Organochlorine pesticides and polychlorinated biphenyl residues in reared and wild Dicentrarchus labrax from the Mediterranean Sea (Sicily, Italy)

The aim of this research was to compare the levels of organochlorine pesticides and PCBs in samples of Dicentrarchus labrax living in the Straits of Messina with samples cultivated in cages in the Mediterranean Sea. Muscles and liver tissues sampled over the months, within the same year, were analyzed. The quantitative determination of the organochlorine compounds was performed by GC-ECD and confirmed with GC–MS. The results showed that the concentrations of DDTs in muscles and livers as such of reared sea bass were in the range 0.2–1.3 μg/kg and 9.6 –48.4 μg/kg, respectively. In wild fish the concentrations of DDTs were very much lower: 0.1 μg/kg in muscles, 5.1–9.0 μg/kg in livers. Total PCBs levels were higher in cultivated sea bass than in wild fish; the concentration ranges were 5.3–59.7 μg/kg and 74.4–267.4 μg/kg in muscle and liver of reared samples, respectively, and 1.1–1.5 μg/kg and 63.2–109.4 μg/kg in muscle and liver of wild samples, respectively.     

Autochthonous clams monitoring of Ganzirri Lake (Sicily)

Two autochthonous clams, Venerupis aurea laeta and Cerastoderma edule/glaucum, collected for a period of 1 year, from May 2007 to January 2008, were studied in the Cape Peloro lagoon. On the samples, it was evaluated the presence of pathogenic microorganisms and proteins, lipids and yield edible part were determined. It was evaluated the concentration of mineral elements (Cd, Cu, Mn, Se, Pb, Zn) and organic contaminants (∑DDT and PCBs). Salmonella is never present in any sample. Total and faecal coliform values have always been under law limits for alive bivalves mussels production and sale. Zn, Cu, Cd and Pb levels were found in clams where they are slightly lower too. Both species do not show significant changes for Mn and Se. DDT and PCBs traces were discovered in Ganzirri Lake’ samples, but in all observed cases, they were below law limits. As a result of all these observations, it is clear that, in recent years, the bivalve’s use of Ganzirri Lake does not denote toxicological risk to human health.     

Speciation of inorganic arsenic in coastal seawater from Ionian and Tyrrhenian Seas (Sicily, Italy) using derivative anodic stripping chronopotentiometry

The purpose of this paper was to use derivative anodic stripping chronopotentiometry (dASCP) as a sensitive and accurate technique, to determine the concentrations of dissolved As (III) and As (V) in coastal seawater samples from the Straits of Messina, the Ionian and the Tyrrhenian seas, and to investigate the relationship between the anthropogenic activities on the coastal areas and the concentration of dissolved inorganic arsenic in seawaters. The obtained data indicated that As (V) was the most abundant species, with concentration ranging from 26.7 to 307 nM, whereas As (III) levels were lower than 48 nM in all the samples. In particular, As (III) and As (V) levels significantly decreased from high to low anthropogenic activities zones (p < 0.00001, ANOVA), with the reference samples, from a wildlife reserve, showing the lowest values. Furthermore it was observed that human activities influenced inorganic arsenic speciation, since the zones that received high human input presented the highest As(V)/As (III) ratio.     

Local versus landscape spatial influence on biodiversity: a case study across five European industrialized areas

Land use change—mostly habitat loss and fragmentation—has been recognized as one of the major drivers of biodiversity loss worldwide. According to the habitat amount hypothesis, these phenomena are mostly driven by the habitat area effect. As a result, species richness is a function of both the extent of suitable habitats and their availability in the surrounding landscape, irrespective of the dimension and isolation of patches of suitable habitat. In this context, we tested how the extent of natural areas, selected as proxies of suitable habitats for biodiversity, influences species richness in highly anthropogenic landscapes. We defined five circular sampling areas of 5 km radius, including both natural reserves and anthropogenic land uses, centred in five major industrial sites in France, Italy and Germany. We monitored different biodiversity indicators for both terrestrial and aquatic ecosystems, including breeding birds, diurnal butterflies, grassland vegetation, odonata, amphibians, aquatic plants and benthic diatoms. We studied the response of the different indicators to the extent of natural land uses in the sampling area (local effect) and in the surrounding landscape (landscape effect), identified as a peripheral ring encircling the sampling area. Results showed a positive response of five out of seven biodiversity indicators, with aquatic plants and odonata responding positively to the local effect, while birds, vegetation and diatoms showed a positive response to the landscape effect. Diatoms also showed a significant combined response to both effects. We conclude that surrounding landscapes act as important biodiversity sources, increasing the local biodiversity in highly anthropogenic contexts.     

