Enhancement effect of water associated with natural organic matter (NOM) on organic compound-NOM interactions: a case study with carbamazepine

Natural organic matter (NOM) in soils and sediments is recognized to strongly affect environmental distributions of organic compounds. Water associated with NOM may have a significant impact on NOM-organic compound interactions. The objectives of this research were (1) to determine the effect of hydration of a model NOM sorbent on interactions with a probe organic compound, carbamazepine (CBZ), and (2) based on the comparison with the literature data, to evaluate the effect of organic compound structure on the cooperative participation of water molecules in organic sorbate-NOM interactions. CBZ is one of the most widely reported water pollutants from the pharmaceutical and personal care products family. Therefore, CBZ sorption on Pahokee peat was compared from water and from n-hexadecane, using solubility-normalized solute concentrations. CBZ-NOM interactions were enhanced by one to two orders of magnitudes when NOM became fully hydrated. This enhancement is associated with the distinct ability of CBZ to undergo strong, specific interactions with NOM which was revealed by comparing the transfer of CBZ and another model sorbate, phenanthrene, from solution in n-hexadecane to the hydrated NOM sorbent. The enhancing effect of NOM hydration on CBZ-NOM interactions was also observed when CBZ sorption was examined on partially hydrated NOM. In comparison with a smaller-size organic sorbate such as phenol, CBZ needs more NOM-associated water in order to demonstrate the strengthening of interactions with NOM. Therefore, for penetration of the larger sorbate molecules into the NOM interior, a greater number of water molecules are needed to compensate for the local NOM disintegration thus suggesting the greater extent of the cooperativity in an involvement of water molecules in the CBZ-NOM interactions.     

An indicator for effects of organic toxicants on lotic invertebrate communities: Independence of confounding environmental factors over an extensive river continuum

Distinguishing between effects of natural and anthropogenic environmental factors on ecosystems is a fundamental problem in environmental science. In river systems the longitudinal gradient of environmental factors is one of the most relevant sources of dissimilarity between communities that could be confounded with anthropogenic disturbances. To test the hypothesis that in macroinvertebrate communities the distribution of species' sensitivity to organic toxicants is independent of natural longitudinal factors, but depends on contamination with organic toxicants, we analysed the relationship between community sensitivity SPEAR_organic (average community sensitivity to organic toxicants) and natural and anthropogenic environmental factors in a large-scale river system, from alpine streams to a lowland river. The results show that SPEAR_organic is largely independent of natural longitudinal factors, but strongly dependent on contamination with organic toxicants (petrochemicals and synthetic surfactants). Usage of SPEAR_organic as a stressor-specific longitude-independent measure will facilitate detection of community disturbance by organic toxicants.     

Prevention and suppression of explosions in gas-air and dust-air mixtures using powder aerosol-inhibitor

The prevention and suppression of explosions is a very topical field of research because annually hundreds of coal mine workers became their victims. In this research a very effective powder “powder for suppression of explosions” (“PSE”) for the suppression of explosions has been developed and tested. The experiments on suppression of explosions of a methane–air mixture (MAM) at a laboratory conditions using “PSE”-powder have been carried out. The possibility of lowering the power of coal-dust explosion with the help of a “PSE”-powder has been investigated. The feasibility of almost instantaneous disperse of powders using intentionally created mini-explosions (ammonal) was investigated. The barrel-suppressor of explosion in the experimental adit (tunnel) was studied and the large-scale tests for suppression of MAM-explosions in experimental adit were also subjects of study.     

Retrospective analysis of the age at death in two heavily polluted and two unpolluted Russian towns

Mean age at death during 1981-1999 was recorded in four small industrial towns located in the Kola Peninsula, north-western Russia. Two of these towns (Nikel and Monchegorsk) are heavily contaminated by sulphur dioxide and toxic metals (primarily Ni, Cu, Cd) emitted by large nickel-copper smelters; two other towns (Apatity and Polyarnye Zori) are nearly unpolluted. The results did not support the hypothesis that human life span is significantly shorter in the contaminated communities; moreover, mean age at death was lowest in Polyarnye Zori, the town not polluted by either sulfur dioxide or heavy metals but located close to the nuclear power plant. It seems that the impact of hazards other than pollution (both social and environmental), which are common for the populations of the investigated towns, shorten the life span so much that the contribution of pollutants to the decline in life expectancy cannot be detected. However, the relative importance of the life-shortening diseases associated with pollution may increase with the (expected) improvement of the quality of life.     

