Use of statistical tools to evaluate the reductive dechlorination of high levels of TCE in microcosm studies

A large, multi-laboratory microcosm study was performed to select amendments for supporting reductive dechlorination of high levels of trichloroethylene (TCE) found at an industrial site in the United Kingdom (UK) containing dense non-aqueous phase liquid (DNAPL) TCE. The study was designed as a fractional factorial experiment involving 177 bottles distributed between four industrial laboratories and was used to assess the impact of six electron donors, bioaugmentation, addition of supplemental nutrients, and two TCE levels (0.57 and 1.90 mM or 75 and 250 mg/L in the aqueous phase) on TCE dechlorination. Performance was assessed based on the concentration changes of TCE and reductive dechlorination degradation products. The chemical data was evaluated using analysis of variance (ANOVA) and survival analysis techniques to determine both main effects and important interactions for all the experimental variables during the 203-day study. The statistically based design and analysis provided powerful tools that aided decision-making for field application of this technology. The analysis showed that emulsified vegetable oil (EVO), lactate, and methanol were the most effective electron donors, promoting rapid and complete dechlorination of TCE to ethene. Bioaugmentation and nutrient addition also had a statistically significant positive impact on TCE dechlorination. In addition, the microbial community was measured using phospholipid fatty acid analysis (PLFA) for quantification of total biomass and characterization of the community structure and quantitative polymerase chain reaction (qPCR) for enumeration of Dehalococcoides organisms (Dhc) and the vinyl chloride reductase (vcrA) gene. The highest increase in levels of total biomass and Dhc was observed in the EVO microcosms, which correlated well with the dechlorination results.     

Thermophilic adaptation of a mesophilic anaerobic sludge for food waste treatment

As opposed to mesophilic, thermophilic anaerobic digestion of food waste can increase the biogas output of reactors. To facilitate the transition of anaerobic digesters, this paper investigated the impact of adapting mesophilic sludge to thermophilic conditions. A 5L bench scale reactor was seeded with mesophilic granular sludge obtained from an up-flow anaerobic sludge blanket digester. After 13 days of operation at 35 degrees C, the reactor temperature was instantaneously increased to 55 degrees C and operated at this temperature until day 21. The biomass was then fed food waste on days 21, 42 and 63, each time with an F/M (Food/Microorganism) ratio increasing from 0.12 to 4.43 gVS/gVSS. Sludge samples were collected on days 0, 21, 42 and 63 to conduct substrate activity tests, and reactor biogas production was monitored during the full experimental period. The sludge collected on day 21 demonstrated that the abrupt temperature change had no pasteurization effect, but rather lead to a biomass with a fermentative activity of 3.58 g Glucose/gVSS/d and a methanogenic activity of 0.47 and 0.26 g Substrate/gVSS/d, related respectively, to acetoclastic and hydrogenophilic microorganisms. At 55 degrees C, an ultimate gas production (Go) and a biodegradation potential (Bo) of 0.2-1.4 L(STP)/gVS(fed) and of 0.1-0.84 L(STP) CH(4)/gVS(fed) were obtained, respectively. For the treatment of food waste, a fully adapted inoculum was developed by eliminating the initial time-consuming acclimatization stage from mesophilic to thermophilic conditions. The feeding stage was initiated within 20 days, but to increase the population of thermophilic methanogenic microorganisms, a substrate supply program must be carefully observed.     

A land use regression model for predicting ambient fine particulate matter across Los Angeles, CA

Land use regression (LUR) models have been used successfully for predicting local variation in traffic pollution, but few studies have explored this method for deriving fine particle exposure surfaces. The primary purpose of this method is to develop a LUR model for predicting fine particle or PM(2.5) mass over the five county metropolitan statistical area (MSA) of Los Angeles. PM(2.5) includes all particles with diameter less than or equal to 2.5 microns. In the Los Angeles MSA, 23 monitors of PM(2.5) were available in the year 2000. This study uses GIS to integrate data regarding land use, transportation and physical geography to derive a PM(2.5) dataset covering Los Angeles. Multiple linear regression was used to create the model for predicting the PM(2.5) surface. Our parsimonious model explained 69% of the variance in PM(2.5) with three predictors: (1) traffic density within 300 m, (2) industrial land area within 5000 m, and (3) government land area within 5000 m of the monitoring site. These results suggest the LUR method can refine exposure models for epidemiologic studies in a North American context.     

