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251.
T.J. Wallington M.D. Hurley O.J. Nielsen 《Atmospheric environment (Oxford, England : 1994)》2009,43(27):4247-4249
The infrared spectrum of HCF2OCF2OCF2CF2OCF2H (CAS# 188690-77-9) has been re-measured. The integrated absorption intensity over the range 1000–1500 cm?1 measured in the present work is (6.65 ± 0.33) × 10?17 cm2 molecule?1 cm?1 in 700 Torr of air at 296 K. The radiative efficiency of HCF2OCF2OCF2CF2OCF2H is calculated to be 1.02 W m?2 ppb?1. The value reported in the 2007 Intergovernmental Panel on Climate Change (IPCC) report is approximately 35% larger reflecting what we believe to be an erroneously high value for the absorption strength of HCF2OCF2OCF2CF2OCF2H adopted by the IPCC. 相似文献
252.
Susceptibility indexing method for irrigation water management planning: applications to K. Menderes river basin, Turkey 总被引:2,自引:0,他引:2
A susceptibility indexing method was developed based on vulnerability and quality indices. The contamination susceptibility index (SI) at a given location was calculated by taking the product of the vulnerability index (VI) and the quality index (QI): SI = VI × QI. This method incorporates both hydrogeological and hydrochemical data for a comprehensive index mapping. The DRASTIC index methodology was used for the hydrogeological data evaluations. The quality index calculation procedure based on a water quality classification scheme was introduced to evaluate hydrochemical data. The suggested susceptibility indexing method was applied to the Küçük Menderes river basin located in western Turkey. The susceptibility index map shows both hydrogeological and hydrochemical data related to the contamination problem including areas that should be taken into consideration during water management planning. The index map indicates that the most susceptible groundwater is located along the river channel between Kiraz and Tire towns, in the Selçuk area and along the Fertek stream channel to the north of Torbal? town. The results indicate that the incorporation of both hydrogeological and hydrochemical datasets enables more realistic evaluations than those of an individual dataset to estimate the groundwater contamination susceptibility of an aquifer. The numerical procedure applied could be extended further by including other parameters such as retardation, potential contaminant sources, etc. that affect the water quality in a given basin. 相似文献
253.
There is growing concern that recreational shoreline angling activity may negatively impact littoral and riparian habitats
independent of any direct or indirect influences of fish harvest or fishing mortality through mechanisms such as disturbance
(e.g., trampling, erosion) and pollution (e.g., littering). We sampled a suite of aquatic and terrestrial variables (i.e.,
water quality, aquatic and terrestrial macrophytes, soil compaction, anthropogenic refuse) at 14 high shoreline angling-activity
sites (identified by way of interviews with conservation officers and angling clubs) within an urban area (Ottawa, Canada).
For each high angling-activity site, a nearby corresponding low angling-activity site was sampled for comparison. We found
that the percentage of barren area and soil compaction were greater in areas of high angling activity compared with areas
that experienced relatively low angling activity. In addition, terrestrial and aquatic macrophyte density, height, and diversity
were lower at high angling-activity sites. Angling- and non-angling-related litter was present in large quantities at each
of the high angling-activity sites, and comparatively little litter was found at low angling-activity sites. Collectively,
these findings indicate that shoreline angling does alter the riparian environment, contributing to pollution and environmental
degradation in areas of high angling intensity. With growing interest in providing urban angling opportunities and in response
to increasing interest in developing protected areas and parks, a better understanding of the ecologic impacts of shoreline
angling is necessary to address multiuser conflicts, to develop angler outreach and educational materials, and to optimize
management of angling effort to maintain ecologic integrity of riparian and aquatic ecosystems. 相似文献
254.
This article analyzes and carries out an econometric test of the explanatory power of economic and attitude variables for
occurrences of the nonnative signal crayfish in Swedish waters. Signal crayfish are a carrier of plague which threatens the
native noble crayfish with extinction. Crayfish are associated with recreational and cultural traditions in Sweden, which
may run against environmental preferences for preserving native species. Econometric analysis is carried out using panel data
at the municipality level with economic factors and attitudes as explanatory variables, which are derived from a simple dynamic
harvesting model. A log-normal model is used for the regression analysis, and the results indicate significant impacts on
occurrences of waters with signal crayfish of changes in both economic and attitude variables. Variables reflecting environmental
and recreational preferences have unexpected signs, where the former variable has a positive and the latter a negative impact
on occurrences of waters with signal crayfish. These effects are, however, counteracted by their respective interaction effect
with income. 相似文献
255.
Among all emerging substances in water, pharmaceutical products (PPs) and residues are a lot of concern. These last two years, the number of studies has increased drastically, however much less for water resources and drinking water than for wastewater. This literature review based on recent works, deals with water resources (surface or groundwater), focusing on characteristics, occurrence and fate of numerous PPs studied, and drinking water including water quality. Through this review, it appears that the pharmaceutical risk must be considered even in drinking water where concentrations are very low. Moreover, there is a lack of research for by-products (metabolites and transformation products) characterization, occurrence and fate in all water types and especially in drinking water. 相似文献
256.
