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221.
Mary K. Stinson Herbert S. Skovronek William D. Ellis 《Journal of the Air & Waste Management Association (1995)》2013,63(1):96-103
A pilot-scale soil washing process, patented by BioTrol, Inc., was demonstrated on soil contaminated by wood treating waste, primarily pentachlorophenol (PCP) and creosote-derived polynuclear aromatic hydrocarbons (PAHs). Although soil washing was the main object of this demonstration, the treatment train that was evaluated included two other BioTrol technologies for treatment of waste streams from the soil washer. The three technologies were: ? The BioTrol Soil Washer (BSW)—a volume reduction process, which uses water to separate contaminated soil fractions from the bulk of the soil. ? The BioTrol Aqueous Treatment System (BATS)—a biological water treatment process. ? The Slurry Bioreactor (SBR)—a BioTrol biological slurry treatment process conducted in an EIMCO BIOLIFTtm reactor. The sandy soil at the site, consisting of less than 10 percent of fines, was well suited for treatment by soil washing. The soil washer was evaluated in two tests on soil samples containing 130 ppm and 680 ppm of PCP, respectively. The BSW successfully separated the feed soil (dry weight basis) into 83 percent of washed soil, 10 percent of woody residues, and 7 percent of fines. The washed soil retained about 10 percent of the feed soil contamination while 90 percent of the feed soil contamination was contained within the woody residues, fines, and process water. The soil washer achieved up to 89 percent removal of PCP and 88 percent of total PAHs, based on the difference between their levels in the as-is (wet) feed soil and the washed soil. PCP concentrations of 14 ppm and 87ppm in the washed soil were achieved from PCP concentrations of 130 ppm and 680ppm in the feed soil. Concentrations of total PAHs were reduced from 247 ppm to 42 ppm and 404 ppm to 48 ppm, respectively, in the two tests. The BATS degraded up to 94 percent of PCP in the process water from soil washing. PAH removal could not be determined due to low influent concentrations. The SBR achieved over 90 percent removals of PCP and 70 to 90 percent removals of PAHs from the slurry of contaminated fines from soil washing. However, steady state operation was not achieved during the single test and the results were variable. Cost of a commercial-scale soil washing, assuming use of all three technologies, was estimated to be $168 per ton of soil treated. Incineration of woody material accounts for 76 percent of the cost. 相似文献
222.
Christian Seigneur Elpida Constantinou Mary Fend Leonard Levin Lawrence Graft Chris Whipple 《Journal of the Air & Waste Management Association (1995)》2013,63(10):823-830
Abstract The inclusion of non-detected chemicals in a health risk assessment may lead, in some cases, to estimated risks that exceed regulatory thresholds, because one must use the detection limit or half of the detection limit. This study presents a methodology which will allow one to estimate appropriate detection limits by conducting a health risk assessment prior to the source sampling program. The advantages and shortcomings of various levels of detail in the risk assessment to determine those detection limits are discussed. The application of the methodology is demonstrated with a case study of the potential health effects of power plant stack emissions. 相似文献
223.
Steve E. Lindberg George R. Southworth Mary Anna Bogle T.J. Blasing Jim Owens Kelly Roy 《Journal of the Air & Waste Management Association (1995)》2013,63(7):859-869
Abstract Mercury-bearing material enters municipal landfills from a wide array of sources, including fluorescent lights, batteries, electrical switches, thermometers, and general waste; however, the fate of mercury (Hg) in landfills has not been widely studied. Using automated flux chambers and downwind atmospheric sampling, we quantified the primary pathways of Hg vapor releases to the atmosphere at six municipal landfill operations in Florida. These pathways included landfill gas (LFG) releases from active vent systems, passive emissions from landfill surface covers, and emissions from daily activities at each working face (WF). We spiked the WF at two sites with known Hg sources; these were readily detected downwind, and were used to test our emission modeling approaches. Gaseous elemental mercury (Hg0) was released to the atmosphere at readily detectable rates from all sources measured; rates ranged from ~1–10 ng m?2 hr?1 over aged landfill cover, from ~8–20 mg/hr from LFG flares (LFG included Hg0 at μg/m3 concentrations), and from ~200–400 mg/hr at the WF. These fluxes exceed our earlier published estimates. Attempts to identify specific Hg sources in excavated and sorted waste indicated few readily identifiable sources; because of effective mixing and diffusion of Hg0, the entire waste mass acts as a source. We estimate that atmospheric Hg releases from municipal landfill operations in the state of Florida are on the order of 10–50 kg/yr, substantially larger than our original estimates, but still a small fraction of current overall anthropogenic losses. 相似文献
224.
