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81.
Georgios Karavalakis Dimitrios Ampatzoglou Stamoulis Stournas Evangelos Bakeas 《Environmental pollution (Barking, Essex : 1987)》2010,158(5):1584-1594
This study explores the impact of five different types of methyl esters on polycyclic aromatic hydrocarbon (PAH), nitrated-PAH and oxygenated PAH emissions. The measurements were conducted on a chassis dynamometer, according to the European regulation. Each of the five different biodiesels was blended with EN590 diesel at a proportion of 10-90% v/v (10% biodiesel concentration). The vehicle was a Euro 3 compliant common-rail diesel passenger car. Emission measurements were performed over the NEDC and compared with those of the real traffic-based Artemis driving cycles. The experimental results showed that the addition of biodiesel led to some important increases in low molecular-weight PAHs (phenanthrene and anthracene) and to both increases and reductions in large PAHs which are characterised by their carcinogenic and mutagenic properties. Nitro-PAHs were found to reduce with biodiesel whereas oxy-PAH emissions presented important increases with the biodiesel blends. The impact of biodiesel source material was particularly clear on the formation of PAH compounds. It was found that most PAH emissions decreased as the average load and speed of the driving cycle increased. Cold-start conditions negatively influenced the formation of most PAH compounds. A similar trend was observed with particulate alkane emissions. 相似文献
82.
Leaching of the organophosphorus nematicide fosthiazate 总被引:1,自引:0,他引:1
Karpouzas DG Pantelelis I Menkissoglu-Spiroudi U Golia E Tsiropoulos NG 《Chemosphere》2007,68(7):1359-1364
Fosthiazate is an organophosphorus nematicide which was recently included in Annex I of the Directive 91/414/EEC under the clause that it should be used with special care in soils vulnerable to leaching. Thus, the leaching of fosthiazate was investigated in columns packed with three different soils which represented situations of high (site 2), intermediate (site 1) and low (site 3) leaching potential. The recommended dose of fosthiazate was applied at the surface of the soil columns and fosthiazate fate and transport was investigated for the next two months. Fosthiazate concentrations in the leachate collected from the bottom of the columns packed with soil from site 2 exceeded 0.1 microgl(-1) in most cases. This soil was characterized as acidic, indicating longer fosthiazate persistence, with low organic matter content, indicating weak adsorption, thus representing a situation vulnerable to leaching. In contrast, the lowest concentrations of fosthiazate in the leachate were evident in the columns packed with soil from site 3. This soil was characterized as alkaline, indicating faster degradation, with higher organic matter content, indicating stronger adsorption, thus representing a situation not favoring leaching of fosthiazate. The highest concentration of fosthiazate in the leachate from the columns packed with soil from site 2 was 3.44 microgl(-1) compared to 1.17 and 0.16 microgl(-1), which were the corresponding maximum values measured in columns packed with soil from sites 1 and 3, respectively. The results of the current study further suggest that fosthiazate is mobile in soil and can leach under conducive soil conditions like acidic soils with low organic matter content. 相似文献
83.
The effectiveness of the enforcement of the ISM-Code and the examination of its role in the distribution of causes of shipping accidents between human and non-human error was studied. All accidents involving Greek-flagged ships from 1995 to 2006, a time-scale which spans over the pre- and post-ISM period in navigational regions of restricted waters, were analyzed.The accident data was processed through a classification tree analysis which enabled the classification of various accident factors. The analysis revealed that although the human error maintained its position as the dominant factor in shipping accidents, there is also substantial evidence in support of the ISM-Code effective control over shipping accidents during the post-ISM period. The implementation of the ISM-Code led to an overall reduction of human-induced accidents in total. Furthermore, in terms of location, the ISM-Code improved the human-induced accident record within restricted waters.Conclusively, the ISM-Code constitutes an effective policy measure for shipping safety. The results of the classification tree analysis reported in the present work can be used by decision makers in companies and international organizations to build knowledge-based expert systems and augment their information in the field of safety policy and management. 相似文献
84.
Geczo Alexandra Giannakoudakis Dimitrios Andreas Triantafyllidis Konstantinos Elshaer Mohammed Ragab Rodríguez-Aguado Elena Bashkova Svetlana 《Environmental science and pollution research international》2021,28(42):58969-58982
Environmental Science and Pollution Research - Activated carbons prepared from cashew nut shells by chemical activation with phosphoric acid were tested for the removal of acetaminophen. It was... 相似文献
85.
