Lead ion adsorption on functionalized sugarcane bagasse prepared by concerted oxidation and deprotonation

Environmental Science and Pollution Research - Targeting the removal of Pb2+ in wastewater, sugarcane bagasse was treated with nitric acid and an alkaline solution to prepare adsorbents. On a...     

Intrinsic chemiluminescence production from the degradation of haloaromatic pollutants during environmentally-friendly advanced oxidation processes: Mechanism, structure–activity relationship and potential applications

The ubiquitous distribution of halogenated aromatic compounds(XAr) coupled with their carcinogenicity has raised public concerns on their potential risks to both human health and the ecosystem. Recently, advanced oxidation processes(AOPs) have been considered as an"environmentally-friendly" technology for the remediation and destruction of such recalcitrant and highly toxic XAr. During our study on the mechanism of metal-independent production of hydroxyl radicals(UOH) by halogenated quinones and H_2O_2, we found, unexpectedly, that an unprecedented UOH-dependent two-step intrinsic chemiluminescene(CL) can be produced by H_2O_2 and tetrachloro-p-benzoquinone, the major carcinogenic metabolite of the widely used wood preservative pentachlorophenol. Further investigations showed that, in all UOH-generating systems, CL can also be produced not only by pentachlorophenol and all other halogenated phenols, but also by all XAr tested. A systematic structure–activity relationship study for all 19 chlorophenolic congeners showed that the CL increased with an increasing number of Cl-substitution in general. More importantly, a relatively good correlation was observed between the formation of quinoid/semiquinone radical intermediates and CL generation. Based on these results, we propose that UOH-dependent formation of quinoid intermediates and electronically excited carbonyl species is responsible for this unusual CL production; and a rapid, sensitive,simple, and effective CL method was developed not only to detect and quantify trace amount of XAr, but also to provide useful information for predicting the toxicity or monitoring real-time degradation kinetics of XAr. These findings may have broad chemical, environmental and biological implications for future studies on halogenated aromatic persistent organic pollutants.     

基于环境约束的浙江省制造业行业结构调整优化研究

文章在综合评价浙江省制造业内部各产业污染排放强度的基础上,对浙江省制造业污染排放量进行了因素分解,并构建了基于污染排放程度系数和工业总产值的区域类型划分矩阵,将浙江省制造业划分为优先发展行业、结构优化发展行业、引导发展行业、推动发展行业和限制发展行业,对浙江省制造业内部各产业结构的调整优化提出了针对性建议。     

Ecological Approaches to Urban Migration of the Three Gorges Reservoir Region

As a global developing tendency, the general viewpoint has been reached in the construction of the ecocities, which has produced widespread influence in the international society. Cities must enable people to live in harmony with nature and achieve sustainable development. Although more and more cities in the world are being designed and built to the ecological ones, the construction is also theoretical questions and arduous tasks. People oriented, ecocity development requires the comprehensiv…     

La2O3—ZrO2缺陷萤石型燃烧催化剂的制备

缺陷萤石型Ｌａ２Ｏ３－ＺｒＯ２固溶体的催化燃烧活性受制备条件的影响，本文通过对其共沉淀前体的表面结构和热分解过程的分析，发现共沸蒸馏的办法可以有效地控制前体表面羟基的缩合过程，减少团聚，保持前体中金属离子均匀分散，为生成缺陷有序的烧结石型的Ｌａ２Ｚｒ２Ｏ７复氧化物提供了可能。复合氧化物固溶体的表面阳离子配置情况与样品的催化氧化性能密切相关，软团聚前体的烧结产物对甲烷燃烧反应具有更高的催化活性。     

Road traffic impact on urban atmospheric aerosol loading at Oporto,Portugal

At urban areas in south Europe atmospheric aerosol levels are frequently above legislation limits as a result of road traffic and favourable climatic conditions for photochemical formation and dust suspension. Strategies for urban particulate pollution control have to take into account specific regional characteristics and need correct information concerning the sources of the aerosol.With these objectives, the ionic and elemental composition of the fine (PM_2.5) and coarse (PM_2.5–10) aerosol was measured at two contrasting sites in the centre of the city of Oporto, roadside (R) and urban background (UB), during two campaigns, in winter and summer.Application of Spatial Variability Factors, in association with Principal Component/Multilinear Regression/Inter-site Mass Balance Analysis, to aerosol data permitted to identify and quantify 5 main groups of sources, namely direct car emissions, industry, photochemical production, dust suspension and sea salt transport. Traffic strongly influenced PM mass and composition. Direct car emissions and road dust resuspension contributed with 44–66% to the fine aerosol and with 12 to 55% to the coarse particles mass at both sites, showing typically highest loads at roadside. In fine particles secondary origin was also quite important in aerosol loading, principally during summer, with 28–48% mass contribution, at R and UB sites respectively. Sea spray has an important contribution of 18–28% to coarse aerosol mass in the studied area, with a highest relative contribution at UB site.Application of Spatial Variability/Mass Balance Analysis permitted the estimation of traffic contribution to soil dust in both size ranges, across sites and seasons, demonstrating that as much as 80% of present dust can result from road traffic resuspension.     

低分压CO_2回收新技术的工业应用

介绍了低分压CO_2回收新技术的特点和基本原理,叙述了该技术用于不同类型烟道气CO_2回收的工业应用实例。该技术可解决一乙醇胺降解损耗及设备腐蚀等技术问题,提高溶液的吸收能力、降低CO_2的再生能耗。     

公共场所人群聚集个人风险的研究

公共场所人群聚集的风险影响因素众多,其随机性和不确定性强,对风险进行定量比较困难.在前人研究的基础上,对事故进行分类,并根据事故发生概率和与其相应的概率分布,通过数学推导和参数补偿,提出了个人风险定量计算模型.最后以公共场所的部分事故统计资料为参考数据,阐述了该模型的使用方法和步骤,同时指出使用该模型过程中应该注意的问题.结果表明,该模型具有一定的合理性和准确性,对公共场所人群聚集安全具有一定的指导意义.根据模型的计算结果,建议一般公共场所个人风险的推荐值为4.50×10-7.