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51.
This study evaluated the potential toxicological risk posed to human health due to the exposure to heavy metals by water ingestion
in an area affected by tanneries – the Cadeia-Feitoria hydrographic basin (Brazil). River water was collected at 10 sites,
every 3 months, from July 1999 to April 2000. After acid digestion, total metal concentration was determined by inductively
coupled plasma optical emission spectrometry (Cd, Cu, Cr, Ni, Zn), flame atomic absorption (Al, Fe, Pb, Mn), or cold vapor
atomic absorption spectrometry (Hg). Cr(VI) was complexed with diphenyl-carbazide and detected by UV–vis spectrometry. In
order to quantify the risk of exposure, the risk assessment methodology employed by the Environmental Protection Agency of
the United States was applied at a screening level. The assumed scenarios included extreme exposure patterns (ingestion of
untreated water, conversion of Cr(III) to Cr(VI), temporal peaks of pollution). Fe, Al, Cd, Hg, and Pb were not included in
the risk analysis, since they showed a low toxicity potential or were undetected in the samples. The selected metals presented
Hazard Quotients < 1, in the following order of increasing risk: Cu < Cr(III) < Zn < Ni < Mn < Cr(VI). Hazard indexes, representing
the additive effect of contaminants, were also low in the basin (< 1), but comparatively increased in the lower reach of Feitoria
and Cadeia Rivers. Although noncarcinogenic risk levels did not suggest possible adverse toxicological effects to the human
population, a considerable deviation from background conditions was observed downstream the area where tanneries are mainly
located. 相似文献
52.
Maria?Faldborg?SteinhausenEmail author John?Fleng?Steffensen Niels?Gerner?Andersen 《Marine Biology》2005,148(1):197-204
Oxygen consumption and tail beat frequency were measured on saithe (Pollachius virens) and whiting (Merlangius merlangus) during steady swimming. Oxygen consumption increased exponentially with swimming speed, and the relationship was described by a power function. The extrapolated standard metabolic rates (SMR) were similar for saithe and whiting, whereas the active metabolic rate (AMR) was twice as high for saithe. The higher AMR resulted in a higher scope for activity in accordance with the higher critical swimming speed (U
crit) achieved by saithe. The optimum swimming speed (U
opt) was 1.4 BL s−1 for saithe and 1.0 BL s−1 for whiting with a corresponding cost of transport (COT) of 0.14 and 0.15 J N−1 m−1. Tail beat frequency correlated strongly with swimming speed as well as with oxygen consumption. In contrast to swimming speed and oxygen consumption, measurement of tail beat frequency on individual free-ranging fish is relatively uncomplicated. Tail beat frequency may therefore serve as a predictor of swimming speed and oxygen consumption of saithe and whiting in the field. 相似文献
53.
Nair GA El-Mariami MA Briones MJ Filogh AM Youssef AK 《Journal of environmental biology / Academy of Environmental Biology, India》2005,26(2):175-178
This study presents the first survey of earthworm species (Oligochaeta) from Benghazi, a Mediterranean coastal city in Libya. A total of three peregrine species were recorded: Allolobophora caliginosa trapezoides, Allolobophora rosea (Family: Lumbricidae), Microscolex dubius (Family: Microscolecidae). Their distribution and density in six habitats (vegetable garden, flower garden, green house, farmland, grassland, plain barren landscape) are discussed in relation to some of the physico-chemical parameters and composition of the soil. 相似文献
54.
