坦桑尼亚水质和污染研究回顾

坦桑尼亚的海岸带(图1)有多种生物栖息地,其中包括珊瑚礁、红树林、海草床、沙坝、湿地和沙滩.除了承担海岸带所有功能中的基本连接作用外,这些海岸带栖息地还提供了生物和非生物资源.     

Efficiency and degradation products elucidation of the photodegradation of mefenpyrdiethyl in water interface using TiO2 P-25 and Hombikat UV100

The photodegradation of mefenpyrdiethyl (MFD), an herbicide safener, was investigated in aqueous suspensions by using Degussa P-25 and Hombikat UV100 titanium oxide under simulated sunlight irradiation. The effects of initial concentration of the herbicide, pH, catalysts and hydrogen peroxide doses as well as their combinations were studied and optimized. Accordingly, the kinetic parameters were determined and the effectiveness of the processes was assessed by calculating the rate constants. A pseudo first-order kinetics was observed. Under experimental conditions, the degradation rate constants were strongly influenced using P-25 and no noticeable effect was observed for Hombikat UV100. DFT calculations with B3LYP/6-311+G(2d,p)//B3LYP/6-31+G(d,p) level of theory were performed to check whether significant conformational changes occur when the charge state of the MFD substrate changes and whether these changes could play a role in the dependency of photodegradation rate constant on the studied pH. High resolution mass spectrometry (FT-ICR/MS) was implemented to identify the main degradation products.     

On the extraction of an exhaustible resource by a monopoly

Hotelling's r-percent rule does not hold for monopoly extractors of durable exhaustible resources. An example with a nondurable resource in which the rule also fails to hold is presented. An economy with a fixed average propensity to save is modelled. The monopoly extractor recognizes that resource extraction, by affecting output and hence capital accumulation, affects future demand. The firm exploits this effect by causing the marginal profitability of extraction to grow faster or slower than the rate of interest, depending upon initial conditions. Conditions are developed under which the growth rate will be less than the interest rate.     

Geochemical variations in aeolian mineral particles from the Sahara-Sahel Dust Corridor

The Sahara-Sahel Dust Corridor runs from Chad to Mauritania and expels huge amounts of mineral aerosols into the Atlantic Ocean. Data on samples collected from Algeria, Chad, Niger, and Western Sahara illustrate how corridor dust mineralogy and chemistry relate to geological source and weathering/transport history. Dusts sourced directly from igneous and metamorphic massifs are geochemically immature, retaining soluble cations (e.g., K, Na, Rb, Sr) and accessory minerals containing HFSE (e.g., Zr, Hf, U, Th) and REE. In contrast, silicate dust chemistry in desert basins (e.g., Bodélé Depression) is influenced by a longer history of transport, physical winnowing (e.g., loss of Zr, Hf, Th), chemical leaching (e.g., loss of Na, K, Rb), and mixing with intrabasinal materials such as diatoms and evaporitic salts. Mineral aerosols blown along the corridor by the winter Harmattan winds mix these basinal and basement materials. Dusts blown into the corridor from sub-Saharan Africa during the summer monsoon source from deeply chemically weathered terrains and are therefore likely to be more kaolinitic and stripped of mobile elements (e.g., Na, K, Mg, Ca, LILE), but retain immobile and resistant elements (e.g., Zr, Hf, REE). Finally, dusts blown southwestwards into the corridor from along the Atlantic Coastal Basin will be enriched in carbonate from Mesozoic-Cenozoic marine limestones, depleted in Th, Nb, and Ta, and locally contaminated by uranium-bearing phosphate deposits.     

Metal concentrations in edible mushrooms following municipal sludge application on forest land

In the context of biosolids utilisation in forestry, effects of sludge application on mushroom metal concentration were studied in six sites of maritime pine forests in the South-West of France. Municipal sludge were applied at a rate of 6 T dry matter per hectare. Edible mushrooms were collected two years after sludge application. As, Cd, Cu, Hg, Pb, Se and Zn concentrations were determined. Results showed a high variability for trace element concentrations in mushrooms collected from control areas. No significant correlation was found between soil parameters (pH and trace elements concentrations) and mushroom trace element concentrations. Even if the concentration of trace metals increased in the soils, sludge application did not affect As, Cu, Se and Zn concentrations in carpophores but slightly increased Cd, Pb and Hg concentrations on some sites. This effect is dependent on sludge type and sites.     

