Globally regional life cycle analysis of automotive lithium-ion nickel manganese cobalt batteries

Electric vehicles based on lithium-ion batteries (LIB) have seen rapid growth over the past decade as they are viewed as a cleaner alternative to conventional fossil-fuel burning vehicles, especially for local pollutant (nitrogen oxides [NO_x], sulfur oxides [SO_x], and particulate matter with diameters less than 2.5 and 10 μm [PM_2.5 and PM₁₀]) and CO₂ emissions. However, LIBs are known to have their own energy and environmental challenges. This study focuses on LIBs made of lithium nickel manganese cobalt oxide (NMC), since they currently dominate the United States (US) and global automotive markets and will continue to do so into the foreseeable future. The effects of globalized production of NMC, especially LiNi_1/3Mn_1/3Co_1/3O₂ (NMC111), are examined, considering the potential regional variability at several important stages of production. This study explores regional effects of alumina reduction and nickel refining, along with the production of NMC cathode, battery cells, and battery management systems. Of primary concern is how production of these battery materials and components in different parts of the world may impact the battery’s life cycle pollutant emissions and total energy and water consumption. Since energy sources for heat and electricity generation are subject to great regional variation, we anticipated significant variability in the energy and emissions associated with LIB production. We configured Argonne National Laboratory’s Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET®) model as the basis for this study with key input data from several world regions. In particular, the study examined LIB production in the US, China, Japan, South Korea, and Europe, with details of supply chains and the electrical grid in these regions. Results indicate that 27-kWh automotive NMC111 LIBs produced via a European-dominant supply chain generate 65 kg CO₂e/kWh, while those produced via a Chinese-dominant supply chain generate 100 kg CO₂e/kWh. Further, there are significant regional differences for local pollutants associated with LIB, especially SO_x emissions related to nickel production. We find that no single regional supply chain outperforms all others in every evaluation metric, but the data indicate that supply chains powered by renewable electricity provide the greatest emission reduction potential.

     

Concentration and Recovery of Viruses from Water: A Comprehensive Review

Enteric viruses are a cause of waterborne disease worldwide, and low numbers in drinking water can present a significant risk of infection. Because the numbers are often quite low, large volumes (100–1,000 L) of water are usually processed. The VIRADEL method using microporous filters is most commonly used today for this purpose. Negatively charged filters require the addition of multivalent salts and acidification of the water sample to effect virus adsorption, which can make large-volume sampling difficult. Positively charged filters require no preconditioning of samples, and are able to concentrate viruses from water over a greater pH range than electronegative filters. The most widely used electropositive filter is the Virosorb 1MDS; however, the Environmental Protection Agency has added the positively charged NanoCeram filters to their proposed Method 1615. Ultrafilters concentrate viruses based on size exclusion rather than electrokinetics, but are impractical for field sampling or processing of turbid water. Elution (recovery) of viruses from filters following concentration is performed with organic (e.g., beef extract) or inorganic solutions (e.g., sodium polyphosphates). Eluates are then reconcentrated to decrease the sample volume to enhance detection methods (e.g., cell culture infectivity assays and molecular detection techniques). While the majority of available filters have demonstrated high virus retention efficiencies, the methods to elute and reconcentrate viruses have met with varying degrees of success due to the biological variability of viruses present in water.     

Tagging Diesel and Residential Oil Furnace Emissions in Roanoke,Virginia, with Enriched Isotopes of Samarium

Stable isotopic tracers were used in Roanoke, Virginia, to tag particulate emissions from diesel trucks and residential oil furnaces, two sources of soot and PAHs which cannot be differentiated on the basis of known constituents. Approximately 1.6 g of enriched ¹⁴⁹Sm were used to tag 264 m³ of diesel fuel burned by the city bus and truck fleets; 0.39 g of ¹⁵⁰Sm were used to tag 106 m³ of residential heating oil. Picogram amounts of the tracers were determined simultaneously by thermal-ionization mass spectrometry in fine particles collected within the city at signal-to-noise ratios as large as 6000. These results demonstrate the feasibility of tracing particles from multiple combustion sources with stable, separated isotopes.     

Narratives Can Motivate Environmental Action: The Whiskey Creek Ocean Acidification Story

Even when environmental data quantify the risks and benefits of delayed responses to rapid anthropogenic change, institutions rarely respond promptly. We propose that narratives complementing environmental datasets can motivate responsive environmental policy. To explore this idea, we relate a case study in which a narrative of economic loss due to regionally rapid ocean acidification—an anthropogenic change—helped connect knowledge with action. We pose three hypotheses to explain why narratives might be particularly effective in linking science to environmental policy, drawing from the literature of economics, environmental policy, and cognitive psychology. It seems that yet-untold narratives may hold similar potential for strengthening the feedback between environmental data and policy and motivating regional responses to other environmental problems.     