Evaluation of Continuous Performance Monitoring Techniques for Hazardous Waste Incinerators

This paper discusses monitoring the waste destruction efficiency of hazardous waste incinerators. The particular problem is to ensure that incinerators do not release, without detection, significant quantities of waste as a result of operating fluctuations or equipment degradation. To detect these conditions, continuous, automated, and real-time source monitoring is required. Detection of degraded performance by monitoring and measuring waste compounds directly is not presently possible on a continuous basis. An alternative is to use commercially available continuous monitors to measure combustion intermediates (e.g., CO or hydrocarbons) and thereby infer waste destruction efficiency. Required, however, is a correlation between the emission of intermediates and the emission of waste. In this paper, the response of a number of these continuous monitors is compared with waste destruction efficiency measurements from a laboratory scale, liquid-spray incinerator operated on fuel oil doped with model waste compounds: benzene, chlorobenzene, acrylonitrile, and chloroform. Total hydrocarbon and CH₄ measurements are found to vary with waste emission in a nearly linear manner; however, a substantial increase in CO emission occurs before a significant amount of waste is released. These results suggest that CO may serve as an indicator of the approach of waste release, while total hydrocarbons may provide an indicator of immediate waste release.     

Impact of woody encroachment on soil organic carbon and nitrogen in abandoned agricultural lands along a rainfall gradient in Italy

Land use changes represent one of the most important components of global environmental change and have a strong influence on carbon cycling. As a consequence of changes in economy during the last century, areas of marginal agriculture have been abandoned leading to secondary successions. The encroachment of woody plants into grasslands, pastures and croplands is generally thought to increase the carbon stored in these ecosystems even though there are evidences for a decrease in soil carbon stocks after land use change. In this paper, we investigate the effects of woody plant invasion on soil carbon and nitrogen stocks along a precipitation gradient (200?C2,500?mm) using original data from paired experiment in Italian Alps and Sicily and data from literature (Guo and Gifford Glob Change Biol 8(4):345?C360, 2002). We found a clear negative relationship (?0.05%?C?mm^?1) between changes in soil organic carbon and precipitation explaining 70% of the variation in soil C stocks after recolonization: dry sites gain carbon (up to +67%) while wet sites lose carbon (up to ?45%). In our data set, there seem to be two threshold values for soil carbon accumulation: the first one is 900?mm of mean annual rainfall, which separates the negative from the positive ratio values; the second one is 750?mm, which divides the positive values in two groups of sites. Most interestingly, this threshold of 750?mm corresponds exactly to a bioclimatic threshold: sites with <750?mm mean annual rainfall is classified as thermo-mediterranean sites, while the ones >750?mm are classified as mesomediterranean sites. This suggests that apart from rainfall also temperature values have an important influence on soil carbon accumulation after abandonment. Moreover, our results confirmed that the correlation between rainfall and trend in soil organic carbon may be related to nitrogen dynamics: carbon losses may occur only if there is a substantial decrease in soil nitrogen stock which occurs in wetter sites probably because of the higher leaching.     

