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101.
Identification of sources of elevated concentrations of polycyclic aromatic hydrocarbons in an industrial area in Tianjin, China 总被引:2,自引:0,他引:2
Wentao Jiao Yonglong Lu Jing Li Jingyi Han Tieyu Wang Wei Luo Yajuan Shi Guang Wang 《Environmental monitoring and assessment》2009,158(1-4):581-592
The concentrations of 16 polycyclic aromatic hydrocarbons (PAHs) were determined by gas chromatography equipped with a mass spectrometry detector in 105 topsoil samples from an industrial area around Bohai Bay, Tianjin in the North of China. Results demonstrated that concentrations of PAHs in 104 soil samples from this area ranged from 68.7 to 5,590 ng g???1 dry weight with a mean of ∑16PAHs 814 ± 813 ng g???1, which suggests that there exists mid to high levels of PAH contamination. The concentration of ∑16PAHs in one soil sample from Tianjin Port was exceptionally high (48,700 ng g???1). Ninety-three of the 105 soil samples were considered to be contaminated with PAHs (>200 ng g???1), and 25 were heavily polluted (>1,000 ng g???1). The sites with high PAHs concentration are mainly distributed around chemical industry parks and near highways. Two low molecular weight PAHs, naphthalene and phenanthrene, were the dominant components in the soil samples, which accounted for 22.1% and 10.7% of the ∑16PAHs concentration, respectively. According to the observed molecular indices, house heating in winter, straw stalk combustion in open areas after harvest, and petroleum input were common sources of PAHs in this area, while factory discharge and vehicle exhaust were the major sources around chemical industrial parks and near highways. Biological processes were probably another main source of low molecular weight PAHs. 相似文献
102.
103.
Luo J Weber FA Cirpka OA Wu WM Nyman JL Carley J Jardine PM Criddle CS Kitanidis PK 《Journal of contaminant hydrology》2007,92(1-2):129-148
We present a travel-time based reactive transport model to simulate an in-situ bioremediation experiment for demonstrating enhanced bioreduction of uranium(VI). The model considers aquatic equilibrium chemistry of uranium and other groundwater constituents, uranium sorption and precipitation, and the microbial reduction of nitrate, sulfate and U(VI). Kinetic sorption/desorption of U(VI) is characterized by mass transfer between stagnant micro-pores and mobile flow zones. The model describes the succession of terminal electron accepting processes and the growth and decay of sulfate-reducing bacteria, concurrent with the enzymatic reduction of aqueous U(VI) species. The effective U(VI) reduction rate and sorption site distributions are determined by fitting the model simulation to an in-situ experiment at Oak Ridge, TN. Results show that (1) the presence of nitrate inhibits U(VI) reduction at the site; (2) the fitted effective rate of in-situ U(VI) reduction is much smaller than the values reported for laboratory experiments; (3) U(VI) sorption/desorption, which affects U(VI) bioavailability at the site, is strongly controlled by kinetics; (4) both pH and bicarbonate concentration significantly influence the sorption/desorption of U(VI), which therefore cannot be characterized by empirical isotherms; and (5) calcium-uranyl-carbonate complexes significantly influence the model performance of U(VI) reduction. 相似文献
104.
安全生产风险预警探讨 总被引:1,自引:0,他引:1
以实现风险预警理论及技术在实际生产过程中的应用为目的,通过在油气初加工企业建立并实施安全生产风险预警的实践,讨论了安全生产风险预警机制的具体建立及实施过程,进一步探讨了风险辨识及评价的模式和方法及风险预警流程. 相似文献
105.
亲水性多孔载体在流化床中的生物膜形成过程分析 总被引:2,自引:0,他引:2
采用实验制备的一种新型亲水性多孔聚合物作为流化床反应器中生物膜附着生长的载体,实现流态化水力条件下的生物挂膜过程.在3个结构尺寸相同的流化床反应器中考察了接种污泥浓度、进水有机负荷及载体粒径对亲水性多孔载体生物挂膜量的影响,试验结果表明,接种污泥浓度为30 g VSS/L、进水TOC值为350 mg/L、载体粒径为5~8 mm时载体表面的附着生物量最大,反应器运行12 d的载体附着生物量达到4.45 g VSS/L,膜结构稳定,表现出较活性污泥法更高的活性.在进水TOC、氨氮浓度分别为350 ms/L、50 mg/L,HRT为6 h的情况下,两者的去除率分别达到了97.1%和64.3%,表明载体上的生物膜对污水中TOC及氨氮的去除表现出高效率.挂膜后载体表面上的微生物以丝状菌为主,孔壁上的微生物以球菌和杆菌为主要生物相,证明载体内外表面皆适宜微生物的生长,并且形成合理的生物相分布. 相似文献
106.
