Mercury fractionation in the sediments of Vembanad wetland, west coast of India

Transformations among different mercury species associated with sediments can have a major effect on the metal's mobility and potential for methylation and hence bioaccumulation. In the present study, various fractions of mercury in the sediments of Vembanad wetland system analysed. Total mercury (THg) concentration in the surface sediment varied from 16.3 to 4,230?ng/g. The results of sequential extraction showed that the major portion of mercury in these sediments existed as elemental form followed by organo-chelated form. The least portion observed was the residual fraction (mercury of natural origin). Even though the percentage of mercury observed in the easily available fractions is relatively small, absolute values of these mobile Hg fractions are quite high due to the very high total mercury values. The fractionation of mercury in the sediment was controlled by the organic matter, sulphur complexes and concentration of THg. The results showed that the bioavailability of mercury is high as the amount of mercury found in the initial three fractions is high, which can also enhance the methylation potential of the Vembanad wetland sediments. The fractionation pattern of mercury also revealed the presence of anthropogenic mercury content in the Vembanad wetland sediments.     

Studies on the utility of plant cellulose waste for the bioadsorption of crystal violet dye

Several synthetic dyes employed in textile and food industries are discharged into aquatic environment. These visible pollutants in water damage environment, as they are carcinogenic and toxic to humans. The use of cost effective and ecofriendly plant cellulose based adsorbents have been studied in batch experiments as an alternative and effective substitution of activated carbon for the removal of toxic dyes from waste water. Adsorbents prepared from sugarcane baggase, were successfully used to remove certain textile dye such as crystal violet from an aqueous solution. The present investigation potentiate the use of sugarcane baggase, pretreated with formaldehyde (referred as Raw Baggase) and sulphuric acid (referred as Chemically Activated Baggase), for the removal of crystal violet dye from simulated waste water. Experiments were carried out at neutral pH with various parameters like dye concentration, temperature, contact time and adsorbent dosage. Efficiency of raw baggase was found better than chemically activated baggase for adsorption of crystal violet dye. The data obtained perfectly fits in the Freundlich adsorption isotherm.     

Agroforestry in the Western Ghats of peninsular India and the satoyama landscapes of Japan: a comparison of two sustainable land use systems

Agroforestry in the Western Ghats (WG) of peninsular India and satoyama in rural Japan are traditional land-use systems with similar evolutionary trajectories. Some of their relevance was lost by the middle of the twentieth century, when modern agricultural technologies and urbanisation engineered shifts in emphasis towards maximising crop production. There has been, however, a resurgence of interest in traditional land-use systems recently, in view of their ability to provide ecosystem services. Both agroforestry and satoyama are thought to be harbingers of biological diversity and have the potential to serve as “carbon forests.” Carbon (C) stock estimates of the sampled homegardens in WG ranged from 16 to 36 Mg ha⁻¹. Satoyama woodlands owing to variations in tree stocking and management conditions indicated widely varying C stocks (2–279 Mg ha⁻¹). Agroforestry and satoyama also differ in nature, complexity, and objectives. While agroforestry involves key productive and protective functions, and adopts ‘intensive management’, the satoyama woodlands are extensively managed; understorey production is seldom a consideration. Differences in canopy architecture (multi-tiered structure of agroforestry vs. the more or less unitary canopy of satoayama) and land ownership pattern (privately owned/managed agroforestry holdings vs. community or local government or privately owned and mostly abandoned satoyamas) pose other challenges in the transfer and application of knowledge gained in one system to the other. Nonetheless, lessons learnt from satoyama conservation may be suitable for common pool resource management elsewhere in Asia, and aspects relating to understorey production in agroforestry may be relevant for satoyama under certain scenarios.     

Environmental impacts of perchlorate with special reference to fireworks—a review

Perchlorate is an inorganic anion that is used in solid rocket propellants, fireworks, munitions, signal flares, etc. The use of fireworks is identified as one of the main contributors in the increasing environmental perchlorate contamination. Although fireworks are displayed for entertainment, its environmental costs are dire. Perchlorates are also emerging as potent thyroid disruptors, and they have an impact on the ecology too. Many studies have shown that perchlorate contaminates the groundwater and the surface water, especially in the vicinity of fireworks manufacturing sites and fireworks display sites. The health and ecological impacts of perchlorate released in fireworks are yet to be fully assessed. This paper reviews fireworks as a source of perchlorate contamination and its expected adverse impacts.     

Environmental protection and ecology-Indian experience

An attempt has been made in this paper to highlight some of environmental problems and suggest possible solutions for planning water resources development projects.     

Color removal of monoazo acid dye from aqueous solution by adsorption and chemical coagulation

This communication presents the results of an investigation conducted on color removal from a monoazo acid dye, C.I. Acid Red 88, by adsorption onto coal based sorbents like Lignite coal, Charfines and Bituminous coal and F-400 Activated carbon and by chemical coagulation employing Aluminum sulfate, Ferric chloride, Manganese sulfate, Manganese chloride and Barium chloride.     

An innovative approach to minimize excess sludge production in sewage treatment using integrated bioreactors

The present investigation deals with an application of integrated sequential oxic and anoxic bioreactor(SOABR) and fluidized immobilized cell carbon oxidation(FICCO) reactor for the treatment of domestic wastewater with minimum sludge generation. The performance of integrated SOABR-FICCO system was evaluated on treating the domestic wastewater at hydraulic retention time(HRT) of 3 hr and 6 hr for 120 days at organic loading rate(OLR)of 191 ± 31 mg/(L·hr). The influent wastewater was characterized by chemical oxygen demand(COD) 573 ± 93 mg/L; biochemical oxygen demand(BOD5) 197 ± 35 mg/L and total suspended solids(TSS) 450 ± 136 mg/L. The integrated SOABR-FICCO reactors have established a significant removal of COD by 94% ± 1%, BOD5 by 95% ± 0.6% and TSS by 95% ± 4% with treated domestic wastewater characteristics COD 33 ± 5 mg/L; BOD59 ± 0.8 mg/L and TSS 17 ± 9 mg/L under continuous mode of operation for 120 days. The mass of dry sludge generated from SOABR-FICCO system was 22.9 g/m~3. The sludge volume index of sludge formed in the SOABR reactor was 32 mL/g and in FICCO reactor it was 46 mL/g. The sludge formed in SOABR and FICCO reactor was characterized by TGA, DSC and SEM analysis. Overall, the results demonstrated that the integrated SOABR-FICCO reactors substantially removed the pollution parameters from domestic wastewater with minimum sludge production.