Evaluating the distribution and potential ecological risks of heavy metal in coal gangue

Environmental Science and Pollution Research - The heavy metals, which derived from accumulated coal gangue, are important source of environmental pollution. In this study, coal gangue dumps,...     

因果图和模糊综合风险评价在城市燃气输配系统的应用

针对复杂的城市燃气输配系统,利用因果图和模糊综合评价相结合的方法对其进行风险分析.因果图能找出影响城市燃气输配系统失效的因素,模糊综合评价则可在其基础上对风险量化.以某市的燃气输配系统为例描述了该方法的步骤.结果表明,因果图和模糊综合评价相结合的方法合理且易于工程应用.     

公共场所人群聚集个人风险的研究

公共场所人群聚集的风险影响因素众多,其随机性和不确定性强,对风险进行定量比较困难.在前人研究的基础上,对事故进行分类,并根据事故发生概率和与其相应的概率分布,通过数学推导和参数补偿,提出了个人风险定量计算模型.最后以公共场所的部分事故统计资料为参考数据,阐述了该模型的使用方法和步骤,同时指出使用该模型过程中应该注意的问题.结果表明,该模型具有一定的合理性和准确性,对公共场所人群聚集安全具有一定的指导意义.根据模型的计算结果,建议一般公共场所个人风险的推荐值为4.50×10-7.     

爆炸性恐怖袭击后果与人群聚集状态的关系研究

在自杀性爆炸中,当爆炸负荷较小时,所产生的人员伤亡主要由爆炸碎片造成.从几何及概率理论的角度对自杀式恐怖袭击中爆炸碎片产生的伤亡后果进行了数学建模.人群聚集状态不同,爆炸后产生的伤亡后果不同.在爆炸负荷一定的情况下,分别以场所中的人数,爆炸气流扩散角为变量对伤亡后果进行研究.结果表明,伤亡人数的变化随场所中人数的增加呈单峰式变化.当场所中总人数超过某一阙值后,期望伤亡人数会减小.伤亡人数随爆炸气流扩散角度的增大而下降.场所中人数及爆炸负荷确定的情况下,当场所面积在 m=6～50之间变化时,伤亡后果先增加,然后缓慢下降,最大伤亡在m=25左右时出现.     

开放空间复杂地形人员疏散模拟研究

为研究开放空间复杂地形条件下人员疏散,开发出能够模拟行人疏散的三维可视化软件系统。将复杂多变的地形分解为一系列连续变化的坡面,分析斜坡上行人受力,考虑重力影响,在经典社会力模型的基础上,提出一个改进模型。选择某气井周边居民疏散案例,运用VC++和OpenGL图形库技术初步完成整合数字高程模型(DEM)、道路网络和行人特征的三维社会力人员疏散模拟程序。最后通过实例模拟,可以明显地观察到人群的动态疏散过程以及在灾难中的拥堵行为、转向躲避行为和超越行为。应用该模型,能够实现复杂地形人员疏散三维动态模拟,并快速预测疏散时间。     

Energy transfer and kinetics in mechanochemistry

Mechanochemistry (MC) exerts extraordinary degradation and decomposition effects on many chlorinated, brominated, and even fluorinated persistent organic pollutants (POPs). However, its application is still limited by inadequate study of its reaction kinetic aspects. In the present work, the ball motion and energy transfer in planetary ball mill are investigated in some detail. Almost all milling parameters are summarised in a single factor—total effective impact energy. Furthermore, the MC kinetic between calcium oxide/Al and hexachlorobenzene is well established and modelled. The results indicate that total effective impact energy and reagent ratio are the two factors sufficient for describing the MC degradation degree of POPs. The reaction rate constant only depends on the chemical properties of reactants, so it could be used as an important index to appraise the quality of MC additives. This model successfully predicts the reaction rate for different operating conditions, indicating that it could be suitably applied for conducting MC reactions in other reactors.

     

A review of toxicity and mechanisms of individual and mixtures of heavy metals in the environment

The rational for the study was to review the literature on the toxicity and corresponding mechanisms associated with lead (Pb), mercury (Hg), cadmium (Cd), and arsenic (As), individually and as mixtures, in the environment. Heavy metals are ubiquitous and generally persist in the environment, enabling them to biomagnify in the food chain. Living systems most often interact with a cocktail of heavy metals in the environment. Heavy metal exposure to biological systems may lead to oxidation stress which may induce DNA damage, protein modification, lipid peroxidation, and others. In this review, the major mechanism associated with toxicities of individual metals was the generation of reactive oxygen species (ROS). Additionally, toxicities were expressed through depletion of glutathione and bonding to sulfhydryl groups of proteins. Interestingly, a metal like Pb becomes toxic to organisms through the depletion of antioxidants while Cd indirectly generates ROS by its ability to replace iron and copper. ROS generated through exposure to arsenic were associated with many modes of action, and heavy metal mixtures were found to have varied effects on organisms. Many models based on concentration addition (CA) and independent action (IA) have been introduced to help predict toxicities and mechanisms associated with metal mixtures. An integrated model which combines CA and IA was further proposed for evaluating toxicities of non-interactive mixtures. In cases where there are molecular interactions, the toxicogenomic approach was used to predict toxicities. The high-throughput toxicogenomics combines studies in genetics, genome-scale expression, cell and tissue expression, metabolite profiling, and bioinformatics.     

论环境监察工作制度修订的必要性

随着环境监察形势的不断变化,环境监察现有工作制度难以有效应对日新月异的环境保护新形势;环境监察工作体制、机制以及执法理念的更新换代,未来的环境监察工作制度需要进一步完善,才能更好地为国家环境保护工作保驾护航。     

抗生素药生产废水处理工艺改进研究

企业抗生素废水经原有工艺处理后污染物指标偏高,且不稳定。工艺通过采用增加初沉池和二沉池、污泥回用等改进措施,COD、氨氮等排放浓度下降且稳定排放,改进效果明显。     

化工园区重大事故风险分析

目前我国对化工园区风险分析的理论研究尚处于起步阶段.针对化工园区这一特殊区域,从整体角度出发,分析研究了化工园区内多个重大事故风险源造成的区域风险,并进行了实例应用.综合考虑多个重大事故风险源产生的风险,分析了其产生风险的叠加效应,绘制出化工园区的个人风险等值线;同时根据ALARP(合理可接受风险水平)准则对化工园区的...