Using pneumatic fracturing extraction to achieve regulatory compliance and enhance voc removal from low-permeability formations

The New Jersey Department of Environmental Protection and Energy (NJDEPE) has been developing cleanup regulations that focus on remediation, rather than extended delineation, and on integrating regulatory requirements with technological developments. To this end, the NJDEPE, under the regulatory aegis of the Environmental Cleanup and Responsibility Act (ECRA), is monitoring an innovative treatment technology pilot test at a TCE-contaminated ECRA site in Hillsborough, New Jersey. The purpose of the study is to determine the applicability of pneumatic fracturing extraction (PFE) as a source-removal technique for extracting volatile organic compounds (VOCs) trapped informations with low permeability. The technology being pilot tested is pneumatic fracturing extraction, a process for enhancing permeability to promote in-situ removal and treatment of VOCs. The patented process uses high-pressure air injected into an isolated subsurface zone at controlled rates and pressures. At a critical point, the geologic material ruptures, and fractures are created that radiate outward from the fracture location. At the pilot test site, formation air flow was increased from 400 percent to 700 percent. PFE is a key component of the overall remediation strategy at the Hillsborough site. Consistent with proposed NJDEPE regulations, a ground-water pump-and-treat system will be installed for plume migration control. Once the pump-and-treat system has been established and shown to be effective, a more aggressive source removal program will be implemented using PFE. This program will include construction of a vadose zone PFE system and evaluation of the use of pneumatic fracturing to remove saturated zone residual dense nonaqueous phase liquids (DNAPL). Preliminary calculations suggest that if source zone concentrations can be reduced to 10 ppm of TCE, then TCE groundwater concentrations may be reduced to background levels at the property boundary compliance points.     

Groundwater-level trends and implications for sustainable water use in the Kabul Basin, Afghanistan

The Kabul Basin, which includes the city of Kabul, Afghanistan, with a population of approximately 4 million, has several Afghan, United States, and international military installations that depend on groundwater resources for a potable water supply. This study examined groundwater levels in the Kabul Basin from 2004 to 2012. Groundwater levels have increased slightly in rural areas of the Kabul Basin as a result of normal precipitation after the drought of the early 2000s. However, groundwater levels have decreased in the city of Kabul due to increasing water use in an area with limited recharge. The rate of groundwater-level decrease in the city is greater for the 2008–2012 period (1.5 meters per year (m/yr) on average) than for the 2004–2008 period (0–0.7 m/yr on average). The analysis, which is corroborated by groundwater-flow modeling and a non-governmental organization decision-support model, identified groundwater-level decreases and associated implications for groundwater sustainability in the city of Kabul. Military installations in the city of Kabul (the Central Kabul subbasin) are likely to face water management challenges resulting from long-term groundwater sustainability concerns, such as the potential drying of shallow water-supply wells. Installations in the northern part of the Kabul Basin may have fewer issues with long-term water sustainability. Groundwater-level monitoring and groundwater-flow simulation can be valuable tools for assessing groundwater management options to improve the sustainability of water resources in the Kabul Basin.     

Self-reported falls and fall-related injuries among persons aged>or=65 years--United States, 2006

PROBLEM: In 2005, 15,802 persons aged>or=65 years died from fall injuries. How many older adults seek outpatient treatment for minor or moderate fall injuries is unknown. METHOD: To estimate the percentage of older adults who fell during the preceding three months, the Centers for Disease Control and Prevention (CDC) analyzed data from two questions about falls included in the 2006 Behavioral Risk Factor Surveillance System (BRFSS) survey. RESULTS: Approximately 5.8 million (15.9%) persons aged>or=65 years reported falling at least once during the preceding three months, and 1.8 million (31.3%) of those who fell sustained an injury that resulted in a doctor visit or restricted activity for at least one day. DISCUSSION: This report presents the first national estimates of the number and proportion of persons reporting fall-related injuries associated with either doctor visits or restricted activity. SUMMARY: The prevalence of falls reinforces the need for broader use of scientifically proven fall-prevention interventions. IMPACT ON INDUSTRY: Falls and fall-related injuries represent an enormous burden to individuals, society, and to our health care system. Because the U.S. population is aging, this problem will increase unless we take preventive action by broadly implementing evidence-based fall prevention programs. Such programs could appreciably decrease the incidence and health care costs of fall injuries, as well as greatly improve the quality of life for older adults.     

