全文获取类型
收费全文 | 2239篇 |
免费 | 17篇 |
国内免费 | 91篇 |
专业分类
安全科学 | 106篇 |
废物处理 | 210篇 |
环保管理 | 280篇 |
综合类 | 293篇 |
基础理论 | 392篇 |
环境理论 | 1篇 |
污染及防治 | 783篇 |
评价与监测 | 193篇 |
社会与环境 | 74篇 |
灾害及防治 | 15篇 |
出版年
2023年 | 11篇 |
2022年 | 33篇 |
2021年 | 36篇 |
2020年 | 12篇 |
2019年 | 41篇 |
2018年 | 70篇 |
2017年 | 58篇 |
2016年 | 78篇 |
2015年 | 54篇 |
2014年 | 67篇 |
2013年 | 178篇 |
2012年 | 123篇 |
2011年 | 143篇 |
2010年 | 96篇 |
2009年 | 129篇 |
2008年 | 134篇 |
2007年 | 144篇 |
2006年 | 128篇 |
2005年 | 114篇 |
2004年 | 105篇 |
2003年 | 97篇 |
2002年 | 88篇 |
2001年 | 62篇 |
2000年 | 35篇 |
1999年 | 24篇 |
1998年 | 20篇 |
1997年 | 23篇 |
1996年 | 16篇 |
1995年 | 18篇 |
1994年 | 18篇 |
1993年 | 19篇 |
1992年 | 10篇 |
1991年 | 19篇 |
1990年 | 10篇 |
1989年 | 9篇 |
1988年 | 10篇 |
1986年 | 7篇 |
1985年 | 8篇 |
1984年 | 7篇 |
1983年 | 7篇 |
1982年 | 10篇 |
1981年 | 10篇 |
1980年 | 9篇 |
1978年 | 6篇 |
1976年 | 5篇 |
1974年 | 4篇 |
1973年 | 5篇 |
1972年 | 6篇 |
1971年 | 6篇 |
1969年 | 5篇 |
排序方式: 共有2347条查询结果,搜索用时 59 毫秒
831.
Jong-Beom Seo Soo-Bin Jeon Je-Young Kim Gang-Woo Lee Jong-Hyeon Jung Kwang-Joong Oh 《环境科学学报(英文版)》2012,24(3):494-498
Aqueous ammonia (NH3) solution can be used as an alternative absorption for the control of CO2 emitted from flue gases due to its high absorption capacity, fast absorption rate and low corrosion problem. The emission of CO2 from iron and steel plants requires much attention, as they are higher than those emitted from power plants at a single point source. In the present work, low concentration ammonia liquor, 9 wt.%, was used with various additives to obtain the kinetic properties using the blast furnace gas model. Although a solution with a high ammonia concentration enables high CO2 absorption efficiency, ammonium ions are lost as ammonia vapor, resulting in reduced CO2 absorption due to the lower concentration of the ammonia absorbent. To decrease the vaporization of ammonia, ethylene glycol, glycerol and glycine, which contain more than one hydroxyl radical, were chosen. The experiments were conducted at 313 K similar to the CO2 absorption conditions for the blast furnace gas model. 相似文献
832.
Amy Hinsley Anita Kar Yan Wan David Garshelis Michael Hoffmann Sifan Hu Tien Ming Lee Keila Meginnis Brendan Moyle Yingjie Qiu Xiangdong Ruan E. J. Milner-Gulland 《Conservation biology》2022,36(3):e13895
An important rationale for legally farmed and synthetic wildlife products is that they reduce illegal, wild-sourced trade by supplying markets with sustainable alternatives. For this to work, more established illegal-product consumers must switch to legal alternatives than new legal-product consumers switch to illegal wild products. Despite the widespread debate on the magnitude and direction of switching, studies among actual consumers are lacking. We used an anonymous online survey of 1421 traditional Chinese medicine consumers in China to investigate switching among legal farmed, synthetic, and illegal wild bear bile. We examined the past consumption behavior, applied a discrete choice experiment framed within worsening hypothetical disease scenarios, and used latent class models to investigate groups with shared preferences. Bear bile consumers (86% respondents) were wealthier, more likely to have family who consumed bile, and less knowledgeable about bile treatments than nonconsumers. Consumer preferences were heterogenous, but most consumer preferences switched between bile types as disease worsened. We identified five distinct latent classes within our sample: law-abiding consumers (34% respondents), who prefer legal products and were unlikely to switch; two all-natural consumer groups (53%), who dislike synthetics but may switch between farmed and wild; and two nonconsumer groups (12%), who prefer not to buy bile. People with past experience of bile consumption had different preferences than those without. Willingness to switch to wild products was related to believing they were legal, although the likelihood of switching was mediated by preferences for cheaper products sold in legal, familiar places. We found that consumers of wild bile may switch to legal alternatives, given the availability of a range of products, whereas legal-product consumers may switch to illegal products if the barriers to doing so are small. Understanding preferences that promote or impede switching should be a key consideration when attempting to predict consumer behavior in complex wildlife markets. 相似文献
833.
