Contamination of soil and the medicinal plant <Emphasis Type="Italic">Phyllanthus niruri</Emphasis> Linn. with cadmium in ceramic industrial areas

Phyllanthus niruri is a plant that is used to prevent calcium oxalate crystallisation and to block the stone formation in urolithiasis. Contaminants in the environment can be readily taken up by medicinal plants due to their ability to absorb chemicals into their tissues. If contaminated plants are ingested, they have the potential to negatively affect human and environmental health. The aim of this study was to assess contamination in the soil and the medicinal plant P. niruri by cadmium (Cd) in ceramic industrial areas of Monte Carmelo, Brazil. Soil samples and plant samples (divided in root, shoot and leaves) were collected from a contaminated monitoring site and from a rural area (which was used as a reference site for comparative purposes). The Cd concentrations of the samples were analysed with an atomic absorption spectrometer. P. niruri was found to be sensitive to soil contamination by Cd that was attributed to ceramic industrial emissions. The results revealed that Cd bioaccumulation in the roots and shoots of P. niruri was associated with a significant increase (p?<?0.05) in the concentration of active lignan compounds (phyllanthin and hypophyllanthin) in the leaves. The identification of high concentrations of Cd and active lignan compounds suggests a risk of contamination of the site and the risk of a high dose of Cd to people exposed at the site.     

Fucus spiralis as monitoring tool of metal contamination in the northwest coast of Portugal under the European Water Framework Directives

Metals (Cd, Cr, Cu, Fe, Mn and Zn) in coastal seawaters and soft tissues of macroalga Fucus spiralis from the northwest coast of Portugal were determined to assess spatial variations of metal bioavailabilities and bioaccumulation factors to compare different ecological quality classifications. Both coastal seawaters and soft tissues of F. spiralis showed significant spatial variations in their metal concentrations along the coast. The macroalgae F. spiralis accumulated more efficiently Cd, Mn and Zn and showed low bioaccumulation factors to Cr, Cu and Fe. Regarding the metal guidelines of the Norwegian Pollution Control Authority, the entire northwest (NW) coast of Portugal in April 2013 should be classified as ‘class I—unpolluted’ for all metals, except in Ave for Cu (‘class II—moderately polluted’) and Cavado for Cd and Cu (‘class II—moderately polluted’), revealing the low metal bioavailabilities of these seawaters. As there were always significant positive correlations between all metals in seawaters and F. spiralis, this macroalga species was considered a suitable monitoring tool of metal contamination in the NW coast of Portugal and a useful aquatic organism to be included in the European Environmental Specimen Banks in order to establish a real-time environmental monitoring network under the European Water Framework Directives.     

Characterization and recycling of polymeric components present in cell phones

The cell phone market is developing at a rapid speed. Today there are more than 1.6 billion consumers in the world, and the lifetime of a cell phone is less than 2 years. As a consequence, there is an increase in the waste associated to this product, and many alternatives to the disposal of the cell phones are being studied, such as recycling which shows to be the most important. It is crucial to know what materials constitute the cell phone in order to carry out recycling and determine environmental and economical issues. This work presents an evaluation of the cell phone components, characterizing the raw materials and some properties of the recycled materials.     

The boom in mineral markets: How long might it last?

The commodity price boom that emerged in 2004 has proved far more persevering than its predecessors of 1950 and 1973. Some analysts have suggested that it may represent the start of a “supercycle” caused by the voracious raw materials demand from China and other emerging economies, with prices remaining high for 20-30 years. We offer an alternative explanation. For a variety of reasons, the establishment of new capacity in minerals and energy to match the accelerated demand trends is more time consuming than commonly assumed, and may take a decade or longer. As soon as the new capacity is in place, however, the boom will be punctuated. Prices may collapse much earlier in the event of a severe recession that cuts the growth in commodity demand.     

Landfill leachate enhances fermentative hydrogen production from glucose and sugarcane processing derivatives

Fermentation can use renewable raw materials as substrate, which makes it a sustainable method to obtain H₂. This study evaluates H₂ production by a mixed culture from substrates such as glucose and derivatives from sugarcane processing (sucrose, molasses, and vinasse) combined with landfill leachate. The leachate alone was not a suitable substrate for biohydrogen production. However, leachate blended with glucose, sucrose, molasses, or vinasse increased the H₂ production rate by 2.0-, 2.8-, 4.6-, and 0.5-fold, respectively, as compared with the substrates without the leachate. Determination of metals (Cu, Cd, Pb, Hg, Ni, and Fe) at the beginning and at the end of the fermentative assays showed how they were consumed during the fermentation and demonstrated improved H₂ production. During fermentation, Cu, Fe, and Cd were the most consumed leachate metals. The best substrate combination to produce H₂ was molasses and leachate, which gave high volumetric productivity—469 ml H₂/l h. However, addition of the leachate to the substrates stimulated lactic acid formation pathways, which lowered the H₂ yield. The use of leachate combined with sugarcane processing derivatives as substrates could add value to the leachate and reduce its polluting power, generating a clean energy source from renewable raw materials.     

Electrodisinfection of real swine wastewater for water reuse

Environmental Chemistry Letters - Swine production generates large volumes of wastewater, rich in organic matter, nutrients and pathogens. Electrodisinfection is used to remove organic matter and...