ANALYZIIG RIPARIAN SITE CAPABILITY AND MANAGEMENT OPTIONS1

ABSTRACT: Riparian areas interact with aquatic and upland conditions and therefore help determine the degree of functionality (streambank stability, shade, sediment, and debris filtering) found in a watershed or catchment. Thus, conditions in riparian areas exert significant influence on water quality. Physical and biological factors (biophysical determinants) that influence these conditions and determine long‐term site ecology include topographic variables, geology, climate, soil texture, and others. These conditions are further modified by management infrastructure (roads, dikes, etc.). Our objective was to develop a system for evaluating site condition in relation to site capability. Since biophysical determinants and infrastructure interact with water quality, our first task was to acquire data concerning the spatial distribution of biophysical determinants and infrastructure constraints and to import them into a GIS system where they could be managed and processed. To expedite analysis, determinants and infrastructure constraints were placed into a hierarchy capable of isolating various site capability types. The hierarchy was designed to incorporate multiscale effects. Site capability areas are georeferenced in this process thereby enabling efficient monitoring and providing a way to focus management on those areas needing improvement. Study tasks included: (1) landscape characterization and hierarchy selection, (2) field assessment, (3) information management and data mining, and (4) information interpretation and adaptive management. This approach appears to be an effective way to isolate general ripananstandardsmaycon site conditions, to provide indications about water quality, and to create strategies necessary for alleviating water quality problems.     

A data integration framework to support Triad projects

Cost‐effective and efficient site remediation and scientifically defensible decisions require site characterizations that are representative of site conditions. The Triad conceptual site model (CSM) is at the center of a continually improving site characterization process that begins during systematic planning and ends after the last data are developed. To gain the full benefit and greatest cost‐effectiveness, the process of CSM refinement should be performed in real time. Thus, the use of collaborative data is critical for evolving and maturing the CSM. In the field, through the use of all available data that are of known quality, a skilled and experienced field team can collect sufficient site information to mature the CSM in a timely manner. To facilitate the planning and execution of such a process, an easily understandable framework is needed to structure data quality that supports scientifically defensible decisions and efficient projects. This article explores such a framework. © 2004 Wiley Periodicals, Inc.     

Management practices as antecedents of safety culture within the trucking industry: similarities and differences by hierarchical level

PROBLEM: A homogeneous perception of safety is important for the achievement of a strong safety culture; however, employees may differ in their safety perceptions, depending on their position and/or hierarchical level within the organization. Moreover, there is limited information on the antecedents of safety culture. This study examines how safety training, driver scheduling autonomy, opportunity for safety input, and management commitment to safety influence individuals' perceptions of safety culture. METHOD: Data for this study were drawn from 116 trucking firms, stratified by three safety performance levels. The data were collected from drivers (lowest hierarchical level), dispatchers (medium hierarchical level), and safety directors (highest hierarchical level), regarding their perceptions of their respective corporate safety cultures. Perceptions of safety culture were analyzed through a linear regression using dummy variables to differentiate among the three hierarchical groups. The resulting model allowed for examination of the specific antecedents of safety culture for the three employee groups and the extent to which the hierarchical groups were in agreement with each other. RESULTS: Driver fatigue training, driver opportunity for safety input, and top management commitment to safety were perceived to be integral determinants of safety culture in all three groups. IMPACT ON INDUSTRY: Trucking firms seeking to strengthen employees' perceptions of safety culture might begin by improving these safety management practices while appreciating that they may have a different impact depending on the employee's hierarchical position (e.g., drivers' perceptions of safety culture are more influenced by top management commitment and driver fatigue training). A fourth safety practice examined, driver scheduling autonomy, was not found to be instrumental in shaping safety culture for any of the three hierarchical levels. Consistent with previous research, implementation of stronger safety cultures should result in fewer accidents.