Biology of penaeid prawns in the Suez Canal lakes

A study was made from January 1988 to March 1989 of the penaid prawns in the Great Bitter Lake and Lake Timsah located in the central part of the Suez Canal. Two species of Red Sea origin were investigated,Metapenaeus stebbingi andTrachypenaeus curvirostris; the former is by far the commoner. Both species displayed seasonal breeding over the period April to October, with peaks in the early and late parts of the season.M. stebbingi had two main cohorts each year. A spring-spawned cohort survived 16 mo, and attained modal sizes of 23 mm carapare length (CL) for females and 16 to 17 mm CL for males. The autumn-spawned cohort survived 13 mo, and reached modal sizes of 20 mm and 15 mm CL for males and females, respectively. The reasons for the success ofM. stebbingi in the Canal lakes, in contrast to other Lessepsian penaeids which have flourished in the Mediterranean Sea, have been considered. The main factors are that it is essentially a shallow-water species, with excellent tolerance of salinity variations and adverse environments. However, the Canal lake populations have smaller maximum sizes, and mature earlier, than those in open seas.     

Bioremediation of HCH-contaminated soil: elimination of inhibitory effects of the insecticide on radish and green gram seed germination

The effects of technical grade hexachlorocyclohexane (tech-HCH) on the germination of different seeds were tested. Two types of seeds, radish and green gram showed marked reduction in germination percentage and seeding vigour index. The abnormalities and reduction in germination increased with increasing concentration of tech-HCH. At 100 microg HCH level the germination of radish and green gram seeds was inhibited almost completely on moist filter paper and soil. Protease and amylase activities were reduced in seeds grown in soil spiked with tech-HCH. Bioremediation of HCH-spiked soils with a HCH-degrading microbial consortium helped in eliminating the toxic effects of tech-HCH towards seed germination. The degradation of 25 microg tech-HCH g(-1) soil was complete by 120 h. The seed germination and the activities of the assayed enzymes, amylase and protease, were same as before or better in bioremediated soils.     

Economic assessment of the negative impacts of ozone on crop yields and forest production. A case study of the estate Ostads Säteri in southwestern Sweden

Ground level ozone concentrations, in combination with the prevailing climate, at the estate Ostads S?teri in southwestern Sweden were estimated to reduce the yield of wheat and potato ranging between 5% and 10%. Occasionally, in years with the highest ozone concentrations and/or climatic conditions favoring high rates of ozone uptake to the leaves, yield loss levels above 10% may occur. Based on simple extrapolation, these ozone-induced reductions of crop yields at Ostads S?teri represent a potential total annual yield loss in Sweden in the range of 24.5 million Euro for wheat and 7.3 million Euro for potato, respectively. A simulation of forest growth at Ostad S?teri predicted that prevailing mean ozone exposure during 1993-2003 had the potential to reduce forest growth by 2.2% and the economic return of forest production by 2.6%. Using this value for extrapolation to the national level, the potential annual economic loss for Sweden due to negative impacts of ozone on forest production would be in the range of 56 million Euro (2004 prices).     

Surfactant solubilization of hydrophobic compounds in soil and water

The soil/water partition coefficient (K_d) of hexachlorobenzene (HCB) ranged from 220 1/kg to 1800 1/kg for eight soils having a wide range of physico-chemical properties. K_d normalised to soil organic carbon (K_oc) was found to be 28000 ± 4800 1/kg. Anionic surfactant dodecylsulphate (DS) present at concentrations above the critical micellar concentration (CMC) caused reductions in the apparent soil/water partition coefficient (K_d ^*) in the range of 3–26 times for most soils and up to 36–91 times for sandy soils. Below CMC, at environmentally relevant surfactant concentrations, K_d ^* was reduced by a factor of 1–13. For clay and calcareous soils significant adsorption/complexation/precipitation of DS occurred. At the lowest DS concentration this produced a two-fold increase in K_d ^*. At increasing DS concentrations this effect was shielded by the solubihzing effect from DS. Monomer (K_mn) and micellar (K_mc) surfactant/water partition coefficients for HCB were determined to be, 980 ± 190 1/kg and 21000 ± 1600 1/kg, respectively.     

Modeling and simulation of biogas-fueled power system

The main objective of this paper is to develop a complete model that fully simulate a biogas-fueled power plant which can be used to supply a rural farm with sufficient electricity. The reactor is fed with animal manure of the farm. The proposed model consists of three main parts; a biogas reactor, a microturbine (MT) coupled to a permanent magnet synchronous generator, and a storage system. The model describes the dynamics of an MT and it is suitable for both steady state and transient simulation and analysis. The volume of biogas output delivered from the Anaerobic Digester depends on the reactor volume, reactor temperature, and animal manure type. The storage system is used to store the excess value of biogas if any. It is composed of two parts: a comparator and a storage tank. The comparator compares the volume of biogas produced by the reactor with that needed to supply the load. An adaptive controller is developed to withstand the system against any transient condition such as suddenly load increase/decrease. The proposed model is implemented for chemical and physical behaviors of the biogas production process, as well as for different variables of MT-generator operations. The model is implemented in Matlab/Simulink environment and tested under different operating conditions in both steady state and transient status to study the impacts of different variables on the system output. The output results prove its applicability and effectiveness under different operating conditions.