Daniel Q. Tong Nicholas Z. Muller Haidong Kan Robert O. Mendelsohn 《Environment international》2009,35(8):1109-1117
Human exposure to ambient ozone (O3) has been linked to a variety of adverse health effects. The ozone level at a location is contributed by local production, regional transport, and background ozone. This study combines detailed emission inventory, air quality modeling, and census data to investigate the source–receptor relationships between nitrogen oxides (NOx) emissions and population exposure to ambient O3 in 48 states over the continental United States. By removing NOx emissions from each state one at a time, we calculate the change in O3 exposures by examining the difference between the base and the sensitivity simulations. Based on the 49 simulations, we construct state-level and census region-level source–receptor matrices describing the relationships among these states/regions. We find that, for 43 receptor states, cumulative NOx emissions from upwind states contribute more to O3 exposures than the state's own emissions. In-state emissions are responsible for less than 15% of O3 exposures in 90% of U.S. states. A state's NOx emissions can influence 2 to 40 downwind states by at least a 0.1 ppbv change in population-averaged O3 exposure. The results suggest that the U.S. generally needs a regional strategy to effectively reduce O3 exposures. But the current regional emission control program in the U.S. is a cap-and-trade program that assumes the marginal damage of every ton of NOx is equal. In this study, the average O3 exposures caused by one ton of NOx emissions ranges from ? 2.0 to 2.3 ppm-people-hours depending on the state. The actual damage caused by one ton of NOx emissions varies considerably over space. 相似文献
257.
258.
Species composition of fishes was studied in rivers (capture sites) inhabited by the riffle minnow. In some localities, this species proved to occupy a leading position in the ichthyofauna, being obviously dominant. In small rivers, 16 species were caught together with it, including seven species regularly occurring in catches. The relative abundance of riffle minnow showed a moderate positive correlation with that of the gudgeon (0.568) and a nonsignificant negative correlation (?0.399) with that of the bleak. It is probable that the population dynamics of riffle minnow are determined mainly by natural intraspecific mechanisms rather than by water quality, which has changed only slightly in the rivers studied. 相似文献
259.
Shadi Dayyani Chandra A. Madramootoo Peter Enright Guillaume Simard Apurva Gullamudi Shiv O. Prasher Ali Madani 《Journal of the American Water Resources Association》2009,45(3):779-792
Abstract: The hydrologic performance of DRAINMOD 5.1 was assessed for the southern Quebec region considering freezing/thawing conditions. A tile drained agricultural field in the Pike River watershed was instrumented to measure tile drainage volumes. The model was calibrated using water table depth and subsurface flow data over a two‐year period, while another two‐year dataset served to validate the model. DRAINMOD 5.1 accurately simulated the timing and magnitude of subsurface drainage events. The model also simulated the pattern of water table fluctuations with a good degree of accuracy. The R2 between the observed and simulated daily WTD for calibration was >0.78, and that for validation was 0.93. The corresponding coefficients of efficiency (E) were >0.74 and 0.31. The R2 and E values for calibration/validation of subsurface flow were 0.73/0.48 and 0.72/0.40, respectively. DRAINMOD simulated monthly subsurface flow quite accurately (E > 0.82 and R2 > 0.84). The model precisely simulated daily/monthly drain flow over the entire year, including the winter months. Thus DRAINMOD 5.1 performed well in simulating the hydrology of a cold region. 相似文献
260.
Polybrominated diphenyl ethers (PBDEs) in leachates from selected landfill sites in South Africa 总被引:2,自引:0,他引:2
The last few decades have seen dramatic growth in the scale of production and the use of polybrominated diphenyl ethers (PBDEs) as flame retardants. Consequently, PBDEs such as BDE -28, -47, -66, -71, -75, -77, -85, -99, -100, -119, -138, -153, -154, and -183 have been detected in various environmental matrices. Generally, in South Africa, once the products containing these chemicals have outlived their usefulness, they are discarded into landfill sites. Consequently, the levels of PBDEs in leachates from landfill sites may give an indication of the general exposure and use of these compounds. The present study was aimed at determining the occurrence and concentrations of most common PBDEs in leachates from selected landfill sites. The extraction capacities of the solvents were also tested. Spiked landfill leachate samples were used for the recovery tests. Separation and determination of the PBDE congeners were carried out with a gas chromatograph equipped with Ni63 electron capture detector. The mean percentage recoveries ranged from 63% to 108% (n=3) for landfill leachate samples with petroleum ether giving the highest percentage extraction. The mean concentrations of PBDEs obtained ranged from ND to 2670pgl(-1), ND to 6638pgl(-1), ND to 7230pgl(-1), 41 to 4009pgl(-1), 90 to 9793pgl(-1) for the Garankuwa, Hatherly, Kwaggarsrand, Soshanguve and Temba landfill sites, respectively. Also BDE -28, -47, -71 and BDE-77 were detected in the leachate samples from all the landfill sites; and all the congeners were detected in two of the oldest landfill sites. The peak concentrations were recorded for BDE-47 at three sites and BDE-71 and BDE-75 at two sites. The highest concentration, 9793+/-1.5pgl(-1), was obtained for the Temba landfill site with the highest BOD value. This may suggest some influence of organics on the level of PBDEs. Considering the leaching characteristics of brominated flame retardants, there is a high possibility that with time these compounds may infiltrate into the groundwater around the sites since most of the sites are not adequately lined. 相似文献