全文获取类型
收费全文 | 4057篇 |
免费 | 18篇 |
国内免费 | 52篇 |
专业分类
安全科学 | 77篇 |
废物处理 | 137篇 |
环保管理 | 454篇 |
综合类 | 999篇 |
基础理论 | 893篇 |
环境理论 | 3篇 |
污染及防治 | 908篇 |
评价与监测 | 288篇 |
社会与环境 | 359篇 |
灾害及防治 | 9篇 |
出版年
2022年 | 36篇 |
2021年 | 66篇 |
2020年 | 31篇 |
2019年 | 35篇 |
2018年 | 63篇 |
2017年 | 57篇 |
2016年 | 90篇 |
2015年 | 53篇 |
2014年 | 118篇 |
2013年 | 320篇 |
2012年 | 121篇 |
2011年 | 180篇 |
2010年 | 123篇 |
2009年 | 163篇 |
2008年 | 156篇 |
2007年 | 175篇 |
2006年 | 141篇 |
2005年 | 117篇 |
2004年 | 111篇 |
2003年 | 130篇 |
2002年 | 119篇 |
2001年 | 134篇 |
2000年 | 95篇 |
1999年 | 63篇 |
1998年 | 33篇 |
1997年 | 41篇 |
1996年 | 25篇 |
1995年 | 55篇 |
1994年 | 33篇 |
1993年 | 37篇 |
1992年 | 38篇 |
1991年 | 37篇 |
1990年 | 49篇 |
1989年 | 40篇 |
1988年 | 28篇 |
1987年 | 31篇 |
1986年 | 23篇 |
1985年 | 31篇 |
1984年 | 26篇 |
1983年 | 38篇 |
1982年 | 26篇 |
1981年 | 41篇 |
1980年 | 30篇 |
1979年 | 30篇 |
1977年 | 25篇 |
1976年 | 28篇 |
1975年 | 25篇 |
1972年 | 23篇 |
1970年 | 23篇 |
1965年 | 23篇 |
排序方式: 共有4127条查询结果,搜索用时 15 毫秒
161.
Gonzalez-Fernandez O Hidalgo M Margui E Carvalho ML Queralt I 《Environmental pollution (Barking, Essex : 1987)》2008,153(2):476-482
Every year between 8 and 9 millions of vehicles in the European Union arrive to their end of life. Car wastes can have a very high metal content, falling into hazardous waste class. A preliminary evaluation of these wastes could be made by metals' leaching test runs which is the main objective of the present study. Evaluation of the total metal content was carried out by X-ray fluorescence and the mobility of these metals using two simple standardized extractions such as the TCLP (Toxicity Characterisation Leaching Procedure) of the US EPA and the German leaching test DIN 38414-S4. Additionally, an extraction test with acetone was performed in order to recognise metals bounded to organic matter. The results show that the total metal content of the ASR can overpass the established values for inert residues. Lead and zinc contents are fairly well correlated with grain-size, whilst other metals' contents do not exhibit clear grain-size dependence. 相似文献
162.
Long-term survey of heavy-metal pollution, biofilm contamination and diatom community structure in the Riou Mort watershed, South-West France 总被引:4,自引:0,他引:4
Morin S Duong TT Dabrin A Coynel A Herlory O Baudrimont M Delmas F Durrieu G Schäfer J Winterton P Blanc G Coste M 《Environmental pollution (Barking, Essex : 1987)》2008,151(3):532-542
In a metal-polluted stream in the Riou Mort watershed in SW France, periphytic biofilm was analyzed for diatom cell densities and taxonomic composition, dry weight and metal bio-accumulation (cadmium and zinc). Periphytic diatom communities were affected by the metal but displayed induced tolerance, seen through structural impact (dominance of small, adnate species) as well as morphological abnormalities particularly in the genera Ulnaria and Fragilaria. Species assemblages were characterized by taxa known to occur in metal-polluted environments, and shifts in the community structure expressed seasonal patterns: high numbers of Eolimna minima, Nitzschia palea and Pinnularia parvulissima were recorded in Summer and Autumn, whereas the species Surirella brebissonii, Achnanthidium minutissimum, Navicula lanceolata and Surirella angusta were dominant in Winter and Spring. Commonly used indices such as the Shannon diversity index and Specific Pollution Sensitivity Index reflected the level of pollution and suggest seasonal periodicity, the lowest diversities being observed in Summer. 相似文献
163.
