Neutralisation of an acidic pit lake by alkaline waste products

A former open pit where black shale (alum shale) was excavated during 1942–1965 has been water filled since 1966. The water chemistry was dominated by calcium and sulphate and had a pH of 3.2–3.4 until 1997–1998, when pH was gradually increasing. This was due to the intrusion of leachates from alkaline cement waste deposited close to the lake. A stable pH of around 7.5 was obtained after 6–7 years. The chemistry of the pit lake has changed due to the neutralisation. Concentrations of some dissolved metals, notably zinc and nickel, have gone down, as a result of adsorption/co-precipitation on solid phases (most likely iron and aluminium hydroxides), while other metals, notably uranium and molybdenum, are present at elevated levels. Uranium concentration is reaching a minimum of around pH 6.5 and is increasing at higher pH, which may indicate a formation of neutral and anionic uranyl carbonate species at high pH (and total carbonate levels around 1 mM). Weathering of the water-exposed shale is still in progress.     

Critical Anthropomorphism and Animal Ethics

Anthropomorphism has long been considered a cardinal error when describing animals. Ethicists have feared the consequences of misrepresenting animals in their reasoning. Recent research within human-animal studies, however, has sophisticated the notion of anthropomorphism. It is suggested that avoiding anthropomorphism merely creates other morphisms, such as mechanomorphism. Instead of avoiding anthropomorphism, it is argued that it is a communicative strategy that should be used critically. Instances of anthropomorphism in animal ethics are analyzed in this paper. Some analogies made between people and non-human animals in present theories of animal ethics are clear instances of psychological anthropomorphism. Other analogies are implicit cases of cultural anthropomorphism. It is argued that animal ethics needs to take the wider discourse of critical anthropomorphism into account in order to sophisticate the understanding and use of anthropomorphic projections. Anthropomorphism is an efficient tool of communication, and it may be made an adequate one as well.     

The legitimacy of leadership in international climate change negotiations

Leadeship is an essential ingredient in reaching international agreements and overcoming the collective action problems associated with responding to climate change. In this study, we aim at answering two questions that are crucial for understanding the legitimacy of leadership in international climate change negotiations. Based on the responses of the three consecutive surveys distributed at COPs 14-16, we seek first to chart which actors are actually recognized as leaders by climate change negotiation participants. Second, we aim to explain what motivates COP participants to support different actors as leaders. Both these questions are indeed crucial for understanding the role, importance, and legitimacy of leadership in the international climate change regime. Our results show that the leadership landscape in this issue area is fragmented, with no one clear-cut leader, and strongly suggest that it is imperative for any actor seeking recognition as climate change leader to be perceived as being devoted to promoting the common good.     

Indications of Recovery from Hypoxia in the Inner Stockholm Archipelago

Improved benthic conditions compared to the 1990s were found during benthic investigations, including sediment and benthic macrofauna in the inner Stockholm archipelago during 2008. In the 1990s, these areas were dominated by black and laminated surface sediments and very sparse fauna. A clear relationship was found when comparing sediment status with the benthic macrofauna. Reduced surface sediment and impoverished macroinvertebrate community was only found at one sampling station representing an enclosed part of the inner archipelago, whereas the other seven stations, with depths ranging from 20 to 50 m, had oxidized surface sediments and considerable biomasses of benthic macrofauna (6–65 g m⁻²) dominated by the invading polychaete Marenzelleria neglecta. An extrapolation of the results shows that, within the investigated area, the coverage of reduced surface sediments had decreased from approximately 17% in the late 1990s to 4% in 2008.     

Inter-laboratory exercise on steroid estrogens in aqueous samples

An inter-laboratory comparison exercise was organized among European laboratories, under the aegis of EU COST Action 636: “Xenobiotics in Urban Water Cycle”. The objective was to evaluate the performance of testing laboratories determining “Endocrine Disrupting Compounds” (EDC) in various aqueous matrices. As the main task three steroid estrogens: 17α-ethinylestradiol, 17β-estradiol and estrone were determined in four spiked aqueous matrices: tap water, river water and wastewater treatment plant influent and effluent using GC-MS and LC-MS/MS. Results were compared and discussed according to the analytical techniques applied, the accuracy and reproducibility of the analytical methods and the nature of the sample matrices. Overall, the results obtained in this inter-laboratory exercise reveal a high level of competence among the participating laboratories for the detection of steroid estrogens in water samples indicating that GC-MS as well as LC-MS/MS can equally be employed for the analysis of natural and synthetic hormones.     

Road dust emissions from paved roads measured using different mobile systems

Very few real-world measurements of road dust suspension have been performed to date. This study compares two different techniques (referred to as Sniffer and Emma) to measure road dust emissions. The main differences between the systems are the construction of the inlet, different instruments for recording particulate matter (PM) levels, and different loads on the wheel axes (the weight of Sniffer was much higher than that of Emma). Both systems showed substantial small-scale variations of emission levels along the road, likely depending on-road surface conditions. The variations observed correlated quite well, and the discrepancies are likely a result of variations in dust load on the road surface perpendicular to the driving direction that cause variations in the measurements depending on slightly different paths driven by the two vehicles. Both systems showed a substantial influence on the emission levels depending on the type of tire used. The summer tire showed much lower suspension than the winter tires (one nonstudded and one studded). However, the relative importance of the nonstudded versus studded tire was rather different. For the ratio of studded/nonstudded, Emma shows higher values on all road sections compared with Sniffer. Both techniques showed increased emission levels with increasing vehicle speed. When the speed increased from 50 to 80 km hr(-1), the relative concentrations increased by 30-170% depending on the tire type and dust load. However, for road sections that were very dirty, Sniffer showed a much higher relative increase in the emission level with the nonstudded tire. Sniffer's absolute concentrations were mostly higher than Emma's. Possible reasons for the differences are discussed in the paper. Both systems can be used for studying relative road dust emissions and for designing air quality management strategies.     

