历史时期黄河流域城市空间格局演变与影响因素

研究历史时期黄河流域城市的空间格局演变,能够更好地理解人居环境的特点和发展脉络,对当今黄河流域生态保护、城镇发展有重要的现实价值。采用哈佛大学CHGIS数据库中城市时间序列数据,以及历史人口数据、流域和高程数据,通过实证分析,梳理黄河流域城市时空格局演变过程与影响因素。研究发现：（1）城市数量变化可划分为五个阶段。（2）一级延续稳定区,以今安阳为中心的河南北部城市高密集区和以今西安为中心的关中城市高密集区;以今济南、太原、洛阳为中心的次高密集区。二级延续稳定区分为五条重要的城市带,即渭河城市带、汾河城市带、鲁中山地北麓城市带、太行山东麓城市带及运河城市带。（3）城市重心迁移的平均距离为32 km,人口重心迁移的平均距离为95.78 km,城市和人口的分布有着较密切的联系。（4）气温、降水、高程、与河流的距离、黄河下游河道的变迁等自然因素,以及战争、都城转移和人工运河等人文因素共同影响了历史时期黄河流域城市的时空格局。     

Deactivation of Cu-SAPO-34 by urea-related deposits at low temperatures and the regeneration

Selective catalytic reduction(SCR) with urea catalyzed by Cu-SAPO-34 is an effective method to eliminate NO_x from diesel exhaust. However, urea-related deposits may form during cold-start and urban driving due to low exhaust temperatures. The activity of CuSAPO-34 at 175°C is significantly degraded by urea exposure, and 300°C is required for regeneration. Through in-situ diffuse reflectance infrared Fourier transform spectroscopy(DRIFTS) and temperature-programmed hydrolysis studies, the dominant stable deposit at 175°C is identified as biuret, which can be eliminated at 300°C. The urea-derived deactivation and regeneration mechanisms of Cu-SAPO-34 were compared with those of anatase-supported catalysts.     

Improved activity and durability of Rh-based three-way catalyst under diverse aging atmospheres by ZrO2 support

The catalytic activity and durability of Rh/ZrO_2 catalyst were investigated compared with Rh/Al_2O_3 catalyst under diverse aging atmospheres, including lean, rich and lean–rich cyclic aging atmospheres, to simulate the real working conditions of three-way catalyst.Oxidation states and microstructures of rhodium species were investigated to correlate with the catalytic performance of the catalysts. The catalytic performance and durability of the Rh catalyst under diverse aging atmospheres were drastically enhanced by ZrO_2 support. ZrO_2 support was confirmed to be able to effectively inhibit rhodium sintering even under diverse aging conditions. It can also successfully keep Rh species in an active low-valence state on the surface of the catalyst. The superiority of ZrO_2 support compared to Al_2O_3 was verified by the Rh-based monolith catalyst.     

北方深水河流岸边带底栖动物采集方法比较研究

深水河流底栖动物的采集比较复杂,采集结果与客观实际往往存在较大的差异,通过2012年-2015年对黑龙江、松花江和乌苏里江等11个断面15个点位的调查、监测,取得81组有效数据,利用统计学方法总结、研究,发现同一采样点不同方法之间的物种数、群落组成和评价结果均存在显著的差异,建议深水河流在应用底栖动物开展水生态评价时,应结合采样点的实际情况,尽量采用多种方法进行底栖动物的采集,合并统计的数据更能准确的代表采集点位的客观情况,是客观、准确评价水生态环境状况的前提.     

陕西潼关冶金污染土壤的修复评价及应用潜力

为了科学评估客土法、石灰和磷酸钙作为重金属钝化剂的原位稳定化修复技术在实际重金属污染土壤改良中的应用潜力,以潼关县安乐乡土壤重金属污染修复示范工程为例,从"三小"冶金土壤污染现状、工程修复技术的筛选、稳定化的修复效果以及修复后土壤农业生产安全性评价等角度进行了系统分析.结果表明"三小"冶炼行为对于周边土壤造成了严重的污染,主要污染物为Cd、Pb和Hg,矿渣是主要的污染源.采用潜在生态危害指数法进行评价,该区域潜在生态危害指数(RI)范围为668~10 969,具有很强的生态危害.通过对重度污染和轻度污染土壤分别采用客土法及原位固化的修复方法,土壤中重金属的总量以及有效态含量均有了显著的下降.除Cd外,土壤中重金属的总量均低于土壤二级标准中的限值.尽管土壤稳定化修复取得了一定的效果,但部分农作物中重金属的累积量高于国家食品安全标准中规定的限值,继续种植存在一定的风险.因此,在重金属污染修复后的土壤上不建议立刻进行粮食生产,应改变原有生产模式同时持续监测,在确保粮食安全后再进行生产.     