Loss of volatile hydrocarbons from an LNAPL oil source 总被引:1,自引:0,他引:1
Baedecker MJ Eganhouse RP Bekins BA Delin GN 《Journal of contaminant hydrology》2011,126(3-4):140-152
The light nonaqueous phase liquid (LNAPL) oil pool in an aquifer that resulted from a pipeline spill near Bemidji, Minnesota, was analyzed for volatile hydrocarbons (VHCs) to determine if the composition of the oil remains constant over time. Oil samples were obtained from wells at five locations in the oil pool in an anaerobic part of the glacial outwash aquifer. Samples covering a 21-year period were analyzed for 25 VHCs. Compared to the composition of oil from the pipeline source, VHCs identified in oil from wells sampled in 2008 were 13 to 64% depleted. The magnitude of loss for the VHCs analyzed was toluene?o-xylene, benzene, C(6) and C(10-12)n-alkanes>C(7)-C(9)n-alkanes>m-xylene, cyclohexane, and 1- and 2-methylnaphthalene>1,2,4-trimethylbenzene and ethylbenzene. Other VHCs including p-xylene, 1,3,5- and 1,2,3-trimethylbenzenes, the tetramethylbenzenes, methyl- and ethyl-cyclohexane, and naphthalene were not depleted during the time of the study. Water-oil and air-water batch equilibration simulations indicate that volatilization and biodegradation is most important for the C(6)-C(9)n-alkanes and cyclohexanes; dissolution and biodegradation is important for most of the other hydrocarbons. Depletion of the hydrocarbons in the oil pool is controlled by: the lack of oxygen and nutrients, differing rates of recharge, and the spatial distribution of oil in the aquifer. The mass loss of these VHCs in the 5 wells is between 1.6 and 7.4% in 29years or an average annual loss of 0.06-0.26%/year. The present study shows that the composition of LNAPL changes over time and that these changes are spatially variable. This highlights the importance of characterizing the temporal and spatial variabilities of the source term in solute-transport models. 相似文献
225.
Romero-Franco M Hernández-Ramírez RU Calafat AM Cebrián ME Needham LL Teitelbaum S Wolff MS López-Carrillo L 《Environment international》2011,37(5):867-871
Sources of phthalates other than Polyvinyl chloride (PVC) related products are scarcely documented in Mexico. The objective of our study was to explore the association between urinary levels of nine phthalate metabolites and the use of personal care products. Subjects included 108 women who participated as controls in an ongoing population-based case-control study of environmental factors and genetic susceptibility to breast cancer in northern Mexico. Direct interviews were performed to inquire about sociodemographic characteristics, reproductive history, use of personal care products, and diet. Phthalate metabolites measured in urine by high performance liquid chromatography-isotope dilution tandem mass spectrometry were monoethyl phthalate (MEP), monobenzyl phthalate (MBzP), mono-n-butyl phthalate (MBP), mono-isobutyl phthalate (MiBP), mono-3-carboxypropyl phthalate (MCPP) as well as mono-2-ethylhexyl phthalate (MEHP), mono-2-ethyl-5-oxohexyl phthalate (MEOHP), mono-2-ethyl-5-hydroxyhexyl phthalate (MEHHP), mono-2-ethyl-5-carboxypentyl phthalate (MECPP) that are metabolites of di-ethylhexyl phthalate (DEHP). Detectable urinary concentrations of phthalate metabolites varied from 75% (MEHP) to 100% (MEP, MBP, MEOHP, MEHHP and MECPP). Medians of urinary concentrations of some phthalate metabolites were significantly higher among users of the following personal care products compared to nonusers: body lotion (MEHHP, MECPP and sum of DEHP metabolites (ΣDEHP)), deodorant (MEHP and ΣDEHP), perfume (MiBP), anti-aging facial cream (MEP, MBP and MCPP) and bottled water (MCPP, MEHHP and MEOHP). Urinary concentrations of MEP showed a positive relationship with the number of personal care products used. Our results suggest that the use of some personal care products contributes to phthalate body burden that deserves attention due to its potential health impact. 相似文献
226.
