全文获取类型
收费全文 | 170篇 |
免费 | 0篇 |
国内免费 | 1篇 |
专业分类
安全科学 | 4篇 |
废物处理 | 17篇 |
环保管理 | 16篇 |
综合类 | 16篇 |
基础理论 | 26篇 |
环境理论 | 2篇 |
污染及防治 | 65篇 |
评价与监测 | 16篇 |
社会与环境 | 8篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 1篇 |
2022年 | 2篇 |
2021年 | 2篇 |
2020年 | 2篇 |
2019年 | 6篇 |
2018年 | 8篇 |
2017年 | 6篇 |
2016年 | 9篇 |
2015年 | 5篇 |
2014年 | 7篇 |
2013年 | 13篇 |
2012年 | 5篇 |
2011年 | 12篇 |
2010年 | 9篇 |
2009年 | 5篇 |
2008年 | 6篇 |
2007年 | 7篇 |
2006年 | 7篇 |
2005年 | 7篇 |
2004年 | 9篇 |
2003年 | 11篇 |
2002年 | 9篇 |
2001年 | 2篇 |
2000年 | 5篇 |
1999年 | 1篇 |
1998年 | 3篇 |
1997年 | 1篇 |
1996年 | 4篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
排序方式: 共有171条查询结果,搜索用时 15 毫秒
41.
The effect of light and iron(II)/iron(III) on the distribution of Tl(I)/Tl(III) in fresh water systems 总被引:1,自引:0,他引:1
The distribution of aqueous Tl(I)/Tl(III) as a function of light exposure and solution properties was studied by quantifying the oxidation states after separation with ion chromatography and on-line detection with ICP-MS. Ultraviolet irradiation of aqueous solutions containing 1 microg l(-1) Tl(III) and in equilibrium with the atmosphere increases the reduction rate. In systems with photoreduction of Fe(III)(aq) a quantitative oxidation of Tl(I)(aq) was observed, notably at low pH. The process is reversible, as indicated by formation of Tl(I) when the irradiated systems were kept in the dark. In systems with colloidal silica-stabilised ferrihydrite, UV irradiation also leads to oxidation of Tl(I)(aq), but not quantitatively. It is suggested that adsorption of thallium to the ferrihydrite determines the rate of oxidation. Detectable, but not quantitative, oxidation of Tl(I)(aq) took place when natural water samples with 1 microg l(-1) Tl(I)(aq) were exposed to either sunlight or UV-light. For these samples, the reduction was not quantitative when they were kept in the dark for 24 h. The results suggest that the light dependent iron cycle in fresh water systems strongly influences the redox state of thallium. 相似文献
42.
K. Piikki J. Klingberg G. Pihl Karlsson P.E. Karlsson H. Pleijel 《Environmental pollution (Barking, Essex : 1987)》2009,157(11):3051-3058
Surface ozone concentration and surface air temperature was measured hourly at three coastal sites, four low elevation inland sites and two high elevation inland sites in southwestern Sweden. Diurnal ozone concentration range (DOR) and diurnal temperature range (DTR) were strongly correlated, both spatially and temporally, most likely because both depended on atmospheric stability. Accumulated ozone exposure above a threshold concentration of x nmol mol−1 (AOTx) was estimated from time-integrated ozone concentration (as from diffusive sampling) and measures of ozone concentration variability. Two methods both estimated 24-h AOTx with high accuracy (modelling efficiencies >90% for x ≤ 40 nmol mol−1). Daytime (08:00–20:00) AOTx could not be equally well estimated. Estimates were better for lower AOT thresholds. Diffusive ozone concentration sampling, combined with hourly temperature monitoring, could be a valuable complement to ozone concentration monitoring with continuous instruments. 相似文献
43.
In the 1990s, the obligation to assess transboundary environmental impacts has become part of international law. The UN/ECE Convention on environmental impact assessment (EIA) in a transboundary context, which entered into force in 1997, is one of the key documents. In this study, we show that difficulties with the practical implementation of the Convention arise partly from an incomplete sharing of the concept of EIA, and partly from different material interests on the part of the Parties to the Convention. Attempts to improve the practical implementation should recognize both aspects. Several approaches are thus needed for improving the implementation. Some will help in developing a mutual understanding of impact assessments, whereas others may help in overcoming differences in material interests. 相似文献
44.
Karlsson PE Tang L Sundberg J Chen D Lindskog A Pleijel H 《Environmental pollution (Barking, Essex : 1987)》2007,150(1):96-106
Trends were found for increasing surface ozone concentrations during April-September in northern Sweden over the period 1990-2006 as well as for an earlier onset of vegetation growing season. The highest ozone concentrations in northern Sweden occurred in April and the ozone concentrations in April showed a strong increasing trend. A model simulation of ozone flux for Norway spruce indicated that the provisional ozone flux based critical level for forests in Europe is exceeded in northern Sweden. Future climate change would have counteracting effects on the stomatal conductance and needle ozone uptake, mediated on the one hand by direct effect of increasing air temperatures and on the other through increasing water vapour pressure difference between the needles and air. Thus, there is a substantial and increasing risk for negative impacts of ozone on vegetation in northern Sweden, related mainly to increasing ozone concentrations and an earlier onset of the growing season. 相似文献
45.
