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21.
The apparent water solubility of pentachlorophenol was measured at pH=6 and at 25 degrees C in pure water, aqueous solutions of three salts (NaCl, KNO(3) and CaCl(2) at 0.010, 0.10 and 1.0M) and in aqueous solutions of three fulvic acids samples extracted from a natural soil (sFA), composted sewage sludge (csFA) and composted livestock's material (lsFA). A solubility enhancement method was developed for the measurement of partition coefficients (K(oc), L/kg organic carbon). Pentachlorophenol associates strongly with the fulvic acid samples and the calculated K(oc) were the following (averages and standard deviations): (sFA) (211+/-22) x 10(2), (csFA) (253+/-26) x 10(2), (lsFA) (235+/-10) x 10(2). For comparison purposes the K(oc) for pyrene were also calculated for the three FA samples and were the following: (sFA) (119+/-10) x 10(2), (csFA) (239+/-21) x 10(2), (lsFA) (92+/-10) x 10(2). The analysis of variance (one-way ANOVA) of the effect of the type of FA sample on the solubilization of pentachlorophenol and pyrene shows that this factor causes significant differences on the aqueous solubilization of these two organic substances. 相似文献
22.
Febros river water was sampled weekly, during 35 successive weeks, and analyzed for microbiological (total coliforms, faecal
coliforms, faecal streptococci and enterococci) and chemical-physical (ammonia and temperature) parameters. All microbiological
parameters were highly correlated with each other and with ammonia, suggesting that the simultaneous determination of all
variables currently in use in the evaluation of the microbiological quality of waters is probably redundant, and could be
simplified, and that ammonia should be tested as a sentinel parameter of the microbiological pollution load of Febros river.
From the strains isolated from positive tubes of the faecal coliforms test (multiple tube fermentation technique) and retested
in this assay, Escherichia coli, Klebsiella oxytoca and Klebsiella pneumoniae subsp. pneumoniae strains were positive, indicating that the faecal coliforms test is not totally specific for Escherichia coli, and can detect other bacteria. Considering that these Klebsiella spp. are not necessarily of faecal origin, it was concluded that the faecal coliforms test can overestimate true faecal pollution.
From the strains isolated from positive tubes of the faecal coliforms procedure, only Escherichia coli strains were clearly positive in the β-D-glucuronidase test. All other species were negative or very weakly positive, suggesting that the assay of the β-D-glucuronidase activity is less prone to false positives than the faecal coliforms test in the quantification of Escherichia coli in environmental waters. 相似文献
23.
Brovini Emília Marques Cardoso Simone Jaqueline Quadra Gabrielle Rabelo Vilas-Boas Jéssica Andrade Paranaíba José R. Pereira Renata de Oliveira Mendonça Raquel Fernandes 《Environmental science and pollution research international》2021,28(43):60635-60648
Environmental Science and Pollution Research - Glyphosate is the most used herbicide worldwide. Many studies have reported glyphosate risks to aquatic organisms of different trophic levels.... 相似文献
24.
Parasite assemblages are increasingly being used as indicators of their hosts’ biology and ecology, especially for economically important marine species such as the Soleidae. In this study, seven species inhabiting Portuguese coastal waters were examined for external and internal macroparasite infections using standard procedures: Dicologlossa cuneata, Microchirus azevia, Microchirus variegatus, Solea lascaris, Solea senegalensis, Solea solea and Synaptura lusitanica. Despite being closely related, these species present different life history patterns and ecological preferences which were expected to be mirrored by their macroparasite assemblages. The aim of the study was, therefore, to study the variation of these assemblages, within and between host species, along the Portuguese coast in order to evaluate the importance of the hosts’ features and environmental factors in the assemblage compositions. Flatfish were obtained seasonally from commercial fishing vessels operating in three areas (northern, central and southern) along the Portuguese coast. Prevalence and mean abundance were calculated and tested for differences between host sex, areas and seasons. The host specificity index and the importance of the host–parasite relationship were computed based on mean abundance. The total number of parasite individuals, species richness, total prevalence, total mean abundance, diversity and evenness were also calculated. A canonical correspondence analysis (CCA) was performed using prevalence and mean abundance data. A total of 44 macroparasite species were found. No significant differences were observed in prevalence and mean abundance between sexes and sampling seasons but, for three of the parasite species, significant differences were found between areas. The highest values of the parasitological and ecological indices were generally registered in the hosts S. lascaris and S. senegalensis and in the southern area. The CCA using the prevalence data revealed the differentiation of S. lascaris samples, which was mainly related to the total prevalence and to the number of important species of macroparasites. When using mean abundance data, the CCA revealed the differentiation of D. cuneata from the south, S. lascaris from the three areas and S. senegalensis from the south, mainly related to total prevalence and richness. The differences found between infection levels and assemblages’ composition were mainly due to differences in hosts’ diet, namely prey type consumption, given that most macroparasites found were transmitted through the food web. However, environmental factors were also important given that they regulate the distribution of ectoparasites and the availability of prey, and therefore the infections’ pattern. These findings were in agreement with the ones from similar studies performed in other species, revealing the importance of parasites as indicators of their hosts’ ecology. 相似文献
25.