Strategic environmental assessment of mining activities: A methodology for quantification of cumulative impacts on the air quality

Environmental impact assessments in Brazil have usually focused solely on project-related issues without considering the regional context. Although required by current environmental legislation, cumulative impact assessments have not been included in the overall environmental assessment of projects. However, in recent Strategic Environmental Assessment (SEA) studies of policies, plans, and programs undertaken on a voluntary basis in support of the decision-making process, this kind of assessment has been performed especially with respect to air quality. This paper presents the application of a methodology for the quantification of cumulative impacts on air quality under high uncertainty caused by various mining activities in a single region that is recommended for SEA studies. In this way, the methodology presented here is suitable for areas lacking detailed modeling information. The developed approach uses a relatively simplified mathematical model, lowering information gathering costs and requiring little processing time. The application of the methodology is illustrated in the case of a SEA of the Corumbá Mining and Industrial Complex Development Program. Despite the lack of data needed for a minimum characterization of conditions of the area surrounding the region modeled, the quantification of impact cumulativeness on air quality has played an important role in the context of the SEA.     

Multi-element accumulation near Rumex crispus roots under wetland and dryland conditions

Rumex crispus was grown under wet and dry conditions in two-chamber columns such that the roots were confined to one chamber by a 21 μm nylon mesh, thus creating a soil-root interface (‘rhizoplane’). Element concentrations at 3 mm intervals below the ‘rhizoplane’ were measured. The hypothesis was that metals accumulate near plant roots more under wetland than dryland conditions. Patterns in element distribution were different between the treatments. Under dryland conditions Al, Ba, Cu, Cr, Fe, K, La, Mg, Na, Sr, V, Y and Zn accumulated in soil closest to the roots, above the ‘rhizoplane’ only. Under wetland conditions Al, Fe, Cr, K, V and Zn accumulated above as well as 3 mm below the ‘rhizoplane’ whereas La, Sr and Y accumulated 3 mm below the ‘rhizoplane’ only. Plants on average produced 1.5 times more biomass and element uptake was 2.5 times greater under wetland compared to dryland conditions.     

Kinetics of particulate organic matter removal as a response to bioflocculation in aerobic biofilm reactors.

Recent research has identified that the major fraction of chemical oxygen demand in domestic wastewaters is in particulate form. The research presented herein develops the kinetics of particle removal as a response to bioflocculation at the surface of aerobic biofilms. This study focuses on the removal of particles that are maintained in aqueous suspension after 30 minutes of gravity settling. It is helpful to consider the particulate organics removal process in biofilms as the sum of four steps, namely (1) external transport of the particles to the biofilm surface, (2) bioflocculation, (3) organic particulate hydrolysis, and (4) diffusion and reaction of the solubilized organics by the bacterial cells comprising the biofilm. Organic (native corn starch) and inorganic particle (Min-U-Sil 10 [U.S. Silica Company, Berkeley Springs, West Virginia]) suspensions, with micronutrients, were continuously fed to a rotating disc biofilm reactor to verify a first-order kinetic expression that has been used to describe bioflocculation and to demonstrate that bioflocculation is the primary particle removal mechanism. Extracellular polymeric substances were extracted and quantified to describe the role they play in the bioflocculation process.     

Temporal changes in soil partitioning and bioaccessibility of arsenic, chromium, and lead

The hazard imposed by trace element contaminants within soils is dependent on their ability to migrate into water systems and their availability for biological uptake. The degree to which a contaminant may dissociate from soil solids and become available to a target organism (i.e., bioaccessibility) is therefore a determining risk factor. We used a physiologically based extraction test (PBET) to estimate the bioaccessible fraction of arsenic-, chromium-, and lead-amended soil. We investigated soils from the A and B horizons of the Melton Valley series, obtained from Oak Ridge National Laboratory site, to address temporal changes in bioaccessibility. Additionally, common extractions that seek to define reactive pools of metals were employed and their correlation to PBET levels evaluated. With the exception of Pb amended to the A horizon, all other treatments exhibited an exponential decrease in bioaccessibility with incubation time. The bioaccessible fraction was less than 0.2 mg kg(-1) within 30 d of incubation for As and Cr in the A horizon and for As and Pb within the B horizon; Cr in the B horizon declined to nearly 0.3 mg kg(-1) within 100 d of aging. The exchangeable fraction declined with incubation period and, with the exception of Pb, was highly correlated with the decline in bioaccessibility. Our results demonstrate limited bioaccessibility in all but one case and the need to address both short-term temporal changes and, most importantly, the soil physiochemical properties. They further reveal the importance of incubation time on the reactivity of such trace elements.