Damianovic MH Saia FT Moraes EM Landgraf D Rezende MO Vazoller RF Foresti E 《Journal of environmental science and health. Part. B》2007,42(1):45-52
Wastewater samples from an anaerobic reactor were extracted with hexane and derivatized with diazomethane (method 1) and with acetic anidride (method 2). Gas chromatography with electron-capture detection (ECD) was employed for separating the parent compound and intermediates trichlorophenols (TCP) and dichlorophenols (DCP) which originated from the penta chlorophenol (PCP) degradation process. The relations between concentrations of PCP, TCP and DCP areas were linear in the range of concentrations of 0.2 to 8 mg/L and 0.025 mg/L to 5 mg/L for methods 1 and 2, respectively. The repeatability of the extraction methods was satisfactory, with variation coefficients lower than 11%. For method 1, at the fortification level of 0.2 mg/L, recovery of PCP, TCP, and DCP was 112%, 74% and 45%, respectively. For method 2, the corresponding recovery values at the fortification level of 0.1 mg/L were 91%, 93% and 103%, respectively. Storage of the frozen samples did not alter their PCP determination properties. The chromatographic methods adapted for chlorophenol determination in wastewater were suitable with relatively simple manipulation techniques. The obtained results were reproducible and allowed identification of intermediates formed during the PCP degradation process. 相似文献
164.
The Distribution and Sources of Polycyclic Aromatic Hydrocarbons in Surface Sediments Along the Egyptian Mediterranean Coast 总被引:2,自引:0,他引:2
El Nemr A Said TO Khaled A El-Sikaily A Abd-Allah AM 《Environmental monitoring and assessment》2007,124(1-3):343-359
Coastal marine sediment samples were collected from 31 sampling stations along the Egyptian Mediterranean Sea coast. All sediment
samples were analyzed to determine aliphatic and polycyclic aromatic hydrocarbons (PAHs) as well as total organic carbon (TOC)
contents and grain size analysis. Total concentrations of 16 EPA-PAHs in the sediments were varied from 88 to 6338 ng g−1 with an average value of 154 ng g−1 (dry weight). However, the concentrations of total aliphatic were varied from 1.3 to 69.9 ng g−1 with an average value of 15.6 ng g−1 (dry weight). The highest contents of PAHs were found in the Eastern harbor (6338 ng g−1), Manzala (5206 ng g−1) and El-Jamil East (4895 ng g−1) locations. Good correlations observed between a certain numbers of PAH concentrations allowed to identify its origin. The
average total organic carbon (TOC) percent was varied from 0.91 to 4.54%. Higher concentration of total pyrolytic hydrocarbons
(∑COMB) than total fossil hydrocarbons (∑PHE) declared that atmospheric fall-out is the significant source of PAHs to marine
sediments of the Egyptian Mediterranean coast. The selected marked compounds, a principal component analysis (PCA) and special
PAHs compound ratios (phenanthrene/anthracene vs fluoranthene/pyrene; ∑COMB/∑EPA-PAHs) suggest the pyrogenic origins, especially
traffic exhausts, are the dominant sources of PAHs in most locations. Interferences of rather petrogenic and pyrolytic PAH
contaminations were noticed in the harbors due to petroleum products deliveries and fuel combustion emissions from the ships
staying alongside the quays. 相似文献
165.
Bürger CM Kolditz O Fowler HJ Blenkinsop S 《Environmental pollution (Barking, Essex : 1987)》2007,148(3):842-854
Global climate change may have large impacts on water supplies, drought or flood frequencies and magnitudes in local and regional hydrologic systems. Water authorities therefore rely on computer models for quantitative impact prediction. In this study we present kernel-based learning machine river flow models for the Upper Gallego catchment of the Ebro basin. Different learning machines were calibrated using daily gauge data. The models posed two major challenges: (1) estimation of the rainfall-runoff transfer function from the available time series is complicated by anthropogenic regulation and mountainous terrain and (2) the river flow model is weak when only climate data are used, but additional antecedent flow data seemed to lead to delayed peak flow estimation. These types of models, together with the presented downscaled climate scenarios, can be used for climate change impact assessment in the Gallego, which is important for the future management of the system. 相似文献
166.
To determine the source of dissolved inorganic nitrogen (N) in runoff, approx. 35kg N enriched with the stable isotope (15)N (2110 per thousand delta(15)N) was added to a mature coniferous forested catchment for one whole year. The total N input was approx. 50kg ha(-1) year(-1). The enrichment study was part of a long-term whole-catchment ammonium nitrate addition experiment at G?rdsj?n, Sweden. The (15)N concentrations in precipitation, throughfall, runoff and upper forest floor were measured prior to, during, and 3-9years following the (15)N addition. During the year of the (15)N addition the delta(15)N level in runoff largely reflected the level in incoming N, indicating that the leached NO(3)(-) came predominantly from precipitation. Only 1.1% of the incoming N was lost during the year of the tracer addition. The cumulative loss of tracer N over a 10-year period was only 3.9% as DIN and 1.1% as DON. 相似文献
167.