107.
Li Zhang Dawen Zhang Yihua Wei Linguan Luo Tingcan Dai 《Environmental monitoring and assessment》2014,186(4):2185-2194
The levels of trace elements (As, Cd, Cr, Cu, Fe, Ni, Pb, Se, and Zn) in eight species of cultured freshwater fishes from Jiangxi province were determined by inductively coupled plasma-mass spectroscopy. All the studied trace element levels in fish muscles from Jiangxi province did not exceed Chinese national standard and European Union standard, and they were often lower than previous studies. The calculated target hazard quotient values for all the studied trace elements in fish samples were much less than 1, suggesting that the studied trace elements in fish muscles from Jiangxi province had not pose obvious health hazards to consumers. As and Cd concentrations in northern snakehead were much higher than that in other fishes, demonstrating that this fish species could be valuable as a bioindicator of As and Cd in environmental surveys. In addition, the highest concentrations of Fe, Zn, and moderate contents of other essential trace elements in crucian carp indicated that crucian carp could be a good nutrient source of essential trace elements for human health. 相似文献
108.
Yan Zhang Wei Luo Junmei Jia Peiru Kong Xiaojuan Tong Yonglong Lu Liqiong Xie Fulong Ma John P. Giesy 《Environmental monitoring and assessment》2014,186(8):5297-5306
Pig manure (PM) is widely used as an organic fertilizer to increase yields of crops. Excessive application of compost containing relatively great concentrations of copper (Cu) and zinc (Zn) can change soil quality. To clarify the effects of different rates of application and to determine the optimal rate of fertilization, PM containing 1,115 mg Cu kg?1, dry mass (dm) and 1,497 mg Zn kg?1, dm was applied to alkaline soil at rates of 0, 11, 22, 44, 88, and 222 g PM kg?1, dm. Phospholipid fatty acids (PLFAs) were used to assess soil microbial community composition. Application of PM resulted in greater concentrations of total nitrogen (TN), NH4 +-N, NO3 ?-N, total carbon (TC), soil organic matter (SOM) but lesser pH values. Soils with application rates of 88–222 g PM kg?1, dm had concentrations of total and EDTA-extractable Cu and Zn significantly greater than those in soil without PM, and concentrations of T-Cu and T-Zn in these amended soils exceeded maximum limits set by standards in china. Except in the soil with a rate of 11 g PM kg?1, dm, total bacterial and fungal PLFAs were directly proportional to rate of application of PM. Biomasses of bacteria and fungi were significantly greater in soils with application rates of 44–222 g PM kg?1, dm than in the soil without PM. SOM, TC and EDTA-Zn had the most direct influence on soil microbial communities. To improve fertility of soils and maintain quality of soil, rate of application should be 22–44 g PM kg?1 dm, soil containing Cu and Zn. 相似文献
109.
Chang Liu Jianlin Luo Xiaona Li Qiang Gao Jianzhang Li 《Journal of Polymers and the Environment》2018,26(1):158-165
The effects of three compounded curing agents on the properties and performance of the urea-formaldehyde (UF) resin were investigated in this study. The compounded curing agents were prepared by mixing ammonium chloride with hexamethylenetetramine, citric acid, and oxalic acid respectively at a ratio of 1:1, named N-H, N–CA, and N–OA, respectively. The curing process, crystallinity, and physical properties were measured, and the three-ply plywood was fabricated to measure its prepress strength, wet shear strength, and formaldehyde emission. Results showed that the compounded curing agents N–CA and N–OA enhanced the initial viscosity, crosslinking density and thermal stability of UF resin. Additionally, the prepress strength of the plywood bonded by UF resin with N–CA and N–OA increased by 82 and 111% respectively compared to the UF resin with NH4Cl, and the wet shear strength increased by 14 and 16%, the formaldehyde emission decreased by 19 and 42% respectively. However, owing to the short pot-life of these curing agent limited their storage time, the curing agents N–CA and N–OA should be applied to fabricate plywood in winter for obtaining a better bond strength and a lower formaldehyde emission. While the UF resin with N–HT showed a suitable pot-life, so it could be applied to fabricate plywood in summer for long time storage and avoiding procuring problem. 相似文献
110.
Huang Shaojian Dai Chunhao Zhou Yaoyu Peng Hui Yi Kexin Qin Pufeng Luo Si Zhang Xiaoshan 《Environmental science and pollution research international》2018,25(17):16548-16566
Environmental Science and Pollution Research - Plant leaves play a key role in the accumulation of PAHs, as they are able to capture PAHs from the air. In this paper, the mechanism, including... 相似文献