关于世行贷款农业灌溉项目环境影响评价问题的讨论

农业灌溉工程建设是我国第十二个五年规划纲要中提出的全面加强农田水利建设工作的重要组成部分。随着越来越多农业灌溉项目的兴建及我国环境影响评价制度的发展,农业灌溉项目的环境影响评价也在不断发展和完善中。本文根据世行贷款项目——中国四川武都农业灌溉项目环境影响评价实践和工作经验,分析总结了世界银行及我国在农业灌溉项目环境影响评价工作方面的特点和要求,其中世界银行在有些方面,如评价等级、公众参与等与国内环评要求基本一致,而有些方面,如回顾性评价、替代方案分析、累积性影响分析、环境管理计划、移民安置行动计划、病虫害管理计划等在国内环境影响评价中尚未引起足够的关注或与世界银行要求存在较大差异,值得我国环评工作参考和借鉴。     

生物质秸秆成型燃料的制备、应用与市场

介绍了国内外生物质能源技术的应用及生物质燃料的研发制备情况,分析了目前生物质燃料制备技术、资源化利用的现状以及存在的问题,针对符合中国国情的生物质(秸秆)成型燃料生产技术及市场需求进行了分析探讨。     

Withdrawal and restraining factors in teachers' turnover intentions

This study examines how work-related withdrawal-inducing and restraining factors affect the intention to leave work of male and female teachers. It is assumed that while these intentions are induced by the employee's affective reaction to the work environment, they are also restrained by those personal gains and advantages provided by the present job that cannot be transferred to another. A path analysis performed on data collected from 239 high school teachers in Israel indicates some differences between the male and female groups. Some restraining effects on the intentions to resign were found among both, but the prevailing assumption that affective work reactions mediate between work environment and the intent to leave, was found among male teachers only. This and other observed differences in the predictors of male and female teachers' intentions to resign question the generality of prevailing assumptions of the psychological process of withdrawal. The need for gender adjustments in withdrawal models is proposed.     

南通龙王桥河沉积物中酸挥发性硫化物的研究

本研究对南通通甲河支流龙王桥河的表层沉积物中酸挥发性硫化物(AVS)随时间的变化情况,AVS与同步浸提重金属(SEM)的关系,以及AVS与有机质(OM)的关系进行了一个月的监测。结果表明:①龙王桥河表层沉积物中AVS的平均含量为1700mg/kg,远高于其他河段,上覆水中AVS的含量达到1.0mg/L,污染严重;②归一法算得SEM/AVS1,沉积物中重金属主要以硫化物形式存在;③沉积物中OM含量与AVS有相关性,OM较高时AVS的含量也较高。     

Effcient degradation of lube oil by a mixed bacterial consortium

A laboratory study was performed to assess the biodegradation of lube oil in bio-reactor with 304# stainless steel as a biofilm carrier. Among 164 oil degrading bacterial cultures isolated from oil contaminated soil samples, Commaonas acidovorans Px1, Bacillus sp. Px2, Pseudomonas sp. Px3 were selected to prepare a mixed consortium for the study based on the e ciency of lube oil utilization. The percentage of oil degraded by the mixed bacterial consortium decreased slightly from 99% to 97.2% as the concentration of lube oil was increased from 2000 to 10,000 mg/L. The degradation of TDOC (total dissolved organic carbon) showed a similar tendency compared with lube oil removal, which indicated that the intermediates in degradation process hardly accumulated. Selected mixed bacterial consortium showed their edge compared to activated sludge. Scanning electron microscopy (SEM) photos showed that biofilms on stainless steel were robust and with a dimensional framework constructed by EPS (extracellular polymeric substances), which could promote the biodegradation of hydrocarbons. The increase of biofilm followed first-order kinetics with rate of 0.216 g glucose/(cm2 day) in logarithm phase. With analysis of Fourier transform infrared spectroscopy (FT-IR) and gas chromatography-mass spectrometry (GC-MS) combined with removal of lube oil and TDOC, mixed bacterial consortium could degrade benzene and its derivatives, aromatic ring organic matters with a percentage over 97%.