Many hospitals or health care facilities have faced financial difficulties and thus they have attempted to find cost-effective treatment and disposal methods of their regulated medical wastes (RMWs). This study investigated generation volume and sources, composition, and treatment and disposal methods for RMWs obtained from three out of the five typical city hospitals in Massachusetts for which we could obtain relevant data on medical waste. Also, this study compared the generation patterns and amounts of RMWs between the hospital and the medical school. The yearly operational treatment and disposal costs of RMWs based on different treatment and disposal methods were analyzed for one hospital. The most cost-effective option of four different treatment and disposal options studied was to combine on-site incineration and microwave technologies. Finally, this study identified measures for the effective waste characterization methods for the reduction of treatment and disposal costs of RMWs. By careful exclusion of non-RMW from RMW waste streams, hospitals can reduce the RMW volume that requires special treatment and reduce disposal costs. 相似文献
834.
Structural investigation of catalyst deactivation of Pt/SDB for catalytic oxidation of VOC-containing wastewater 总被引:2,自引:0,他引:2
The stability of styrene-divinyl benzene copolymer (SDB)-supported Pt (Pt/SDB) catalysts for destruction of volatile-organic-compound (VOC) in wastewater was examined. The test reaction was wet oxidation of water-containing aliphatic alcohol and formaldehyde at 140 degrees C and 90 psig for 40 h. The catalytic performance tests indicated that activity of the Pt/SDB catalysts could be maintained for VOC concentration of 3 wt.%, whereas the catalysts deactivated rapidly for 10 wt.% VOC containing wastewater. In order to investigate the nature of catalyst deactivation, extended X-ray absorption fine structure (EXAFS) and X-ray absorption near edge (XANES) spectroscopy were used to characterize the fresh and used catalysts. After the reaction, there is no oxidation of Pt clusters observed in EXAFS and XANES spectroscopy suggesting that the oxidation reaction takes places via the adsorbed oxygen. The spectroscopy results further indicated that deactivation of the catalysts were mainly caused by the increase of Pd particle size. After the reaction, the Pt-Pt coordination number has no significant change for the 3 wt.% wastewater whereas increase from 5.6 to 6.2 for 10 wt.% wastewater. Combined with the fact that the catalysts fractured during the reactions, we suggested that Pt agglomeration was mainly caused by thermal migration of the metal clusters. 相似文献
835.
Edward H Owens Gary A Sergy Chantal C Guénette Roger C Prince Kenneth Lee 《Spill Science & Technology Bulletin》2003,8(3):257-272
The Svalbard Shoreline Field Trials quantified the effectiveness of sediment relocation, mixing, bioremediation, bioremediation combined with mixing, and natural attenuation as options for the in situ treatment of oiled mixed-sediment (sand and pebble) shorelines. These treatments were applied to oiled plots located in the upper beach at three experimental sites, each with different sediment character and wave-energy exposure. Systematic monitoring was carried out over a 400-day period to quantify oil removal and to document changes in the physical character of the beach, oil penetration, oil loading, movements of oil to the subtidal environment, biodegradation, toxicity, and to validate oil-mineral aggregate formation.The results of the monitoring confirmed that sediment relocation significantly accelerated the rate of oil removal and reduced oil persistence where oil was stranded on the beach face above the level of normal wave activity. Where the stranded oil was in the zone of wave action, sediment relocation accelerated the short-term (weeks) rate of oil loss from the intertidal sediments.Oil removal rates on a beach treated by mechanical mixing or tilling were not significantly higher than those associated with natural recovery. However there is evidence that mixing/tilling may have enhanced microbial activity for a limited period by increasing the permeability of the sediment.Changes in the chemical composition of the oil demonstrated that biodegradation was significant in this arctic environment and a bioremediation treatment protocol based on nutrient enrichment effectively doubled the rate of biodegradation. However, on an operational scale, the success of this treatment strategy was limited as physical processes were more important in causing oil loss from the beaches than biodegradation, even where this oil loss was stimulated by the bioremediation protocols. 相似文献
836.
Natural radionuclides, such as 210Po and 210Pb were measured in the water samples collected from six stations at Kuala Selangor, Malaysia. Results for 210Po and 210Pb in dissolved and particulate phases have showed the difference in distribution and chemical behavior. The fluctuation activities of 210Po and 210Pb depend on wave action, geology and degree of fresh water input occurring at study areas and probably due to different sampling dates. The distribution coefficient, Kd, values of 210Po and 210Pb ranged from 2.0 × 103 l g−1 to 265.15 × 105 l g−1, and from 3.0 × 103 l g−1 to 558.16 × 105 l g−1, respectively. High Kd values of 210Po and 210Pb indicated that a strong adsorption of 210Po and 210Pb onto suspended particles, and the sinking of both nuclides on the seabed at study locations were controlled by the characteristics of suspended particles. 相似文献
837.