Modeling the Relations Between Flow Regime Components,Species Traits,and Spawning Success of Fishes in Warmwater Streams 总被引:1,自引:0,他引:1
Scott W. Craven James T. Peterson Mary C. Freeman Thomas J. Kwak Elise Irwin 《Environmental management》2010,46(2):181-194
Modifications to stream hydrologic regimes can have a profound influence on the dynamics of their fish populations. Using
hierarchical linear models, we examined the relations between flow regime and young-of-year fish density using fish sampling
and discharge data from three different warmwater streams in Illinois, Alabama, and Georgia. We used an information theoretic
approach to evaluate the relative support for models describing hypothesized influences of five flow regime components representing:
short-term high and low flows; short-term flow stability; and long-term mean flows and flow stability on fish reproductive
success during fish spawning and rearing periods. We also evaluated the influence of ten fish species traits on fish reproductive
success. Species traits included spawning duration, reproductive strategy, egg incubation rate, swimming locomotion morphology,
general habitat preference, and food habits. Model selection results indicated that young-of-year fish density was positively
related to short-term high flows during the spawning period and negatively related to flow variability during the rearing
period. However, the effect of the flow regime components varied substantially among species, but was related to species traits.
The effect of short-term high flows on the reproductive success was lower for species that broadcast their eggs during spawning.
Species with cruiser swimming locomotion morphologies (e.g., Micropterus) also were more vulnerable to variable flows during the rearing period. Our models provide insight into the conditions and
timing of flows that influence the reproductive success of warmwater stream fishes and may guide decisions related to stream
regulation and management. 相似文献
227.
INTRODUCTION: This study examines the effects of high-visibility garment design on daytime pedestrian conspicuity in work zones. Factors assessed were garment color, amount of background material, pedestrian arm motion, scene complexity, and driver age. METHOD: The study was conducted in naturalistic conditions on public roads in real traffic. Drivers drove two passes on a 31-km route and indicated when they detected pedestrians outfitted in the fluorescent garments. The locations of the vehicle and the pedestrian were recorded. RESULTS: Detection distances between fluorescent yellow-green and fluorescent red-orange garments were not significantly different, nor were there any significant two-way interactions involving garment color. Pedestrians were detected at longer distances in lower complexity scenes. Arm motion significantly increased detection distances for pedestrians wearing a Class 2 vest, but had little added benefit on detection distances for pedestrians wearing a Class 2 jacket. DISCUSSION: Daytime detection distances for pedestrians wearing Class 2 or Class 3 garments are longest when the complexity of the surround is low. The more background information a driver has to search through, the longer it is likely to take the driver to locate a pedestrian--even when wearing a high-visibility garment. IMPACT ON INDUSTRY: These findings will provide information to safety garment manufacturers about characteristics of high-visibility safety garments which make them effective for daytime use. 相似文献
228.
