Mercury baseline levels in Flemish soils (Belgium)

It is important to establish contaminant levels that are normally present in soils to provide baseline data for pollution studies. Mercury is a toxic element of concern. This study was aimed at assessing baseline mercury levels in soils in Flanders. In a previous study, mercury contents in soils in Oost-Vlaanderen were found to be significantly above levels reported elsewhere. For the current study, observations were extended over two more provinces, West-Vlaanderen and Antwerpen. Ranges of soil Hg contents were distinctly higher in the province Oost-Vlaanderen (interquartile range from 0.09 to 0.43 mg/kg) than in the other provinces (interquartile ranges from 0.7 to 0.13 and 0.7 to 0.15 mg/kg for West-Vlaanderen and Antwerpen, respectively). The standard threshold method was applied to separate soils containing baseline levels of Hg from the data. Baseline concentrations for Hg were characterised by a median of 0.10mg Hg/kg dry soil, an interquartile range from 0.07 to 0.14 mg/kg and a 90% percentile value of 0.30 mg/kg. The influence of soil properties such as clay and organic carbon contents, and pH on baseline Hg concentrations was not important. Maps of the spatial distribution of Hg levels showed that the province Oost-Vlaanderen exhibited zones with systematically higher Hg soil contents. This may be related to the former presence of many small-scale industries employing mercury in that region.     

Thirty years of land-cover change in Bolivia

Land-cover change in eastern lowland Bolivia was documented using Landsat images from five epochs for all landscapes situated below the montane tree line at approximately 3000 m, including humid forest, inundated forest, seasonally dry forest, and cloud forest, as well as scrublands and grasslands. Deforestation in eastern Bolivia in 2004 covered 45,411 km2, representing approximately 9% of the original forest cover, with an additional conversion of 9042 km2 of scrub and savanna habitats representing 17% of total historical land-cover change. Annual rates of land-cover change increased from approximately 400 km2 y(-1) in the 1960s to approximately 2900 km2 y(-1) in the last epoch spanning 2001 to 2004. This study provides Bolivia with a spatially explicit information resource to monitor future land-cover change, a prerequisite for proposed mechanisms to compensate countries for reducing carbon emissions as a result of deforestation. A comparison of the most recent epoch with previous periods shows that policies enacted in the late 1990s to promote forest conservation had no observable impact on reducing deforestation and that deforestation actually increased in some protected areas. The rate of land-cover change continues to increase linearly nationwide, but is growing faster in the Santa Cruz department because of the expansion of mechanized agriculture and cattle farms.     

Towards a renewed research agenda in ecotoxicology

New concerns about biodiversity, ecosystem services and human health triggered several new regulations increasing the need for sound ecotoxicological risk assessment. The PEER network aims to share its view on the research issues that this challenges. PEER scientists call for an improved biologically relevant exposure assessment. They promote comprehensive effect assessment at several biological levels. Biological traits should be used for Environmental risk assessment (ERA) as promising tools to better understand relationships between structure and functioning of ecosystems. The use of modern high throughput methods could also enhance the amount of data for a better risk assessment. Improved models coping with multiple stressors or biological levels are necessary to answer for a more scientifically based risk assessment. Those methods must be embedded within life cycle analysis or economical models for efficient regulations. Joint research programmes involving humanities with ecological sciences should be developed for a sound risk management.     

Oryzalin fate and transport in runoff water in Mediterranean vineyards

An experimental study was conducted in a 91.4-ha Mediterranean vineyard catchment in southern France to characterize the fate and transport of oryzalin in runoff water and thus to assess the risk of contamination of surface waters. Oryzalin concentrations in soil were monitored on two fields, one no-till and one tilled from March 1998 to March 2000. Concentrations in solution and on solid phase of runoff water were measured at the outlets of both fields and the catchment. The droughts in the two summer periods reduced the dissipation of oryzalin and increased its field half-life up to 35 days. Consequently, oryzalin was detected throughout the year in runoff water, with maximum dissolved concentrations > 600 microg l(-1) at the field scale. Oryzalin transport essentially occurred in solution. At the no-till field, seasonal losses were 2.29% and 1.89% of the applied amount in 1998 and 1999, respectively. The corresponding values at the tilled field were 1.56% and 0.29%, since tillage reduced total losses by reducing surface runoff. At the catchment scale, oryzalin concentrations were smaller than those at the field scale, due to dilution effects and staggering of application. Large part of the overland flow from the fields reinfiltrated in the ditches before reaching the outlet of the catchment. As a result, seasonal oryzalin losses were <0.2% of the applied amount.     

