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551.
Endosulfan, one of the major pesticides used in cotton-growing, is of environmental concern because of its toxicity to fish and its apparent persistence in the environment. This study examines the distribution and degradation pathways for endosulfan in an aquatic system and the processes by which it is removed. In the alkaline waters of the cotton region, hydrolysis is the dominant degradation process. By this mechanism alone, the expected half-lives for the alpha- and beta-endosulfan isomers were found to be 3.6 days and 1.7 days, respectively. Partitioning studies showed, however, that the major proportion of endosulfan would associate with the sediments (log Koc(alpha) 3.6 and log Koc(beta) 4.3). Field studies confirmed the presence of high concentrations in sediments. Microcosm experiments showed that loss of endosulfan was slower than predicted from hydrolysis rates. Models are presented to explain how desorption from sediment limits the loss of endosulfan from a system. 相似文献
552.
Norway spruce seedlings were sprayed twice weekly with one of a range of artificial mists at either pH 2.5, 3.0 or 5.6, for three months. The mists consisted of either (NH4)2SO4 (pH 5.6), NH4NO3 (pH 5.6), water (pH 5.6), HNO3 (pH 2.5), H2SO4 (pH 2.5). In late December 1988 and early January 1989 the light response of assimilation and stomatal conductance were assessed in the laboratory following a 4-day equilibration period at 12 degrees C. The intact trees were then subjected to a mild (-10 degrees C), brief (3 h) frost in the dark and the recovery of light saturated assimilation (Amax) was followed during the subsequent light period. The same trees were then subjected to a second 3 h (-18 degrees C) frost. The recovery of Amax during the next day was followed. All ion-containing mists stimulated Amax and apparent quantum yield relative to control trees, irrespective of pH. The mists containing SO4 made stomatal conductance unresponsive to light flux density and caused the stomata to lock open. Frosts of -10 degrees C and -18 degrees C did not inhibit the Amax of control trees for longer than 200 min into the light period. In contrast, the ion-containing mists exerted a significant inhibitory effect upon the recovery of Amax. Nitric acid inhibited Amax to 35% of the pre-frost value, whilst the remaining treatments inhibited Amax between 15% and 40% of the pre-frost value. It is concluded that SO4 causes increased mid-winter frost sensitivity and NO3 ameliortes this effect. The results are discussed in relation to forest decline. 相似文献
553.
Concentrations of V, Al and Br determined by neutron activation analysis showed significant interspecies differences: the epiphytic lichen
had consistently higher elemental concentrations than the peat moss
or the terricolous lichen
collected from the same sites. A regional survey with the latter two species indicated a distinct decrease of V and Al levels from south to north Finland. A large-scale survey with
mosses showed relatively low levels of vanadium in remote areas of Scandinavia, but somewhat elevated concentrations of V e.g. in samples from Leningrad region, northern Germany, Wales and northeastern U.S.A. 相似文献
554.
The dose-response relationship between low-caloric sweetening agents, sorbitol and maltitol, administered orally in single doses, and the induction of diarrheal symptoms was investigated. Seven healthy male and 7 healthy female Japanese each in their twenties, thirties, and forties, respectively, or a total of 42 subjects were admitted to the study. The 50% laxative effective dose of sorbitol was estimated to be 0.4 g/kg for males and 1.0 g/kg for females and that of maltitol was estimated to be 0.8 g/kg for both males and females. The maximum non-effective dose of sorbitol was estimated to be 0.15 g/kg for males and 0.3 g/kg for females and that of maltitol was estimated to be 0.3 g/kg for both males and females. 相似文献
555.
556.
A model for gaseous pollutant sorption by leaves 总被引:1,自引:0,他引:1
J H Bennett A C Hill D M Gates 《Journal of the Air Pollution Control Association》1973,23(11):957-962
557.
Incineration of municipal refuse results in the production of massive quantities of fly ash and bottom ash. Toxic elements in the original refuse may be concentrated up to 40-fold in the resultant ash. There is concern that burial of such ash in landfills could result in leaching of these elements downward into groundwater. In this study, refuse ashes were incorporated into glass, ceramic and cement composites to immobilize such toxic elements. The EP Toxicity Test (1986) was used to show that extraction of such elements by simulated acid rain is effectively blocked in these new solid materials. 相似文献
558.
Mixed primary sewage sludge was incubated anaerobically with and without azide addition to prevent biological activity. The behaviour of 1,3-, 1,4- and 1,2-dichlorobenzene, 1,3,5-, 1,2,4- and 1,2,3-trichlorobenzene, 1,2,3,4- and 1,2,4,5-tetrachlorobenzene, hexachlorobenzene, and cis- and trans-permethrin was examined to determine their potential removal during anaerobic digestion. All the chlorobenzenes were removed to varying extents over 32 days of incubation, ranging from 25% removal for 1,3,5-trichlorobenzene to 80% removal for 1,4-dichlorobenzene. Biodegradation may have been responsible for the reductions in 1,3- and 1,4-dichlorobenzene and 1,2,4- and 1,2,3-trichlorobenzene as there was no significant removal of these compounds in azide treated sludge. The removal over 32 days of cis- and transpermethrin was 87% and 96% respectively. These removals were attributed to a chemical or physical process. 相似文献
559.
MacDonald RC Kimmerer TW Razzaghi M 《Environmental pollution (Barking, Essex : 1987)》1989,62(4):337-351
We measured the frequency with which leaves of trees in the Ohio River Valley produced ethanol aerobically, to determine if aerobic ethanol production might provide a viable field assay for air pollution stress. Leaves were collected from trees during the summers of 1985 and 1986 and ethanol production was determined using headspace GC. Frequency of ethanol production was compared with environmental factors, including air pollution concentrations. We found frequent foliar ethanol production and elevated alcohol dehydrogenase activity in the leaves of several species of trees in the Ohio River Valley, USA. The ethanol concentrations measured were often equivalent to those produced by anaerobic leaves. Ethanol production was associated with hot, hazy weather and elevated NO(2) concentrations. Ethanol production was more frequent in urban and industrialized areas. Ethanol production was not associated with natural stresses such as flooding and herbivory. We propose that aerobic ethanol production is the result of cell acidification due to the accumulation of acidic gases in the cytoplasm. The use of ethanol production as a diagnostic tool for detecting stress imposed by acidic gases is discussed. 相似文献
560.
Following earlier work (Al-Omran & Preston, 1987) in which phthalate ester speciation was examined in laboratory studies, the present paper describes the results of an attempt to validate the results by field measurements in the River Mersey Estuary, Liverpool, UK. Samples of water, suspended solids and sediments were analysed for their phthalate ester content. Solid samples were also analysed for their carbon, organic carbon and lipid content. A comparison of the field and laboratory results confirms the association between diethylhexyl phthalate and small particles and shows that other phthalates tend to be associated with relatively coarse, lipid-rich particles. Partition coefficients between dissolved phthalate esters and suspended particles are calculated and compared with other laboratory studies. 相似文献