A review of arsenicals in biology

The most toxic form of arsenic is arsine gas. Arsenite is also highly toxic and arsenate is moderately toxic. Arsine gas will lyse red blood cells, arsenite inactivates particular enzymes and arsenate uncouples oxidative phosphorylation. Arsenic does not appear to be a significant mutagen. Epidemiological studies have implicated arsenic as a cause of lung cancer and skin cancer, but arsenic generally does not induce cancer in laboratory animals. Arsenic may bioaccumulate in some plants and marine organisms. Bacteria can be resistant to arsenic by preventing arsenate from entering the cell (chromosomal resistance) or pumping arsenic out of the cell (plasmid resistance). Many different organisms, including mammals, have the ability to methylate inorganic arsenic. Biomethylation seems to be a mechanism of arsenic detoxification.     

Estimation and testing for covariance-spectral spatial-temporal models

Environmental and Ecological Statistics - In this paper we explore a covariance-spectral modelling strategy for spatial-temporal processes which involves a spectral approach for time but a...     

LANGUAGE CONSTRAINTS TO WATER RESOURCE UTILIZATION1

ABSTRACT: Worldwide development of water resources and control of pollution would be improved by the ability for direct, multilateral communication between workers in the dozens of different language communities involved. Current language-based problems which should be eliminated include (1) incomplete diffusion of scientific knowledge, (2) technical inbreeding, (3) unsatisfactory international conferences, (4) money wasted on translation, and (5) unstandardized technical terminology. General education in a common second language for international use can eliminate these conditions. Ethnic languages are not qualified for this purpose, because of their national biases and extreme learning difficulties. The Esperanto language is free of these limitations, and its application is recommended as a means for improving the overall performance of the industry.     

Enhanced anaerobic bioremediation in a DNAPL residual source zone: Test Area North case study

An Interstate Technology and Regulatory Council (ITRC) forum was recently held that focused on case studies in which bioremediation of dense nonaqueous‐phase liquids (DNAPLs) was performed. This first case study, the Test Area North (TAN) site of the Idaho National Engineering and Environmental Laboratory, involves a trichloroethene (TCE) residual source area in a deep, fractured basalt aquifer that has been undergoing enhanced bioremediation since January 1999. Complete dechlorination from TCE to ethene was documented within nine months of operation, and sodium lactate injections were shown to enhance TCE mass transfer from the residual source. Since that time, optimization of injection strategies has maintained efficient dechlorination while demonstrating accelerated cleanup at a lower cost by changing to a whey powder amendment that solubilizes DNAPL. © 2006 Wiley Periodicals, Inc.     

Conservation of Biodiversity in a World of Use

Abstract: Biodiversity conservation has become the stated objective of national governments, state agencies, local communities, and scientific organizations. Yet despite this attention the term biodiversity remains poorly defined. One of the unfortunate consequences of this lack of definition is a proliferation of claims that biodiversity can be both used and conserved. This claim is difficult to assess without a more precise way of defining biodiversity. We offer a heuristic framework for measuring the consequences of human use for biodiversity. Our definition of biodiversity includes three components: genetic, population/species, and community/ecosystem. Each component has its own three attributes: composition, structure, and function. Using this definition, we assessed the effects of different types of human use on the different components and attributes of biodiversity. We show that (1) different degrees of human use or alteration result in differential conservation of biodiversity components; (2) some components and attributes of biodiversity are more sensitive to human use than others; and (3) only extremely limited use or virtually no alteration will protect all components.     

NUTRIENTS DISCHARGED TO THE MISSISSIPPI RIVER FROM EASTERN IOWA WATERSHEDS, 1996.19971

ABSTRACT: The introduction of nutrients from chemical fertilizer, animal manure, wastewater, and atmospheric deposition to the eastern Iowa environment creates a large potential for nutrient transport in watersheds. Agriculture constitutes 93 percent of all land use in eastern Iowa. As part of the U.S. Geological Survey National Water Quality Assessment Program, water samples were collected (typically monthly) from six small and six large watersheds in eastern Iowa between March 1996 and September 1997. A Geographic Information System (GIS) was used to determine land use and quantify inputs of nitrogen and phosphorus within the study area. Streamliow from the watersheds is to the Mississippi River. Chemical fertilizer and animal manure account for 92 percent of the estimated total nitrogen and 99.9 percent of the estimated total phosphorus input in the study area. Total nitrogen and total phosphorus loads for 1996 were estimated for nine of the 12 rivers and creeks using a minimum variance unbiased estimator model. A seasonal pattern of concentrations and loads was observed. The greatest concentrations and loads occur in the late spring to early summer in conjunction with row‐crop fertilizer applications and spring nmoff and again in the late fall to early winter as vegetation goes into dormancy and additional fertilizer is applied to row‐crop fields. The three largest rivers in eastern Iowa transported an estimated total of 79,000 metric tons of total nitrogen and 6,800 metric tons of total phosphorus to the Mississippi River in 1996. The estimated mass of total nitrogen and total phosphorus transported to the Mississippi River represents about 19 percent of all estimated nitrogen and 9 percent of all estimated phosphorus input to the study area.     

Groundwater Vulnerability,Brownfield Redevelopment and Land Use Planning

An understanding of groundwater vulnerability in urban watersheds is important for the prevention of both surface water and groundwater contamination and can therefore be a useful tool in brownfield redevelopment and land use planning. Although industrial activity in southeastern Michigan has historically been restricted to the urbanized sections of metropolitan Detroit, new industrial development is rapidly taking place in rural and undeveloped areas. Although environmentalists and urban planners agree that industrial site recycling in urban centres (a.k.a. brownfield redevelopment) is preferable to developing green areas, many older sites remain undeveloped due to real and perceived risks. Using a PC-based geographic information system, a conceptual model of solute transport in soil was developed to evaluate potential impacts to both groundwater and surface water quality resulting from industrial development. The model was used to create a map of groundwater vulnerability within the Rouge River watershed of southeastern Michigan. The map has been used to pin-point several rural and undeveloped areas where groundwater quality is threatened by proposed development. It has also clearly demonstrated that many older brownfield sites, within the City of Detroit, are located on materials that have a much lower vulnerability to groundwater contamination and may therefore be far less costly to redevelop than greenfield sites in undeveloped areas of the watershed.     

Estimates of Ground Level TSP,S02 and HCI for a Municipal Waste Incinerator to be Located at Tynes Bay—Bermuda

The computer model Industrial Source Complex Short Term (ISCST) was used to study the stack emissions from a refuse Incinerator proposed for the island of Bermuda. The model predicts that the highest ground level pollutant concentrations will occur near Prospect, 800 m to 1000 m due south of the stack. We installed a portable laboratory and instruments at Prospect to begin making air quality baseline measurements. By comparing the model’s estimates of the incinerator contribution to the background levels measured at the site we predict that stack emissions will not cause an Increase In TSP or SO₂. The incinerator will be a significant source of HCI to Bermuda air with ambient levels approaching air quality guidelines.