绿色合成膨胀石墨负载纳米零价铁去除水中Cd(Ⅱ)

工业生产中Cd(Ⅱ)对水体的危害,本文合成了两种新型吸附剂,纳米零价铁(nZVI)和膨胀石墨负载纳米零价铁(EG-nZVI).利用FESEM、EDS、TEM、XRD、FTIR及BET比表面积测定对nZVI和EG-nZVI进行表征,探讨了二者对溶液中Cd(Ⅱ)的去除效果.结果 表明,含有100 mg·L-1Cd(Ⅱ)溶液,nZVI和EG-nZVI的投加量分别达到0.4 mg·L-1和2 mg·L-1,在超声波辅助的条件下,常温、pH 8、反应30 min时,Cd(Ⅱ)去除率分别为56.3％和78.4％.EG-nZVI和nZVI去除Cd (Ⅱ)过程均符合伪二级动力学模型和Langmuir吸附等温模型;将吸附剂置于空气中不同时间,测定结果显示EG-nZVI对Cd(Ⅱ)的去除活性明显高于nZVI,说明EG-nZVI较nZVI有更高的去除效能和稳定性.     

Electrochemical detoxification of four phosphorothioate obsolete pesticides stocks

The phosphorothioate pesticides are widely used for crop production and fruit tree treatment, but their disposal causes serious environmental problems. Four commercial phosphorothioate pesticides (Demeton-S-methyl, Metamidophos, Fenthion and Diazinon) were treated by an electrolysis system using Ti/Pt as anode and stainless steel 304 as cathode. A number of experiments were run in a laboratory scale pilot plant and the results are presented. For Fenthion the achieved reduction was over 60%, while for Demeton-S-methyl, Metamidophos and Diazinon was more than 50%. Diazinon had the lowest energy demand. The COD/BOD5 ratio was improved considerably after electrolysis for all four pesticides examined. As a conclusion, electrochemical oxidation could be used as a pretreatment method of the pesticides detoxification.     

如何加强车间安全管理工作

车闻安全管理是企业安全管理的重要环节,用怎样的措施手段和方法来强化车间安全管理呢? 正确理解党的安全方针“安全第一,预防为主”这八字方针是一个整体,在工作中不能分开讲,也不能分开理解。安全第一是搞好生产的基础和前提条件,预防为主是搞好安全生产的实际行动、有力措施和有效手段。如果只讲安全第一,不讲预防为主,会产生安全工作挂在嘴上、写在纸上、赔上墙、没有落实在行动上的形式主义。     

洞庭湖区的湿地资源及保护对策

介绍了洞庭湖区湿地类型、分布、湿地生态资源现状,指出了洞庭湖区湿地生态系统所存在的主要问题并对其保护对策,提出合理建议.     

山体绕流和尾流区气态污染物输送扩散规律的研究

采用瞬时烟线仪与迪沙(DISA)热线风速仪相结合的方法探测了山体的绕流区和尾流区结构。试验结果表明,山体的绕流和尾流对低架源排放的气态污染物扩散影响甚大,山体绕流可改变烟流的地面浓度分布.结果还表明,我们所用的探测流向的方法较为有效和准确.     

城市污水净化的环境效益与环境影响分析

对佛山城市污水净化系统的环境响应和效益预测原则，城市污水净系统正式运转将对佛山水道化纤厂至人民桥段及佛山涌水质有明显改善，其社会效益十分显著，但净化系统的建设交将带来以恶臭、卫生防疫和噪声等方面为主的不利环境影响。因此在城市环境建设中应尽量减少城市污水净化的负面影响，充分发挥其环境效应和社会效益，为城市环境综合整治创造良好的条件。     

Application of closed-vessel microwave digestion method for the determination of multi-elements in environmental samples by sequential ICP-AES

A closed-vessel microwave digestion method is described for the rapid dissolution of environmental samples such as foods, soils and sediments. Depending on the sample type, 0.1-0.2 g sample was decomposed with HNO3/H2O2 or HNO3 / H2O2/HF acid mixture in a PTFE digestion vessel by using microwave heating for 2-3 min at 500W of microwave power. The solution, or to which 0.5 g of boric acid was added, was diluted to 25-50 ml and directly determined by sequential ICP-AES. The accuracy of the procedure was validated by the analysis of six standard reference materials for 10 elements. Ail results were in a good agreements with the certified values.     

H2O2对载银TiO2光催化降解Aroclor1260的影响

光催化氧化法降解水中有机污染物是近来发展较为迅速的废水处理技术，以锐钛型载银TiO2为催化剂，在发射光谱波长为254nm，功率的15W紫外灯照射下，考察不同H2O2浓度对Aroclor1260的光催化降解的影响，结果表明：低浓度的H2O2对Aroclor1260的光催化降解有促进作用，而当H2O2的浓度高于30mol/l时，光催化降解受到抑制，而且这种影响对不同PCB单体化合物的效果基本一致。