Integrating contributing areas and indexing phosphorus loss from agricultural watersheds

Most states in the USA have adopted P Indexing to guide P-based management of agricultural fields by identifying the relative risk of P loss at farm and watershed scales. To a large extent, this risk is based on hydrologic principles that frequently occurring storms can initiate surface runoff from fields. Once initiated, this hydrological pathway has a high potential to transport P to the stream. In regions where hydrologically active areas of watersheds vary in time and space, surface runoff generation by "saturation excess" has been linked to distance from stream, with larger events resulting in larger contributing distances. Thus, storm-return period and P loss from a 39.5-ha mixed-land-use watershed in Pennsylvania was evaluated to relate return-period thresholds and distances contributing P to streams. Of 248 storm flows between 1997 and 2006, 93% had a return period of 1 yr, contributing 47% of total P (TP) export, while the largest two storms (10-yr return period) accounted for 23% of TP export. Contributing distance thresholds for the watershed were determined (50-150 m) for a range of storm-return periods (1-10 yr) from hydrograph analysis. By modifying storm-return period thresholds in the P Index and thereby contributing distance, it is possible to account for greater risk of P loss during large storms. For instance, increasing return period threshold from 1 (current P indices) to 5 yr, which accounted for 67% of TP export, increased the P-management restricted area from 20 to 58% of the watershed. An increase in impacted area relative to a decreased risk of P loss creates a management-policy dilemma that cannot be ignored.     

Contribution of hydrolysis in the abiotic attenuation of RDX and HMX in coastal waters

Sinking of military ships, dumping of munitions during the two World Wars, and military training have resulted in the undersea deposition of numerous unexploded ordnances (UXOs). Leaching of energetic compounds such as hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) and octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) from these UXOs may cause adverse ecological effects so that the long-term fate of these chemicals in the sea should be known. The present study assesses the contribution of alkaline hydrolysis into the natural attenuation of RDX and HMX in coastal waters. Alkaline hydrolysis rates were shown to be unaffected by the presence of sodium chloride, the most common component in marine waters. Kinetic parameters (E(a), ln A, k(2)) quantified for the alkaline hydrolysis of RDX and HMX in deionized water (30-50 degrees C, pH 10-12) agreed relatively well with abiotic degradation rates determined in sterilized natural coastal waters (50 and 60 degrees C, variable salinity) even if the latter were generally slightly faster than the former. Furthermore, similar products (HCHO, NO(2)(-), O(2)NNHCH(2)NHCHO) were obtained on alkaline hydrolysis in deionized water and abiotic degradation in coastal waters. These two findings suggested that degradation of nitramines in sterilized natural coastal waters, away from light, was mainly governed by alkaline hydrolysis. Kinetic calculations using the present parameters showed that alkaline hydrolysis of RDX and HMX in marine waters at 10 degrees C would respectively take 112 +/- 10 and 2408 +/- 217 yr to be completed (99.0%). We concluded that under natural conditions hydrolysis should not contribute significantly to the natural attenuation of HMX in coastal waters whereas it could play an active role in the natural attenuation of RDX.     

Investigation of the Curve Number Method For Surface Runoff Estimation In Tropical Regions

This study tests the applicability of the curve number (CN) method within the Soil and Water Assessment Tool (SWAT) to estimate surface runoff at the watershed scale in tropical regions. To do this, surface runoff simulated using the CN method was compared with observed runoff in numerous rainfall‐runoff events in three small tropical watersheds located in the Upper Blue Nile basin, Ethiopia. The CN method generally performed well in simulating surface runoff in the studied watersheds (Nash‐Sutcliff efficiency [NSE] > 0.7; percent bias [PBIAS] < 32%). Moreover, there was no difference in the performance of the CN method in simulating surface runoff under low and high antecedent rainfall (PBIAS for both antecedent conditions: ~30%; modified NSE: ~0.4). It was also found that the method accurately estimated surface runoff at high rainfall intensity (e.g., PBIAS < 15%); however, at low rainfall intensity, the CN method repeatedly underestimated surface runoff (e.g., PBIAS > 60%). This was possibly due to low infiltrability and valley bottom saturated areas typical of many tropical soils, indicating that there is scope for further improvements in the parameterization/representation of tropical soils in the CN method for runoff estimation, to capture low rainfall‐intensity events. In this study the retention parameter was linked to the soil moisture content, which seems to be an appropriate approach to account for antecedent wetness conditions in the tropics.     

Cadmium concentrations in tissues of willow ptarmigan (Lagopus lagopus) and rock ptarmigan (Lagopus muta) in Nunavik, Northern Québec

Willow and rock ptarmigan were obtained from Northern Québec. Willow ptarmigan were found to have mean cadmium concentrations of 179.7 microg/g (dw) in the kidneys and 25.8 microg/g (dw) in the liver; these levels were three times higher than those found in the rock ptarmigan. The cadmium levels in the ptarmigan were below the threshold above which adverse effects can be observed in birds. The difference between the two ptarmigan species in cadmium content is explained by the diet. A comparison of their diet showed that willow, which stores cadmium, is an important food resource for willow ptarmigan but not for rock ptarmigan. Because there is limited information available on the consumption of ptarmigan kidneys and liver by the Inuit, and the fact that this is a traditional way of life and provides nutritional benefits to the Inuit population, no consumption guidelines are proposed.     

Low dose effects and non-monotonic dose responses for endocrine active chemicals: Science to practice workshop: Workshop summary

A workshop was held in Berlin September 12–14th 2012 to assess the state of the science of the data supporting low dose effects and non-monotonic dose responses (“low dose hypothesis”) for chemicals with endocrine activity (endocrine disrupting chemicals or EDCs). This workshop consisted of lectures to present the current state of the science of EDC action and also the risk assessment process. These lectures were followed by breakout sessions to integrate scientists from various backgrounds to discuss in an open and unbiased manner the data supporting the “low dose hypothesis”. While no consensus was reached the robust discussions were helpful to inform both basic scientists and risk assessors on all the issues. There were a number of important ideas developed to help continue the discussion and improve communication over the next few years.     

Four priorities for new links between conservation science and accounting research

Article impact statement: New collaborations with accounting research can improve conservation impact of ecosystem-based information systems.     

Moving beyond “mitigation and adaptation”: examining climate change responses in New Zealand

Despite the apparent failure of international negotiations and renewed criticism of the accuracy of climate science, responses to climate change continue in households, cities, fields, and meeting rooms. Notions of “doing something about”, or “taking action on” or “mitigating and adapting” to climate change inform practices of carbon trading, restoring native forests, constructing wind turbines, insulating houses, using energy efficient light bulbs, and lobbying politicians for more or less of these actions. These expressions of agency in relation to climate change provide the focus of our enquiry. We found that relationships or social networks linked through local government are building capabilities to respond to climate change. However, the framework of “mitigation–adaptation” will need to be supplemented by a more diverse suite of mental models for making sense of climate change. Use of appropriate languages, cultural reference points, and metaphors embedded in diverse histories of climates and change will assist actors in their networked climate change responses.