Integrated Measures of Anthropogenic Stress in the U.S. Great Lakes Basin

Integrated, quantitative expressions of anthropogenic stress over large geographic regions can be valuable tools in environmental research and management. Despite the fundamental appeal of a regional approach, development of regional stress measures remains one of the most important current challenges in environmental science. Using publicly available, pre-existing spatial datasets, we developed a geographic information system database of 86 variables related to five classes of anthropogenic stress in the U.S. Great Lakes basin: agriculture, atmospheric deposition, human population, land cover, and point source pollution. The original variables were quantified by a variety of data types over a broad range of spatial and classification resolutions. We summarized the original data for 762 watershed-based units that comprise the U.S. portion of the basin and then used principal components analysis to develop overall stress measures within each stress category. We developed a cumulative stress index by combining the first principal component from each of the five stress categories. Maps of the stress measures illustrate strong spatial patterns across the basin, with the greatest amount of stress occurring on the western shore of Lake Michigan, southwest Lake Erie, and southeastern Lake Ontario. We found strong relationships between the stress measures and characteristics of bird communities, fish communities, and water chemistry measurements from the coastal region. The stress measures are taken to represent the major threats to coastal ecosystems in the U.S. Great Lakes. Such regional-scale efforts are critical for understanding relationships between human disturbance and ecosystem response, and can be used to guide environmental decision-making at both regional and local scales.     

Biological and chemical transformation of atrazine in coastal aquatic sediments

The degradation and distribution potential of atrazine, a persistent triazine herbicide, into three chemical fractions were measured in coastal aquatic sediments in the laboratory over time. Sediments with varying organic carbon contents were extracted with an organic solvent followed by an alkali hydrolysis reaction, and atrazine, deethylatrazine (DEA) and deisopropylatrazine (DIA) were quantified in the aqueous, solvent, and basic fractions using gas chromatography-mass spectrometry. The total amount of atrazine and its metabolites recovered after 95 days varied by site and ranged from 5% to 30% in which 95% was atrazine found primarily in the solvent fraction. Sediment organic carbon was positively correlated with the distribution of atrazine into the basic fraction and the decline in the total amount recovered. No DIA was detected in laboratory spiked sediments and transformation to DEA was limited in all sediments and made up less than 1% of the mass balance. The production and persistence of DEA were inversely correlated to organic carbon; sediments with less carbon and limited binding sites had increased formation and persistence of DEA. A secondary metabolite, methylated atrazine (M-ATR) not previously documented to be derived from atrazine, was chemically produced, detected in all sediments and time points, and concentrations were an order of magnitude higher than DEA. Based on results from spiked estuarine sediments, atrazine and M-ATR may have the potential to persist in the environment while DEA and DIA may not be an ecological threat due to their limited formation.     

Dairy manure treatment, digestion and nutrient recovery as a phosphate fertilizer

A combined approach of biological treatment, solids digestion and nutrient recovery was tested on dairy manure. A sequencing batch reactor (SBR) was operated in three modes, in order to optimize nutrient (nitrogen and phosphorus) removals. The highest average removal efficiencies of 91% for NH4-N, 59% for PO4-P and 80% for total chemical oxygen demand (COD) were achieved. Staining experiments suggested the coexistence of glycogen and phosphorus accumulating organisms. Anaerobic digestion of wasted bio-solids was able to produce a PO4-P concentration of 70 mgL-1 in the supernatant. A pilot-scale experiment, designed to recover phosphorus in the supernatant as struvite (magnesium ammonium phosphate), was able to remove 82% of soluble PO4-P.     

Mammalian community characteristics on surface mine lands in Pennsylvania

Mammalian communities were studied on 10 surface mines over a four year period. The size and composition of these communities varied among the different areas. The size, composition, and spatial distribution of these mammalian communities were related to the structure of the plant community, and native plant species were of greater importance in determining size and composition of these communities than were those used in reclamation.     

Foraminifera as bioindicators in coral reef assessment and monitoring: the FORAM Index. Foraminifera in Reef Assessment and Monitoring

Coral reef communities are threatened worldwide. Resource managers urgently need indicators of the biological condition of reef environments that can relate data acquired through remote-sensing, water-quality and benthic-community monitoring to stress responses in reef organisms. The FORAM (Foraminifera in Reef Assessment and Monitoring) Index (FI) is based on 30 years of research on reef sediments and reef-dwelling larger foraminifers. These shelled protists are ideal indicator organisms because: Foraminifers are widely used as environmental and paleoenvironmental indicators in many contexts; Reef-building, zooxanthellate corals and foraminifers with algal symbionts have similar water-quality requirements; The relatively short life spans of foraminifers as compared with long-lived colonial corals facilitate differentiation between long-term water-quality decline and episodic stress events; Foraminifers are relatively small and abundant, permitting statistically significant sample sizes to be collected quickly and relatively inexpensively, ideally as a component of comprehensive monitoring programs; and Collection of foraminifers has minimal impact on reef resources.USEPA guidelines for ecological indicators are used to evaluate the FI. Data required are foraminiferal assemblages from surface sediments of reef-associated environments. The FI provides resource managers with a simple procedure for determining the suitability of benthic environments for communities dominated by algal symbiotic organisms. The FI can be applied independently, or incorporated into existing or planned monitoring efforts. The simple calculations require limited computer capabilities and therefore can be applied readily to reef-associated environments worldwide. In addition, the foraminiferal shells collected can be subjected to morphometric and geochemical analyses in areas of suspected heavy-metal pollution, and the data sets for the index can be used with other monitoring data in detailed multidimensional assessments.