Profiles of enzymatic activity in earthworms from zinc, lead and cadmium polluted areas near Olkusz (Poland) 总被引:9,自引:0,他引:9
Łaszczyca P Augustyniak M Babczyńska A Bednarska K Kafel A Migula P Wilczek G Witas I 《Environment international》2004,30(7):901-910
The aim of the study was to determine whether there are signs of adaptation of soil fauna to a gradient of heavy metal contamination. Earthworms Aporrectodea caliginosa, Lumbricus terrestris and Eisenia fetida were collected during the spring and summer of 2000 and 2001 from meadow sites situated between 2 and 32 km from the Bukowno-Olkusz complex of zinc-lead ore mines and smelters. The heavy metal content in the soil near smelters reaches 10,500 mg/kg (d.w.) for Zn, 2600 mg/kg for Pb and 81.9 mg/kg for Cd. The sites differ with respect to species composition of earthworm community, with A. caliginosa being dominant. Complete data was obtained only for A. caliginosa, since other species were not abundant at all investigated sites during the whole period of investigation. The body burdens of Zn, Pb, Cd and Cu in A. caliginosa reached 1500, 100, 220 and 10 microg/g, respectively, in the vicinity of the smelter (2-4 km), and decreased to 400, 2, 36 and 6 microg/g at the most distant site (32 km). Cadmium and lead content was significantly elevated in the whole body of L. terrestris collected at the site 2.5 km distant from the smelters when compared to more distant sites, while in E. fetida only the body burden of cadmium was elevated at the nearest site compared to the next site of transect. Activities of glutathione peroxidase (GPX; EC 1.11.1.9) against hydrogen peroxide (H2O2) or cumene hydroperoxide (cumOOH), glutathione reductase (GR; EC 1.6.4.2), glutathione S-transferase (GST; EC 2.5.1.18) and catalase (CAT; EC 1.11.1.6) were assayed in postmitochondrial supernatant obtained from whole body homogenates. Seasonal and annual variations of enzyme activity were reflected by higher GPX activity in the late summer of 2001 in comparison with the spring and summer of 2000. This may reflect severe drought in the spring and summer of 2000. The activity of both GPX isozymes, GR and GST in A. caliginosa and L. terrestris increased with increasing distance from the smelters and reached maximum at sites III and IV (4 and 8 km from the smelters, respectively) and then it decreased in the animals from site V (32 km). These may be the effects of antagonism between the enzyme inducing and enzyme inhibiting action of smelter emissions, a phenomenon known as a hormetic effect. It is postulated here that this effect is of diagnostic value for metal pollution biomonitoring. 相似文献
55.
José Tomás Albergaria Maria da Conceição M. Alvim-Ferraz Maria Cristina F. Delerue-Matos 《Environmental monitoring and assessment》2010,171(1-4):171-180
The objectives of this work were: (1) to identify an isotherm model to relate the contaminant contents in the gas phase with those in the solid and non-aqueous liquid phases; (2) to develop a methodology for the estimation of the contaminant distribution in the different phases of the soil; and (3) to evaluate the influence of soil water content on the contaminant distribution in soil. For sandy soils with negligible contents of clay and natural organic matter, contaminated with benzene, toluene, ethylbenzene, xylene, trichloroethylene (TCE), and perchloroethylene (PCE), it was concluded that: (1) Freundlich’s model showed to be adequate to relate the contaminant contents in the gas phase with those in the solid and non-aqueous liquid phases; (2) the distribution of the contaminants in the different phases present in the soil could be estimated with differences lower than 10% for 83% of the cases; and (3) an increase of the soil water content led to a decrease of the amount of contaminant in the solid and non-aqueous liquid phases, increasing the amount in the other phases. 相似文献
56.
Bioindicator organisms: Heavy metal pollution evaluation in the Ionian Sea (Mediterranean Sea—Italy)
Trace metal concentrations of mercury, cadmium, lead and chromium in Patella caerulea, and Mullus barbatus were investigated to provide information on pollution of Ionian Sea, since these metals have the highest toxic potential. High chromium levels (0.47–0.97 g g–1 ww) were registered in limpet samples collected from two station near the Gulf of Taranto, while elevated concentration of mercury (0.31–1.50 g g–1 ww) were found in mullet specimens from Sicily. The metal concentrations recorded at the clean stations may be considered as useful background levels to which to refer for comparison within the Mediterranean area. On the contrary, the high levels of chromium and mercury found respectively in the areas near the Gulf of Taranto and at Capo Passero being of concern in terms of environmental health need frequent monitoring. 相似文献
57.