K.E. Lee L.B. Barber H.L. Schoenfuss 《Journal of the American Water Resources Association》2014,50(2):401-419
Alkylphenolic chemicals (APCs) and hormones were measured six times from February through October 2007 in three Minnesota streams receiving wastewater to identify spatial and temporal patterns in concentrations and in estrogen equivalency. Fish were collected once during the study to evaluate endpoints indicative of endocrine disruption. The most commonly detected APCs were 4‐tert‐octylphenol and 4‐nonylphenol and the most commonly detected hormones were estrone and androstenedione. Chemical concentrations were greatest for nonylphenol ethoxycarboxylates (NPECs) (5,000‐140,000 ng/l), followed by 4‐nonlylphenol and 4‐nonylphenolethoxylates (50‐880 ng/l), 4‐tert‐octylphenol and 4‐tert‐octylphenolethoxylates with concentrations as great as 130 ng/l, and hormones (0.1‐54 ng/l). Patterns in chemicals and estrogen equivalency indicated that wastewater effluent is a pathway of APCs and hormones to downstream locations in this study. However, upstream contributions can be equally or more important indicating alternative sources. This study indicates that aquatic organisms experience both spatially and temporally variable exposures in the number of compounds, total concentrations, and estrogenicity. This variability was evident in fish collected from the three rivers as no clear upstream to downstream pattern of endocrine disruption endpoints emerged. 相似文献
838.
Sulphamethazine in poultry manure changes carbon and nitrogen mineralisation in soils 总被引:1,自引:0,他引:1
Yasser M. Awad Avanthi Deshani Igalavithana Young Han Lee Yeon-Kyu Sonn Adel R. A. Usman 《Chemistry and Ecology》2016,32(10):899-918
Antibiotics are newly emerging organic pollutants in manure, soil, vegetables and water. Animal manure application might be leading to the accumulation of antibiotics in the farmland. However, the effect of sulphamethazine (SMZ) on the soil microbial community was scarcely investigated. This study was aimed to evaluate the impact of SMZ on poultry manure, on the structure and function of microbial community, carbon mineralisation, and changes in nitrogen forms in soil via an incubation experiment lasting 56?d. The treatments consisted of poultry manure at 1% wt (PM), PM containing 20?mg?kg?1 SMZ (PM?+?20SMZ) and PM containing 100?mg?kg?1 SMZ (PM?+?100SMZ), along with the untreated soil (control). Solid phase extraction was performed to measure the SMZ concentration in soils using high-pressure liquid chromatography. The cumulative CO2-C was increased in all treated soils over the incubation period compared to the control. The PM?+?100SMZ had the highest increase in cumulative CO2-C from the soil at 56?d of incubation. The treatment of PM?+?20SMZ showed a short-term decrease in nitrification rate in the soils at 1?d by altering the microbial community composition with 17% dissimilarity and decreasing the abundance of bacteria compared to PM-treated soil. The PM?+?100SMZ increased C mineralisation in the soil. 相似文献
839.
840.
由于毒性评估项目很难与日渐增长的需要测试的污染物保持同步,所以较难将关注点集中在影响水生生态系统的最为生物相关的污染物上。由于评估潜在毒性污染物所造成的生物影响已被证明是有效的,内生性代谢物的研究(代谢组学)对于剔除那些较低可能造成生物影响的污染物或许有一定帮助,从而找出生物重要性最高的污染物。本研究在北美五大湖流域的18个地点针对置于笼中的黑头软口鲦(Pimephales promelas)进行实验。我们测定了水体温度和水样中的污染物浓度(目标污染物132种,检出86种),并使用1H-NMR谱测量了肝极性提取物中的内生性代谢物。利用偏最小二乘法回归来比对内生性代谢物的相对丰度与污染物浓度和环境温度。结果表明内生性极性代谢物的指标与最多49种污染物存在共同变化。因此我们认为至多52%的检出污染物与内生性代谢物变化的共同变化不显著,表明这些污染物很可能不会在这些地点造成可以检测到的影响。这是通过缩短对于实验地点有着潜在影响的污染物列表从而扫描出检出污染物生物相关性的第一步。类似的信息有助于风险评估者区分不同污染物的重要性并将重点毒性测试放在最为生物相关的污染物上。
精选自Nicol Janecko, Lucie Pokludova, Jana Blahova, Zdenka Svobodova, Ivan Literak. Linking field-based metabolomics and chemical analyses to prioritize contaminants of emerging concern in the Great Lakes basin. Environmental Toxicology and Chemistry: Volume 35, Issue 10, pages 2493–2502, October 2016.
DOI: 10.1002/etc.3409
详情请见http://onlinelibrary.wiley.com/doi/10.1002/etc.3409/full 相似文献