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231.
A dynamic system based on the water/air equilibrium at the interface within the length of a microporous tube has been used to determine experimentally the Henry's law constants (HLC) of two pesticides: metolachlor and diazinon. The measurements were conducted over the temperature range 283-301 K. At 293 K, HLCs values are (42.6+/-2.8) x 10(3) (in units of M atm(-1)) for metolachlor and (3.0+/-0.3)x10(3) for diazinon. The obtained data were used to derive the following Arrhenius expressions: HLC=(3.0+/-0.4) x 10(-11) exp((10,200+/-1,000)/T) for metolachlor and (7.2+/-0.5) x 10(-15) exp((11,900+/-700)/T) for diazinon. At a cumulus cloud temperature of 283 K, the fractions of metolachlor and diazinon in the atmospheric aqueous phase are about 57% and 11% respectively. In order to evaluate the impact of a cloud on the atmospheric chemistry of both studied pesticides, we compare also their atmospheric lifetimes under clear sky (tau(gas)), and cloudy conditions (tau(multiphase)). The calculated multiphase lifetimes (in units of hours) are significantly lower than those in gas phase at a cumulus temperature of 283 K (in parentheses): metolachlor, 0.4 (2.9); diazinon, 1.9 (5.0). 相似文献
232.
Degradation of chlorobenzenes by a strain of Acidovorax avenae isolated from a polluted aquifer 总被引:3,自引:0,他引:3
A subsurface microbial community was isolated from a polluted site of Suquía River (Córdoba-Argentina), acclimated during 15 days in aerobic conditions using 1,2-dichlorobenzene (1,2-DCB) as the sole carbon source. From this acclimated community, we isolated and identified by 16S rDNA analysis a strain of Acidovorax avenae, which was able to perform the complete biodegradation of 1,2-DCB in two days affording stoichiometric amounts of chloride. This pure strain was also tested for biodegradation of chlorobenzene (CB); 1,3-DCB and 1,4-DCB, giving similar results to the experiments using 1,2-DCB. The aromatic-ring-hydroxylating dioxygenase (ARHDO) alpha-subunit gene core, encoding the catalytic site of the large subunit of chlorobenzene dioxygenase, was detected by PCR amplification and confirmed by DNA sequencing. These results suggest that the isolated strain of A. avenae could use a catabolic pathway, via ARHDO system, leading to the formation of chlorocatecols during the first steps of biodegradation, with further chloride release and subsequent paths that showed complete substrate consumption. 相似文献
233.
Luis Lassaletta Héctor García-Gómez Benjamín S. Gimeno José V. Rovira 《Environmental Science & Policy》2010,13(5):423-433
The European Union Water Framework Directive (WFD) aims to achieve the “good status” of waters by 2015, through monitoring and control of human impacts on “bodies of surface water” (BSWs), discrete elements for quality diagnosis and management. Headwater streams, however, are frequently neglected as they are not usually recognised as BSW. This poses limitations for the management of river catchments, because anthropogenic impacts on headwaters can constrain the quality of downstream rivers. To illustrate this problem, we compared nitrate levels and land use pressures in a small agricultural catchment with those recorded in the catchment in which it is embedded (Ega), and in the Ebro River Basin (NE Spain) comprising both. Agriculture greatly influenced water nitrate concentration, regardless of the size of the catchments: R2 = 0.91 for headwater catchments (0.1–7.3 km2), and R2 = 0.82 for Ebro tributary catchments (223–3113 km2). Moreover, nitrate concentration in the outlet of a non-BSW small river catchment was similar to that of the greater downstream BSW rivers. These results are of interest since, despite representing 76% of the length of the Ega catchment hydrographical network, only 3.1% of the length of the headwater streams has been identified as BSWs. Human activities affecting headwater streams should therefore be considered if the 2015 objective of the WFD is to be achieved. 相似文献
234.
Efficiency of white lupin in the removal of mercury from contaminated soils: Soil and hydroponic experiments 总被引:1,自引:0,他引:1
Pilar Zornoz Roc′?o Mill′an M. Jos′e Sierr Almudena Seco Elvira Esteban 《环境科学学报(英文版)》2010,22(3):421-427
This study examined the ability of the white lupin to remove mercury (Hg) from a hydroponic system (Hg concentrations 0, 1.25, 2.5, 5 and 10 μmol/L) and from soil in pots and lysimeters (total Hg concentration (19.2 ± 1.9) mg/kg availability 0.07%, and (28.9 ± 0.4) mg/kg availability 0.09%, respectively), and investigated the accumulation and distribution of Hg in different parts of the plant. White lupin roots efficiently took up Hg, but its translocation to the harvestable parts of the plant was low. The Hg concentration in the seeds posed no risk to human health according to the recommendations of the World Health Organization, but the shoots should not be used as fodder for livestock, at least when unmixed with other fodder crops. The accumulation of Hg in the hydroponically-grown plants was linear over the concentration range tested. The amount of Hg retained in the roots, relative to the shoots, was almost constant irrespective of Hg dose (90%). In the soil experiments, Hg accumulation increased with exposure time and was the greater in the lysimeter than in the pot experiments. Although Hg removal was the greater in the hydroponic system, revealing the potential of the white lupin to extract Hg, bioaccumulation was the greatest in the lysimeter-grown plants; the latter system more likely reflects the true behaviour of white lupin in the field when Hg availability is a factor that limits Hg removal. The present results suggest that the white lupin could be used in long-term soil reclamation strategies that include the goal of profitable land use in Hg-polluted areas. 相似文献
235.