Maria Bargh 《Environment, Development and Sustainability》2014,16(3):459-470
Vandana Shiva has argued that the world is experiencing the triple crises of climate change, peak oil and increasing global food insecurity (Shiva 2008). A Green Economy, which focuses on a “low carbon, resource efficient and socially inclusive economy” (UNEP 2011, 16), has been viewed in some quarters as a way to begin combating the triple crises. In Aotearoa New Zealand, some of the local indigenous peoples Maori are looking at green opportunities, primarily in renewable energy production. Some scholars suggest, however, that the Green Economy should be combined with a Blue Economy. The Blue Economy, as explained by Gunter Pauli 2010, is one which focuses on nature and encourages companies and entrepreneurs to mimic nature in their processes and in the creation of their products. In this article, I suggest that considering a Blue Economy through the lens of a Maori worldview allows us to explore in another way the questions that the Blue Economy raises. 相似文献
58.
Chemical and spectroscopic characterization of organic matter during the anaerobic digestion and successive composting of pig slurry 总被引:1,自引:0,他引:1
Maria Rosaria Provenzano Anna D. Malerba Daniela Pezzolla Giovanni Gigliotti 《Waste management (New York, N.Y.)》2014,34(3):653-660
In this work, anaerobic digestion of pig slurry and successive composting of the digestate after centrifugation were studied by means of chemical analysis, FTIR and fluorescence spectroscopy as excitation–emission matrix (EEM). Chemical analysis highlighted the organic matter transformation occurring during the processes. A decrease of volatile solids and total organic carbon were observed in the digestate with respect to the fresh pig slurry as a consequence of the consumption of sugars, proteins, amino acids and fatty acids used by microorganisms as a C source. Water Extractable Organic Matter (WEOM) was obtained for all samples and fractionated into a hydrophilic and a hydrophobic fraction. The highest WEOM value was found in the pig slurry indicating a high content of labile organic C. The digestate centrifuged and the digestate composted showed lower hydrophilic and higher hydrophobic contents because of the decrease of labile C. Total phenolic content was lower in the digestate with respect to fresh pig slurry sample (36.7%) as a consequence of phenolic compounds degradation. The strong decrease of total reducing sugars in the digestate (76.6%) as compared to pig slurry confirmed that anaerobic process proceed mainly through consumption of sugars which represent a readily available energy source for microbial activity. FTIR spectra of pig slurry showed bands indicative of proteins and carbohydrates. A drop of aliphatic structures and a decrease of polysaccharides was observed after the anaerobic process along with the increase of the peak in the aromatic region. The composted substrate showed an increase of aromatic and a relative decrease of polysaccharides. EEM spectra provided tryptophan:fulvic-like fluorescence ratios which increased from fresh substrate to digestate because of the OM decompostion. Composted substrate presented the lowest ratio due to the humification process. 相似文献
59.
60.
Shimabukuro VG Alexandre NM Coluci MZ Rosecrance JC Gallani MC 《International journal of occupational safety and ergonomics》2012,18(1):15-26
Physical therapists engage in work tasks that expose them to occupational risk factors related to musculoskeletal disorders. Due to the gap in the literature on instruments focused on those workers, this study adapted a job factors questionnaire to physical therapists, and assessed its psychometric properties. The questionnaire was adapted and its content validity was established. The psychometric properties were evaluated among 142 physical therapists. Reliability was verified using the temporal-stability design and internal consistency. Construct validity was assessed with the known-groups technique. Test-retest results demonstrated intraclass correlation coefficients between .82 and .90 (p < .001). Cronbach's α of .91 verified the reliability of the questionnaire. The known-groups technique demonstrated a statistically significant difference on the scores of the items when physical therapists were compared to office workers. The results indicated that the adapted questionnaire had acceptable psychometric properties for assessing problematic job factors among physical therapists working in hospitals. 相似文献