Schaeffer Roberto Logan Jeffrey Szklo Alexandre Salem Chandler William de Souza Marques João Carlos 《Mitigation and Adaptation Strategies for Global Change》2001,6(1):47-69
This study analyzes the options for meeting power demand in the Brazilianpower sector through the year 2015. Three policy cases are constructedto test economic and environmental policy measures against a baseline:advanced technologies scenario, environmental control scenario and carbon(C) elimination scenario. Least-cost modeling simulated these scenarios throughchanges in emissions fees and caps, costs for advanced technologies,demand side efficiency, and clean energy supplies. Results show that, in theabsence of alternative policies, new additions to Brazil's electric powersector will shift rapidly from hydroelectricity to combined-cycle natural gasplants. When the cost of environmental impacts are incorporated in theprice of power, the least-cost mix of electric power generation technologycould change in other ways. In all scenarios, energy efficiency andcogeneration play an important role in the least-cost power solution. Savingelectricity through increased efficiency offsets the needs for new supply andhas enormous potential in Brazil's industrial sector. Efficiency also reducesthe environmental burden associated with electricity production andtransmission, without compromising the quality of the services demandedby end users. Interesting enough, carbon dioxide (CO2) emissions will remainrelatively low under almost every conceivable scenario. 相似文献
26.
Timur Deniz Ozer Cinar Ana C Marques C P Leslie Grady 《Water environment research》2006,78(4):340-352
The response of a mixed microbial culture to cyclic aerobic and anoxic (denitrifying) conditions was studied in a chemostat with a 48-hour hydraulic residence time receiving a feed containing benzoate and pyruvate. When the cyclic conditions were 3-hour aerobic and 9-hour anoxic, the bacteria-degraded benzoate aerobically via the catechol 2,3-dioxygenase (C23DO) pathway. The quantity of C23DO remained constant throughout the anoxic period but decreased during the initial portion of the aerobic period before returning to the level present in the anoxic period. Anoxic biodegradation of benzoate was via benzoyl-CoA reductase, which remained constant regardless of the redox condition. The aerobic benzoate uptake capability (AeBUC) of the culture increased during the aerobic period but decreased during the anoxic period. The anoxic benzoate uptake capability (AnBUC) exhibited the opposite response. When the cycle was 6-hour aerobic and 6-hour anoxic, aerobic biodegradation of benzoate proceeded via the protocatechuate 4,5-dioxygenase (P45DO) pathway. The P45DO activity decreased early in the aerobic period, but then increased to the level present during the anoxic period. The level of benzoyl-CoA reductase was constant throughout the cycle. Furthermore, AeBUC and AnBUC responded in much the same way as in the 3/9-hour chemostat. During a 9-hour aerobic and 3-hour anoxic cycle, the culture synthesized both P45DO and C23DO, with the former having significantly higher activity. Unlike the other two cycles, AeBUC changed little during the aerobic period, although AnBUC decreased. The culture was well-adapted to the cyclic conditions as evidenced by the lack of accumulation of either substrate during any cycle tested. This suggests that cyclic aerobic-anoxic processes can be used in industrial wastewater-treatment facilities receiving significant quantities of simple aromatic compounds like benzoate. However, the results showed that the kinetics of benzoate degradation were different under aerobic and anoxic conditions, a situation that must be considered when modeling cyclic bioreactors receiving aromatic compounds. 相似文献
27.
Ivan Viegas Sónia Cotrim Marques Filipa Bessa Ana Lígia Primo Filipe Martinho Ulisses Miranda Azeiteiro Miguel ?ngelo Pardal 《Marine Biology》2012,159(1):33-43
This study provides a comprehensive examination of the life cycle dynamics of the brown shrimp (Crangon crangon L.) in the Mondego estuary, Portugal, a habitat located near the southern edge of the range of this species in European waters.
The phenology of all life stages was documented (from the occurrence of ovigerous females, developing embryos, planktonic
larvae and benthic post-larvae), and migration patterns of larvae into and out of the estuary were examined. Temperature-dependent
functions of egg and larval development were combined with data on field abundance to predict the timing and magnitude of
occurrence of larvae and recruits. Compared to brown shrimp at higher latitudes, southern conspecifics grow slower, mature
earlier and have smaller brood sizes, and larvae have a more protracted settlement period. The Mondego estuary, besides acting
as nursery area, is a dynamic platform for C. crangon to use in different stages, sizes and seasons. 相似文献
28.
Adjusting for the operational environment in studies of performance measurement is very important, otherwise the analysis may lead to unrealistic scores, especially when its influence on costs is high, such as in the water utilities. In this paper, we study the influence of exogenous variables on the water utilities performance by applying conditional efficiency measures based on the order-m method and its probabilistic formulation. We use a sample of 66 water utilities operating between 2002 and 2008, representing about 70% of the Portuguese population. Our research suggests that inefficiency of Portuguese water utilities is substantial for some utilities: several exogenous variables might influence it considerably. For example, regulation has a positive influence on efficiency but when drinking water supply and wastewater services are provided by the same utility or when the wholesale and retail activities are provided together, the performance is lower. The effect of ownership is inconclusive and the variables residential customers, water source, peak factor, and density of customers have a mixed influence on performance which varies according to their scores. 相似文献
29.
Daniela Marques Ana I. Esteves Marise Almeida Joana Xavier Madalena Humanes 《Marine Biology》2008,153(5):807-813
The aim of this work is to investigate the activity of the antioxidant enzyme superoxide dismutase in the cosmopolitan sponge
Cliona celata (Grant, 1826), since this enzyme has been described as a useful biomarker for marine pollution in other marine invertebrates.
The quantification of the catalytic activity for superoxide dismutase is quite complex because its substrate is an unstable
free radical. Several methods have been developed for this enzymatic activity determination; most of them are based on inhibition
of a redox reaction involving the superoxide radical. In this work, two methods are compared, for crude sponge extracts, as
far as repeatability, reproducibility and sensibility are concerned. The adrenaline oxidation method seems to be the most
adequate for these determinations. Statistical treatment of the data indicates that the reference value for the specific superoxide
dismutase activity in C. celata should be in the interval [0–535.5] U/mg of total protein in wet tissues, for normal populations. 相似文献
30.
Richard Roth Paul R. Marques Robert B. VoasAuthor vitae 《Journal of Safety Research》2009,40(6):437-441