236.
237.
Teresa Pamatz-Bolaños Denis A. Cabrera-Munguia Horacio González Rosa E. Del Río José L. Rico Gabriela Rodríguez-García 《International Journal of Green Energy》2018,15(8):465-472
Caesalpinea eriostachys seed oil, as a source of triglycerides with potential application for biodiesel production in Mexico is introduced. Its lipid profile obtained by Gas Chromatography-Mass Spectrometry (GC-MS) revealed saturated and unsaturated glycerol esters as the constituents. Therefore, heterogeneous and homogeneous catalyzed transesterification reactions were assayed employing ZnAl hydrotalcites and KOH, as the catalysts, respectively. The transesterification reactions yielded 59% for Zn/Al(2), 79% for Zn/Al(4), and 90% for KOH, depicting typical behavior, as in biodiesel production data from literature, where Zn-Al hydrotalcites or KOH were assayed. The caloric, density, viscosity values, and fatty acid methyl esters profile from reaction products were concordant to EN 14214, suggesting C. eriostachys as a promising feedstock for biodiesel production. 相似文献
238.
José María Navas Helmut Segner 《Environmental science and pollution research international》1998,5(2):75-82
A number of natural and man-made chemicals possess antiestrogenic activity, i.e. they antagonize a broad spectrum of estrogen-induced
responses in vertebrates. Examples of antiestrogens include dioxin, furan and PCB congeners, certain PAHs, pesticides and
indol-3-carbinol derivatives. Major mechanisms of antiestrogenicity are antagonistic action of chemicals at the estrogen receptor,
or binding of chemicals to the arylhydrocarbon (Ah) receptor and subsequent interaction with estrogen-responsive genes. Toxicological
consequences resulting from antiestrogenic activity have not been conclusively demonstrated to date, although antiestrogenic
compounds could critically affect sensitive reproductive and developmental processes. 相似文献
239.
Rodolfo Paranhos André P. Pereira Letícia M. Mayr 《Environmental monitoring and assessment》1998,50(2):131-141
The objective is to describe and quantify the diel variability of water quality in a tropical coastal system, Guanabara Bay, Brazil. Water samples were collected in spring and neap tide cycles over 24 h periods at three strategic sites. A pollution gradient was evident between the sampling sites. The average fecal coliform values decreased from 106 (site 3, most polluted) to 101 (site 1, less polluted). Organic matter mineralization was found in a similar gradient to organic pollution. However, complete nitrification was only found associated to regions where the water quality was better. Variability in this data set was determined mostly by the pollution gradient observed, and by tidal influence as well. The poor water quality indicates that the bay undergoes severe environmental stress. However water renewal promoted by tidal action was an important mechanism in diluting the pollution, improving water quality even in ebb tides and in the inner channels. The significance of micro-scale changes in water quality assessment in Guanabara Bay was confirmed, as well as the importance of these strategic sampling sites, reinforcing the importance of these measurements in monitoring programs. 相似文献
240.
Eduardo Soto-Galera Joel Paulo-Maya Eugenia López-López José Angel Serna-Hernández John Lyons 《Environmental management》1999,24(1):133-140
Chirostoma charari and C. compressum, and they are presumed extinct. Twelve (63%) of the remaining species had declines in distribution. Sixteen (80%) of the 20
localities sampled had lost species. The greatest declines occurred in Lago de Cuitzeo proper and in the lower portion of
the Río Grande de Morelia watershed. Species losses from the lake were attributable to drying and hypereutrophication of the
lake because of substantial reductions in the amount and quality of tributary inputs, whereas losses from the Río Grande de
Morelia watershed were the result of pollution from agricultural, municipal, and industrial sources, especially in the region
around the city of Morelia. Three localities in the upper portion of the Río Grande de Morelia watershed—Cointzio reservoir,
La Mintzita spring, and Insurgente Morelos stream—contained most of the remaining fish species diversity in the basin and
deserve additional protection. Fish faunal changes indicated major declines in the health of aquatic ecosystems in the Morelia–Cuitzeo
basin. 相似文献