Occurrence and congener profiles of polybrominated diphenyl ethers (PBDEs) in environmental samples from coastal British Columbia, Canada

Environmental levels and detailed congener profiles (31 congeners and 3 coeluting congener groups) of polybrominated diphenyl ethers (PBDEs) were assessed in a number of biota samples taken over a large geographic range covering harbours and industrial sites on Canada's West Coast. Additionally, PBDE congener profiles were determined using semipermeable membrane devices (SPMDs) deployed in the Fraser River, the river in Western Canada with the largest industrial activity. PBDE levels detected in biota were between 4 and 2300 ng/g lipid and these levels were compared with those reported in selected European biota to provide a wider perspective on PBDE contamination on Canada's West Coast. Thirteen-congener PBDE patterns in the environmental samples were examined using principal component analysis (PCA), and additionally, comparisons were made between the PBDE profiles in the sample groups and commercially used PBDE technical mixtures (e.g., Bromkals) on a percent composition basis. PCA on congener specific data revealed that PBDE patterns are remarkably similar over a wide geographical range in Western Canada, however, the general pattern in environmental samples varies significantly from those of the predominant technical mixtures. Finally, correlations between PBDE and other persistent and toxic co-occurring contaminants found in Dungeness crab were determined.     

Partitioning studies of coal-tar constituents in a two-phase contaminated ground-water system

Organic compounds derived from coal-tar wastes in a contaminated aquifer in St. Louis Park, Minnesota, were identified, and their partition coefficients between the tar phase and aqueous phase were determined and compared with the corresponding n-octanol/water partition coefficients. Coal tar contains numerous polycyclic aromatic compounds, many of which are suspected carcinogens or mutagens. Groundwater contamination by these toxic compounds may pose an environmental health hazard in nearby public water-supply wells. Fluid samples from this aquifer developed two phases upon settling: an upper aqueous phase, and a lower oily-tar phase. After separating the phases, polycyclic aromatic compounds in each phase were isolated using complexation with N-methyl-2-pyrrolidone and identified by fused-silica capillary gas chromatography/mass spectrometry. Thirty-one of the polycyclic aromatic compounds were chosen for further study from four different classes: 12 polycyclic aromatic hydrocarbons, 10 nitrogen heterocycles, 5 sulfur heterocycles, and 4 oxygen heterocycles. Within each compound class, the tar/water partition coefficients of these compounds were reasonably comparable with the respective n-octanol/water partition coefficient.     

Application of ground-based Lidar for studies of the dynamics of ozone in a mountainous basin

A ground-based Differential Absorption Lidar was employed to study the dynamics of atmospheric O3 within the planetary boundary layer of a basin in the 'Fichtelgebirge' mountains, NE Bavaria. In particular, the night-time dynamics of O3 linked to the ground were investigated. The Lidar system measured vertical profiles of O3 up to 1 km above ground. For detailed analysis of the night-time dynamics of ozone, supplementary data from three ground-based stations (measuring mixing ratios of O3 and NO(x), as well as meteorological parameters) are essential. The Lidar results could be evaluated with these data from various altitudes above the basin floor. For the station with the largest (vertical) distance to the ground-based Lidar, the agreement was very good at all times. The Lidar method proved to be useful for examining the spatial distribution of O3. The observed night-time decrease of O3 at the bottom of the basin was due to deposition and to advection of air masses containing less O3 from the mountain slopes.     

Deep Ethology, Animal Rights, and the Great Ape/Animal Project: Resisting Speciesism and Expanding the Community of Equals

In this essay I argue that the evolutionary and comparative study of nonhuman animal (hereafter animal) cognition in a wide range of taxa by cognitive ethologists can readily inform discussions about animal protection and animal rights. However, while it is clear that there is a link between animal cognitive abilities and animal pain and suffering, I agree with Jeremy Bentham who claimed long ago the real question does not deal with whether individuals can think or reason but rather with whether or not individuals can suffer. One of my major goals will be to make the case that the time has come to expand. The Great Ape Project (GAP) to The Great Ape/Animal Project (GA/AP) and to take seriously the moral status and rights of all animals by presupposing that all individuals should be admitted into the Community of Equals. I also argue that individuals count and that it is essential to avoid being speciesist cognitivists; it really doesn't matter whether ‘dogs ape’ or whether ‘apes dog’ when taking into account the worlds of different individual animals. Narrow-minded primatocentrism and speciesism must be resisted in our studies of animal cognition and animal protection and rights. Line-drawing into ‘lower’ and ‘higher’ species is a misleading speciesist practice that should be vigorously resisted because not only is line-drawing bad biology but also because it can have disastrous consequences for how animals are viewed and treated. Speciesist line-drawing also ignores within species individual differences. This revised version was published online in July 2006 with corrections to the Cover Date.     

Butterflies (Lepidoptera: Papilionoidea and Hesperioidea) of Roxborough State Park, Colorado, USA: Baseline Inventory, Community Attributes, and Monitoring Plan

/ Roxborough State Park in Colorado's Front Range was established in 1975 following a history of cattle and sheep ranching by private ownership. Survey work conducted from 1979 to 1995 resulted in the documentation of 93 species of butterflies. A variety of factors are responsible for the composition of the butterfly community: (1) overgrazing and its effect on the presence or absence of specific butterfly host plants; (2) habitat differences resulting from topographical and geological features; and (3) ecological and historical biogeography. This study provides data on community sampling adequacy, along with estimates of effort needed to monitor trends in abundance by using a community self-similarity curve and power analysis. An annual monitoring plan is proposed to assess trends in community composition. The plan includes collection of presence/absence and abundance data for select butterflies based on natural history information.KEY WORDS: Butterfly communities; Grazing; Inventory; Monitoring; Natural history