Conditioning sulfidic mine waste for growth of Agrostis capillaris—impact on solution chemistry

Contamination of the environment due to mining and mineral processing is an urgent problem worldwide. It is often desirable to establish a grass cover on old mine waste since it significantly decreases the production of leachates. To obtain sustainable growth, it is often necessary to improve several properties of the waste such as water-holding capacity, nutrient status, and toxicity. This can be done by addition of organic materials such as wood residues, e.g., compost. In this study, we focus on the solution chemistry of the leachates when a substrate containing historic sulfidic mine waste mixed with 30 % (volume) bark compost is overgrown by Agrostis capillaris. The pot experiments also included other growth-promoting additives (alkaline material, mycorrhiza, and metabolizable carbon) to examine whether a more sustainable growth could be obtained. Significant changes in the plant growth and in the leachates composition were observed during 8 weeks of growth. It was concluded that in this time span, the growth of A. capillaris did not affect the composition of the leachates from the pots. Instead, the composition of the leachates was determined by interactions between the bark compost and the mine waste. Best growth of A. capillaris was obtained when alkaline material and mycorrhiza or metabolizable carbon was added to the substrate.     

Comparison of static and mineralogical ARD prediction methods in the Nordic environment

Acid rock drainage (ARD) is a major problem related to the management of mining wastes, especially concerning deposits containing sulphide minerals. Commonly used tests for ARD prediction include acid–base accounting (ABA) tests and the net acid generation (NAG) test. Since drainage quality largely depends on the ratio and quality of acid-producing and neutralising minerals, mineralogical calculations could also be used for ARD prediction. In this study, several Finnish waste rock sites were investigated and the performance of different static ARD test methods was evaluated and compared. At the target mine sites, pyrrhotite was the main mineral contributing to acid production (AP). Silicate minerals were the main contributors to the neutralisation potential (NP) at 60% of the investigated mine sites. Since silicate minerals appear to have a significant role in ARD generation at Finnish mine waste sites, the behaviour of these minerals should be more thoroughly investigated, especially in relation to the acid produced by pyrrhotite oxidation. In general, the NP of silicate minerals appears to be underestimated by laboratory measurements. For example, in the NAG test, the slower-reacting NP-contributing minerals might require a longer time to react than is specified in the currently used method. The results suggest that ARD prediction based on SEM mineralogical calculations is at least as accurate as the commonly used static laboratory methods.     

Quantification of the resource recovery potential of municipal solid waste incineration bottom ashes

Municipal solid waste incineration (MSWI) plays an important role in many European waste management systems. However, increasing focus on resource criticality has raised concern regarding the possible loss of critical resources through MSWI. The primary form of solid output from waste incinerators is bottom ashes (BAs), which also have important resource potential. Based on a full-scale Danish recovery facility, detailed material and substance flow analyses (MFA and SFA) were carried out, in order to characterise the resource recovery potential of Danish BA: (i) based on historical and experimental data, all individual flows (representing different grain size fractions) within the recovery facility were quantified, (ii) the resource potential of ferrous (Fe) and non-ferrous (NFe) metals as well as rare earth elements (REE) was determined, (iii) recovery efficiencies were quantified for scrap metal and (iv) resource potential variability and recovery efficiencies were quantified based on a range of ashes from different incinerators. Recovery efficiencies for Fe and NFe reached 85% and 61%, respectively, with the resource potential of metals in BA before recovery being 7.2%ww for Fe and 2.2%ww for NFe. Considerable non-recovered resource potential was found in fine fraction (below 2 mm), where approximately 12% of the total NFe potential in the BA were left. REEs were detected in the ashes, but the levels were two or three orders of magnitude lower than typical ore concentrations. The lack of REE enrichment in BAs indicated that the post-incineration recovery of these resources may not be a likely option with current technology. Based on these results, it is recommended to focus on limiting REE-containing products in waste for incineration and improving pre-incineration sorting initiatives for these elements.     

By-Catch Impacts in Fisheries: Utilizing the IUCN Red List Categories for Enhanced Product Level Assessment in Seafood LCAs

Overexploitation of fish stocks causes concern not only to fisheries managers and conservation biologists, but also engages seafood consumers; more integrated product perspectives would be useful. This could be provided by life cycle assessment (LCA); however, further complements of present LCA methodology are needed to assess seafood production, one being by-catch impacts. We studied the scientific rationale behind using the IUCN Red List of Threatened Species? for assessment of impacts relating to fish species’ vulnerability. For this purpose, the current Red List status of marine fish in Sweden was compared to the advice given in fisheries as well as key life history traits known to indicate sensitivity to high fishing pressure. Further, we quantified the amount of threatened fish (vulnerable, endangered, or critically endangered) that was discarded in demersal trawl fisheries on the Swedish west coast. The results showed that not only did the national Red List of marine fish have a high consistency with advice given in fisheries and indices of vulnerability, the different fishing practices studied were also found to have vastly different amounts of threatened fish discarded per kilo landing. The suggested approach is therefore promising as a carrier of aggregated information on the extent to which seafood production interferes with conservation priorities, in particular for species lacking adequate stock assessment. To enable extensive product comparisons, it is important to increase coverage of fish species by the global IUCN Red List, and to reconsider the appropriate assessment unit (species or stocks) in order to avoid false alarms.