Jaji MO Bamgbose O Odukoya OO Arowolo TA 《Environmental monitoring and assessment》2007,133(1-3):473-482
The quality of Ogun river in South-West, Nigeria was studied by a field survey for a period of 1 year (covering dry season
and rainy season). Water samples were collected from thirteen sites and analysed for physico-chemical and bacteriological
parameters as well as heavy metals using standard methods. Generally, the values obtained for turbidity, phosphate, oil and
grease, iron and faecal coliform from all the sites in both seasons were above the maximum acceptable limit set by the World
Health Organization (WHO) for drinking water. Also, the manganese content from all the sites in the dry season, lead concentrations
from three sites in the dry season and cadmium concentrations from some sites in both seasons were above the WHO limit. The
values obtained for total dissolved solids, dissolved oxygen and chloride at site M in the dry season and nitrate at site
J in the rainy season were also above the WHO limit. Pollution of Ogun river water along its course is evidenced by the high
concentrations of pollution indicators, nutrients and trace metals above the acceptable limit. This poses a health risk to
several rural communities who rely on the river primarily as their source of domestic water. The study showed a need for continuous
pollution monitoring programme of surface waters in Nigeria. 相似文献
168.
Minero C Maurino V Bono F Pelizzetti E Marinoni A Mailhot G Carlotti ME Vione D 《Chemosphere》2007,68(11):2111-2117
The effect of selected organic and inorganic compounds, present in snow and cloudwater was studied. Photolysis of solutions of nitrate to nitrite was carried out in the laboratory using a UVB light source. The photolysis and other reactions were then modelled. It is shown that formate, formaldehyde, methanesulphonate, and chloride to a lesser extent, can increase the initial formation rate of nitrite. The effect, particularly significant for formate and formaldehyde, is unlikely to be caused by scavenging of hydroxyl radicals. The experimental data obtained in this work suggest that possible causes are the reduction of nitrogen dioxide and nitrate by radical species formed on photooxidation of the organic compounds. Hydroxyl scavenging by organic and inorganic compounds would not affect the initial formation rate of nitrite, but would protect it from oxidation, therefore, increasing the concentration values reached at long irradiation times. The described processes can be relevant to cloudwater and the quasi-liquid layer on the surface of ice and snow, considering that in the polar regions irradiated snow layers are important sources of nitrous acid to the atmosphere. Formate and (at a lesser extent) formaldehyde are the compounds that play the major role in the described processes of nitrite/nitrous acid photoformation by initial rate enhancement and hydroxyl scavenging. 相似文献
169.
The apparent water solubility of pentachlorophenol was measured at pH=6 and at 25 degrees C in pure water, aqueous solutions of three salts (NaCl, KNO(3) and CaCl(2) at 0.010, 0.10 and 1.0M) and in aqueous solutions of three fulvic acids samples extracted from a natural soil (sFA), composted sewage sludge (csFA) and composted livestock's material (lsFA). A solubility enhancement method was developed for the measurement of partition coefficients (K(oc), L/kg organic carbon). Pentachlorophenol associates strongly with the fulvic acid samples and the calculated K(oc) were the following (averages and standard deviations): (sFA) (211+/-22) x 10(2), (csFA) (253+/-26) x 10(2), (lsFA) (235+/-10) x 10(2). For comparison purposes the K(oc) for pyrene were also calculated for the three FA samples and were the following: (sFA) (119+/-10) x 10(2), (csFA) (239+/-21) x 10(2), (lsFA) (92+/-10) x 10(2). The analysis of variance (one-way ANOVA) of the effect of the type of FA sample on the solubilization of pentachlorophenol and pyrene shows that this factor causes significant differences on the aqueous solubilization of these two organic substances. 相似文献
170.
Garcia-Reyero N Grimalt JO Vives I Fernandez P Piña B 《Environmental pollution (Barking, Essex : 1987)》2007,145(3):745-752
Fish muscle extracts from ten European mountain lakes were analyzed for organochlorine compounds (OCs) and estrogenic activity, the latter by a recombinant yeast assay based on the human estrogen receptor. Seventy percent of the samples showed estrogenic activity above detection limits and a subset of five samples showed estrogenic activities, equivalent to more than 10,000 pg/g of estradiol. These highly estrogenic samples occurred in two lakes, Velké Hin?ovo in the Tatra Mountains and Redon in the Pyrenees. Principal component analysis correlated estrogenic activity of muscle extracts to fish age and concentrations of the more chlorinated polychlorobiphenyls (PCBs). This is consistent with previously observed correlations of these PCBs with fish age. In addition, most fish with high estrogenic activity were found in lakes containing high OC levels in the sediments, which gives further ground to atmospheric deposition of anthropogenic pollutants as main process leading to the observed endocrine disruption effects. 相似文献