indicate that 27-kWh automotive NMC111 LIBs produced via a European-dominant supply chain generate 65 kg CO₂e/kWh, while those produced via a Chinese-dominant supply chain generate 100 kg CO₂e/kWh. Further, there are significant regional differences for local pollutants associated with LIB, especially SO_x emissions related to nickel production. We find that no single regional supply chain outperforms all others in every evaluation metric, but the data indicate that supply chains powered by renewable electricity provide the greatest emission reduction potential.

     

Mammalian community characteristics on surface mine lands in Pennsylvania

Mammalian communities were studied on 10 surface mines over a four year period. The size and composition of these communities varied among the different areas. The size, composition, and spatial distribution of these mammalian communities were related to the structure of the plant community, and native plant species were of greater importance in determining size and composition of these communities than were those used in reclamation.     

Creating sustainable environmental health conditions by redefining municipal roles and responsibilities: experiences from Tunisia and Ecuador

The multiple and interlinked problems that plague most peri-urban communities can only be successfully addressed and resolved if roles and responsibilities of all actors in the urban setting are redistributed. This will require fundamental changes in the way municipalities work and define their accomplishments. Behaviour needs to change at all levels, beginning with public sector institutions responsible for communities. Without changes at the municipal level, requisite changes at the community level to remedy the root causes of environment-related illness, do not occur. Public sector institutions and communities, working as partners with clearly defined roles and responsibilities, and, most importantly, with mutual trust, can together make real progress toward improving health and well-being in peri-urban settlements. This article discusses two recent projects sponsored by the Environmental Health Project of the U.S. Agency for International Development (USAID): an 18-month pilot project to improve peri-urban environmental health in two cities in Tunisia, and a project in Ecuador to support the Ministry of Health in combating cholera in affected provinces. The following examples, methodology, and results may be useful to officials and donor organizations in designing environmental health projects.     

Infant feeding in emergencies

Recent experience of emergency relief operations in middle-income countries has shown that infant feeding issues can greatly complicate attempts to protect infant health. The two main problems are: how to protect and support breastfeeding in communities where it is no longer the norm and how to assist artificially fed infants without exposing them to the dramatically increased risks associated with artificial feeding under disaster conditions. This article explores the underlying issues and makes a number of recommendations for policy and programmes.     

Growth and physiology of Northern Red Oak: preliminary comparisons of mature tree and seedling responses to ozone

Considerable progress has been made during the past decade in the development of mechanistic models that allow complex chemical, physical, and biological processes to be evaluated in the global change context. However, quantitative predictions of the response of individual trees, stands, and forest ecosystems to pollutants and climatic variables require extrapolation of existing data sets, derived largely from seedling studies, to increasing levels of complexity with little or no understanding of the uncertainties associated with these extrapolations. Consequently, a project designed to address concerns associated with scaling from seedling to mature tree responses was initiated. During the 1990 and 1991 growing seasons, mature northern red oak (Quercus rubra L.) trees and seedlings were exposed to subambient, ambient, and twice ambient ozone (O(3)) concentrations. The initial focus of the study was to identify possible trends and obvious differences between mature trees and seedlings, both in terms of growth and physiology and in response to O(3). Generally, mature trees exhibited a greater decrease in photosynthesis rates over the growing season than did the seedlings. Ozone treatments had no consistent effect on gas exchange rates of seedlings, but the twice ambient O(3) treatment resulted in reduced photosynthesis rates in the mature tree. Despite no effect of O(3) on seedling gas exchange rates, total seedling biomass was significantly less at the end of the 1991 growing season for those seedlings exposed to twice ambient O(3) levels. Disproportionate reductions in root biomass also resulted in reduced root to shoot ratios at elevated O(3) concentrations.     

Response of the predatorRhizophagus grandis to host plant derived chemicals inDendroctonus micans larval frass in wind tunnel experiments (Coleoptera: Rhizophagidae,Scolytidae)

Summary Adults of the predatory beetleRhizophagus grandis are strongly attracted to both adult and larval frass of its specific prey,Dendroctonus micans, in walking bioassays. Spruce bark and resin are relatively unattractive. Solvent extracts of larval frass that were attractive toR. grandis adults in a flight wind tunnel contained a mixture of monoterpenes of host plant origin. A synthetic mixture of these monoterpenes, (+)—-pinene, (–)—-pinene, -phellandrene,dl limonene and 3-carene, was responsible for 70–80% of the activity of the most attractive extract. We suggest that a blend of monoterpenes in frass acts as a kairomone forR. grandis but that attraction to monoterpenes is only the first of a sequence of behavioural responses that ensures successful host location and identification.     

Theory into Practice: Implementing Ecosystem Management Objectives in the USDA Forest Service

In the United States and around the world, scientists and practitioners have debated the definition and merits of ecosystem management as a new approach to natural resource management. While these debates continue, a growing number of organizations formally have adopted ecosystem management. However, adoption does not necessarily lead to successful implementation, and theories are not always put into practice. In this article, we examine how a leading natural resource agency, the United States Department of Agriculture Forest Service, has translated ecosystem management theory into concrete policy objectives and how successfully these objectives are perceived to be implemented throughout the national forest system. Through document analysis, interviews, and survey responses from 345 Forest Service managers (district rangers, forest supervisors, and regional foresters), we find that the agency has incorporated numerous ecosystem management components into its objectives. Agency managers perceive that the greatest attainment of such objectives is related to collaborative stewardship and integration of scientific information, areas in which the organization has considerable prior experience. The objectives perceived to be least attained are adaptive management and integration of social and economic information, areas requiring substantial new resources and a knowledge base not traditionally emphasized by natural resource managers. Overall, success in implementing ecosystem management objectives is linked to committed forest managers.     

A Multiscale Conceptual Framework for Integrated Ecogeomorphological Research to Support Stream Naturalization in the Agricultural Midwest

The complexity of fluvial systems necessitates interdisciplinary research in fluvial geomorphology and aquatic ecology to develop a fundamental understanding of interconnections among biotic and abiotic aspects of these systems. Integrated knowledge of this type is vital for environmental management of streams in human-dominated environments. A conceptual framework is presented for integrating geomorphological and ecological research on streams in East Central Illinois, USA, a glaciated low-relief agricultural landscape. The framework embodies a multiscale perspective in which a geomorphological conception of the fluvial system is used to define a hierarchy of characteristic spatial scales for exploring important linkages between stream geomorphology and aquatic ecology. The focus ecologically is on fish, because a rich body of historical information exists on fisheries in East Central Illinois and because past work has suggested that availability of physical habitat is a major factor influencing the community characteristics of fish in this human-altered environment. The hierarchy embodied in the framework includes the network, link, planform, bar unit, bar element, and bedform/grain scales. Background knowledge from past research is drawn upon to identify potential linkages between geomorphological and ecological conditions at each of these scales. The conceptual framework is useful for guiding integrated ecogeomorphological research at specific scales and across different scales. It also is helpful for illustrating how widespread human modification of streams has catastrophically altered the scalar structure of fluvial systems in East Central Illinois. Knowledge emerging from the integrated research provides a basis for environmental-management schemes directed toward stream naturalization.