Permeable grass-covered surfaces can reduce the quantity of storm water runoff and filter out potentially harmful chemicals. The objective of this study was to develop permeable structural soils that sustained healthy turf growth and filtered heavy metals from contaminated pavement runoff. The basic soil medium was a 50:50 mixture (v/v) of expanded shale (ExSh) and quartz sand (QS). The ExSh component consisted of (i) large-diameter particles (3-6 mm), (ii) small-diameter particles (1-3 mm), or (iii) a 50:50 mixture (v/v) of the two. The basic blends were mixed with 0, 10, and 20% sphagnum peat moss (v/v) and 0, 10, and 20% natural zeolites (v/v) and placed in 15-cm-diameter pots in a greenhouse. Bermudagrass plugs were planted in each pot. The addition of sphagnum peat moss to the basic ExSh/QS blend increased bermudagrass growth and improved plant response to added fertilizer. Zeolites had no significant effect on plant growth in the absence of sphagnum peat moss. Growing mediums that contained 10 to 20% sphagnum peat moss and 10 to 20% zeolites consistently produced more bermudagrass biomass than the unamended ExSh/QS mixture. Changing the ratio of small- to large-diameter ExSh in the basic medium did not affect bermudagrass yield. Very low amounts of Cd, Cu, Pb, and Zn were recovered in leachate after the addition of 10 mg metal per pot, suggesting that most heavy metals (>99%) were retained in the growing mediums. Zeolites reduced the amount of Cd and Pb in leachate water, but not Cu or Zn. 相似文献
229.
Báez-Cazull SE McGuire JT Cozzarelli IM Voytek MA 《Journal of environmental quality》2008,37(1):30-46
Determining the processes governing aqueous biogeochemistry in a wetland hydrologically linked to an underlying contaminated aquifer is challenging due to the complex exchange between the systems and their distinct responses to changes in precipitation, recharge, and biological activities. To evaluate temporal and spatial processes in the wetland-aquifer system, water samples were collected using cm-scale multi-chambered passive diffusion samplers (peepers) to span the wetland-aquifer interface over a period of 3 yr. Samples were analyzed for major cations and anions, methane, and a suite of organic acids resulting in a large dataset of over 8000 points, which was evaluated using multivariate statistics. Principal component analysis (PCA) was chosen with the purpose of exploring the sources of variation in the dataset to expose related variables and provide insight into the biogeochemical processes that control the water chemistry of the system. Factor scores computed from PCA were mapped by date and depth. Patterns observed suggest that (i) fermentation is the process controlling the greatest variability in the dataset and it peaks in May; (ii) iron and sulfate reduction were the dominant terminal electron-accepting processes in the system and were associated with fermentation but had more complex seasonal variability than fermentation; (iii) methanogenesis was also important and associated with bacterial utilization of minerals as a source of electron acceptors (e.g., barite BaSO(4)); and (iv) seasonal hydrological patterns (wet and dry periods) control the availability of electron acceptors through the reoxidation of reduced iron-sulfur species enhancing iron and sulfate reduction. 相似文献
230.
This study was conducted to assess the effects of a one time embryonic exposure to trenbolone acetate on reproductive development and function in Japanese quail (Coturnix japonica). Embryos were exposed to either 0.05, 0.5, 5, or 50microg trenbolone or a sesame oil vehicle control at embryonic day 4. Onset of puberty, gonadal histopathology, sperm motility, cloacal gland size, and male copulatory behavior were assessed in adults. Trenbolone delayed onset of puberty in males, inhibited cloacal gland development, and reduced male reproductive behaviors. Industry laboratories have shown trenbolone acetate to be non-teratogenic in mammalian studies. Our study, however, shows that this one time in ovo exposure delayed onset of puberty in and suppressed adult copulatory behavior in quail males. These results suggest that this one time embryonic exposure to trenbolone may have disrupted development of either the central nervous system or the hypothalamic-pituitary-gonadal axis. This is the first study to demonstrate a demasculinizing effect on copulatory behavior in Japanese quail from embryonic exposure to a non-aromatizable androgenic chemical. More studies are needed to determine the mechanisms behind the observed effects. 相似文献