Mavriou Zografina Alexandropoulou Ioanna Melidis Paraschos Karpouzas Dimitrios G. Ntougias Spyridon 《Environmental science and pollution research international》2021,28(4):3774-3786
Environmental Science and Pollution Research - The large quantities and the persistent nature of fungicide wastewaters have increased the efforts towards a sustainable technological solution. In... 相似文献
86.
Charvalas Georgios Solomou Alexandra D. Giannoulis Kyriakos D. Skoufogianni Elpiniki Bartzialis Dimitrios Emmanouil Christina Danalatos Nicholaos G. 《Environmental science and pollution research international》2021,28(4):3858-3863
Environmental Science and Pollution Research - Phytoremediation is an effective technique for the processing of contaminated soil and for sequestering environmental contaminants such as heavy... 相似文献
87.
88.
A series of experimental runs were conducted from 1995 to 1999 in Madison (WI, USA) with the goal to investigate the biodegradation process of seven (7) solid waste components and mixtures of them under near optimal aerobic conditions. It was shown that substrates with high initial lignin contents or high initial HWSM contents were observed to have relatively low and high degradation extents, respectively. Two linear equations were derived that correlate degradation extent (as indicated by the volatile solids reduction) to initial lignin and initial HWSM contents separately. The lignin equation was compared to a similar equation previously developed for anaerobic environments by Chandler et al. (Predicting methane fermentation biodegradability. In: Biotechnology and Bioengineering Symposium No. 10 (1980) New York: John Wiley & Sons). With comparison to the Chandler formula, lignin was found to be less inhibitory to the overall substrate decomposition in aerobic environments compared to anaerobic ones. Cellulose loss contributed to a higher than 50% to the overall dry mass loss for all substrates studied. In addition, the cellulose to lignin (C/L) ratio appeared to be a relatively accurate compost maturity indicator, since it reduced to a value less than 0.5 for most substrates that had reached their degradation extent. 相似文献
89.
Dimitrios Melas Ioannis Kioutsioukis Ioannis C. Ziomas 《Journal of the Air & Waste Management Association (1995)》2013,63(4):495-501
ABSTRACT In this paper, an attempt is made for the 24-hr prediction of photochemical pollutant levels using a neural network model. For this purpose, a model is developed that relates peak pollutant concentrations to meteorological and emission variables and indexes. The analysis is based on measurements of O3 and NO2 from the city of Athens. The meteorological variables are selected to cover atmospheric processes that determine the fate of the airborne pollutants while special care is taken to ensure the availability of the required input data from routine observations or forecasts. The comparison between model predictions and actual observations shows a good agreement. In addition, a series of sensitivity tests is performed in order to evaluate the sensitivity of the model to the uncertainty in meteorological variables. Model forecasts are generally rather insensitive to small perturbations in most of the input meteorological data, while they are relatively more sensitive in changes in wind speed and direction. 相似文献
90.
Several simple models for the estimation of the half-life (t(1/2)) for the depletion of an organic chemical from a soil surface to air were examined. For moist surfaces, two models are proposed: the first requires knowledge of the soil/organic carbon partition coefficient (K(oc)) and the Henry's law constant (H) and the second the vapor pressure (P(s)) of the chemical involved. Due to uncertainties in the experimental K(oc) values those ones predicted by the group-contribution model of Meylan et al. [Environ. Sci. Technol. 26 (1992) 1560]-and proposed by the U.S. Environmental Protection Agency (EPA)-should be used. If reliable experimental P(s) values are not available, the first model is proposed, where in cases when H values are not available, predicted ones by the Bond-Contribution method of Meylan and Howard [Environ. Toxicol. Chem. 10 (1991) 1283]-and also proposed by EPA-can be used. In general, the agreement of the predicted t(1/2) values with the measured ones is within a factor of 3-5. Similar expressions, but with somewhat poorer results, are presented for dry field soils. In all cases, the obtained results represent a substantial improvement over those obtained with the currently used Dow method: t(1/2) = 1.58 x 10(-8)((K(oc) x S)/P(S)), where S is the solubility of the compound in water. 相似文献