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141.
Morville S Scheyer A Mirabel P Millet M 《Environmental science and pollution research international》2006,13(2):83-89
Goal, Scope and Background Atmospheric sampling (gas and particles) of 5 phenols (phenol, m-cresol, p-cresol, o-cresol, pentachlorophenol) and 15 nitrophenols
(3-methyl-2-nitrophenol, 3-nitrophenol, 4-methyl-2-nitrophenol, 5-methyl-2-nitrophenol, 2-methyl-3nitrophenol, 3-methyl-4-nitrophenol,
2,6-dinitrophenol, bromoxynil, 2,5-dinitrophenol, 2,6-dinitro-p-cresol, 2,4-dinitrophenol, ioxynil, DNOC, 3,4-dinitrophenol,
dinoseb) on XAD-2 resin (20 gr) and glass fibre filters, respectively, were performed in 2002 by using 'Digitel DA80' high
volume samplers. These measurements were undertaken in order to show spatial and geographical variations of concentrations
and the role of traffic in the emissions of these compounds to the atmosphere.
Methods Sampling were performed in Strasbourg (eastern France), in its vicinity (Schiltigheim) and in Erstein. Sites were chosen
to be representative of urban (Strasbourg), suburban (Schiltigheim) and rural (Erstein) conditions. Field campaigns were undertaken
simultaneously in urban and suburban sites during all the seasons during 4 hours at a flow rate of 60 m3.h-1, which gives
a total of 240 m3 of air per sample. Period of sampling varied between 06h00 to 10h00, 11h00 to 15h00 and 18h00 to 22h00 in
order to evaluate a variation of concentration during automobile traffic between urban, suburban and rural areas. Gas and
particle samples were separately Soxhlet extracted for 12 h with a mixture of CH2Cl2 / n-hexane (50:50 v/v), concentrated
to about 1 mL with a rotary evaporated and finally dried under nitrogen. Dry extracts were dissolved in 1 mL of CH3CN. Before
analysis, extracts were sylilated by using MTBSTFA. Analysis was performed by GC/MSD in the SIM mode.
Results and Discussion Partitioning of phenolic compounds between gas and particle phases seems to be mainly correlated with vapour pressure. Among
phenolic compounds analysed, phenol, p-cresol, pentachlorophenol and 2.4-dinitrophenol were detected in all samples and emissions
from traffic seems to be the major source for the presence of these compounds to the atmosphere. No increase of concentrations
in autumn tend to confirm this hypothesis since, with the use of domestic heating in colder months, increases of PAHs concentrations
were observed and these compounds are known to be emitted by all combustion processes.
Pentachlorophenol is a special case since this molecule is only used as wood preservative. Its presence in all atmospheric
samples, whatever the locations and the period of time is the consequence of its persistence.
Conclusions and Perspectives These measurements demonstrate that phenols and nitrophenols are emitted to the atmosphere and further measurements, in order
to confirm their sources, their behaviour and their potential impact to the air quality and to human health should be undertaken
especially since the literature collected is relatively old. Concentrations of pentachlorophenol measured are very low and,
due to its toxicity, further investigations should be undertaken.
- * The basis of this peer-reviewed paper is a presentation at the 9th FECS Conference on 'Chemistry and Environment', 29 August
to 1 September 2004, Bordeaux, France. 相似文献