The cyanobacterial hepatotoxin nodularin is abundantly produced by the cyanobacterium Nodularia spumigena in the Baltic Sea during July-August. Nodularin is a potent hepatotoxin and a tumour promoter, distributed in various Baltic Sea environmental compartments, especially food webs involving mussels. Flounders receive nodularin through consumption of blue mussels. In this study nodularin concentrations in individual flounders (liver) were examined between July and September 2002 (six sample sets, four to 10 samples/set), providing information about contribution of sampling on estimates of bioaccumulation intensity. Toxin was determined using liquid chromatography/mass spectrometry (LC/MS) and enzyme-linked immunosorbent assay (ELISA). Additionally, liver histopathology was examined. Observed toxin concentrations were ND-390 microg kg(-1) dw (LC/MS) and 20-2230 microg kg(-1) dw (ELISA), with maximum concentrations in September (ELISA). The ELISA protocol generally resulted in higher, up to approximately 10-fold, toxin concentrations than LC/MS, with increasing difference toward September. This difference may have originated from different extraction solvents in LC/MS and ELISA, ion suppression in LC/MS, and temporal increase in nodularin metabolites detectable with ELISA. The differences in toxin concentrations between individual liver samples were considerable with relative standard deviation values of 20-154% (LC/MS) and 28-106% (ELISA). Since the precision of the ELISA method employed was <25% and that of LC/MS <10%, it can be concluded that the largest source of error in bioaccumulation estimates may be an inadequate number of samples. Although there were tissue lesions in several liver samples, occurrence of lesions was not related to toxin concentrations. 相似文献
46.
47.
Coralie Chasset Jerker Jarsjö Mikael Erlström Vladimir Cvetkovic Georgia Destouni 《International Journal of Greenhouse Gas Control》2011,5(5):1303-1318
Deep saline aquifers have large capacity for geological CO2 storage, but are generally not as well characterized as petroleum reservoirs. We here aim at quantifying effects of uncertain hydraulic parameters and uncertain stratigraphy on CO2 injectivity and migration, and provide a first feasibility study of pilot-scale CO2 injection into a multilayered saline aquifer system in southwest Scania, Sweden. Four main scenarios are developed, corresponding to different possible interpretations of available site data. Simulation results show that, on the one hand, stratigraphic uncertainty (presence/absence of a thin mudstone/claystone layer above the target storage formation) leads to large differences in predicted CO2 storage in the target formation at the end of the test (ranging between 11% and 98% of injected CO2 remaining), whereas other parameter uncertainty (in formation and cap rock permeabilities) has small impact. On the other hand, the latter has large impact on predicted injectivity, on which stratigraphic uncertainty has small impact. Salt precipitation at the border of the target storage formation affects CO2 injectivity for all considered scenarios and injection rates. At low injection rates, salt is deposited also within the formation, considerably reducing its availability for CO2 storage. 相似文献
48.
Mikael Drackner 《Waste management & research》2005,23(3):175-181
What is waste? To whom?--An anthropological perspective on garbage explores the fact that what constitutes waste is a highly subjective notion. In Tacna, Peru, the place from where this article draws its empirical material, waste is not only seen as a risk to public health and the environment. Some find it is a mere aesthetic inconvenience, for others it is the only source of income. Yet another way of perceiving waste is as a social contagion, in which the negative qualities of garbage are transmitted to surrounding people in the eyes of others. Such perceptions of waste, it is argued, are important parts of local waste management systems, and the understanding of such perceptions might increase the effectiveness of waste management campaigns. 相似文献
49.
Mikael Hult María Jos Martínez Canet Peter N. Johnston Kazuhisa Komura 《Journal of environmental radioactivity》2002,60(3)
During the JCO-accident in Tokai-mura in 1999, the surrounding village was irradiated by an uncontrolled neutron flux. At some locations in that village, the thermal neutron flux was determined retrospectively by measurement of the very low activity of 51Cr and 60Co in stainless-steel spoons using γ-ray spectrometry in underground laboratories. Activities determined in the HADES underground facility are presented here, together with calibrations performed using a well-defined thermal neutron flux to directly estimate the fluence of thermal neutrons independent of most assumptions. The results show measurable 51Cr in three samples and 60Co in four samples taken from locations at distances of up to 430 m from the accident location despite the elapse of 4 half-lives of 51Cr before measurement. Effects of air transport of the samples were considered and shown to be negligible. 相似文献
50.
Johnston PN Hult M Gasparro J Martínez-Canet MJ Vasselli R McKenzie RJ Solomon SB Lambrichts I 《Journal of environmental radioactivity》2005,80(2):245-257
It is possible to estimate radon exposure to man retrospectively by the in vivo measurement of the decay product (210)Pb, which accumulates in the bones. For in vivo methods, knowledge of the distribution of (210)Pb in the skeleton is needed to determine the optimal site for measurement, the skull or the knee. In this study the activity of (210)Pb in a variety of bone samples from 3 individuals have been measured in vitro using underground gamma-ray spectrometry. The individuals were unlikely to have had elevated intakes of Rn. These measurements give baseline data on the bone massic activity of (210)Pb. They show that the massic activity is similar for each of these people and there are similar massic activities of (210)Pb in the skull and the knee of the 2 individuals for which the skull was measured. Additionally for 2 of the individuals trabecular and cortical bone were separated and massic activities were found to be strongly correlated indicating that the (210)Pb is associated with the hydroxyapatite. 相似文献