The dispersion of 99Tc in the Nordic Seas and the Arctic Ocean: a comparison of model results and observations

The radionuclide (99)Tc had been discharged from the nuclear reprocessing facility in Sellafield (UK) into the Irish Sea in increased amounts in the 1990s. We compare the simulated dispersion of (99)Tc in surface water as calculated by a hydrodynamic model and an assessment box model with field-observations from 1996 to 1999 to study concentrations, pathways and travel times. The model results are consistent with the observations and show the typical pathway of dissolved radionuclides from the Irish Sea via the North Sea along the Norwegian Coast. Subsequently the contaminated water separates into three branches of which the two Arctic branches bear the potential for future monitoring of the signal in the next decades. The results of the hydrodynamic model indicate a large variability of surface concentrations in the West Spitsbergen Current which has implications for future monitoring strategies. According to the observed and simulated distributions we suggest an improved box model structure to better capture the pattern for concentrations at the surface.     

A capabilities approach to the prioritization of critical infrastructure

As a consequence of the U.S. effort to increase infrastructure security and resilience, the Department of Homeland Security (DHS) and other U.S. federal agencies have identified 16 critical infrastructure sectors that are considered vital to the nation’s well-being in terms of economic security, public health, and safety. However, there remains no articulated set of values that justify this particular list of infrastructure systems or how decision-makers might prioritize investments towards one critical sector over another during a crisis. To offer a more integrated and holistic approach to critical infrastructure resilience, this research employs the capabilities approach to human development, which offers an alternative view of critical infrastructure that focuses on the services that infrastructure provides rather than its physical condition or vulnerability to threats. This service-based perspective of infrastructure emphasizes the role of infrastructure in enabling and supporting central human capabilities that build adaptive capacity and improve human well-being. We argue that the most critical infrastructure systems are those that are essential for providing and/or supporting central human capabilities. This paper examines the DHS designation of criticality from a capabilities perspective and argues for a capabilities basis for making distinctions between those systems that should be considered most critical and those that might be temporarily sacrificed. A key implication of this work is that an across sector approach is required to reorganize existing critical infrastructure efforts around the most valuable infrastructure end-services.     

A roadmap for the conservation of freshwater mussels in Europe

Europe has a long history of human pressure on freshwater ecosystems. As pressure continues to grow and new threats emerge, there is an urgent need for conservation of freshwater biodiversity and its ecosystem services. However, whilst some taxonomic groups, mainly vertebrates, have received a disproportionate amount of attention and funds, other groups remain largely off the public and scientific radar. Freshwater mussels (Bivalvia, Unionida) are an alarming example of this conservation bias and here we point out six conceptual areas that need immediate and long-term attention: knowledge, threats, socioeconomics, conservation, governance and education. The proposed roadmap aims to advance research, policy and education by identifying the most pressing priorities for the short- and long-term conservation of freshwater mussels across Europe.     

Differential sex- and age-related migration of Bluethroats Luscinia svecica at Eilat, Israel

This paper examines the phenology and biometrics of Bluethroats staging in the Eilat region. This is of special interest because of the extreme conditions with which this temperate zone breeding species has to contend because Eilat is a desert habitat and is the last green area before the crossing of the deserts in autumn or after it in spring. Data were collected during 20 spring and 18 autumn migration seasons in the years 1984–2003, and a total of 7,464 Bluethroat were recorded. The number of trapped birds was much higher in autumn than in spring. The majority of Bluethroats caught in both the autumn and spring migrations were juveniles. We found differences in sex ratio in the individual age classes only in the autumn wherein among both adults and juveniles, males were in greater numbers. We also found significant differences in the dates of ringed birds from different sex–age classes in the spring and in autumn migrations. In spring, males from both age classes were caught earlier than females. In autumn, adult birds arrived earlier than juveniles. We think that it is important to identify and conserve the high quality stopover habitats such as Eilat wherein not only Bluethroats have been shown to stopover but also several hundred other species.     

Pollution resistance of mountain birch, Betula pubescens subsp. czerepanovii, near the copper-nickel smelter: natural selection or phenotypic acclimation?

Mountain birch, Betula pubescens subsp. czerepanovii (Orlova) Hamet-Ahti, is one of the very few woody plants surviving in the heavily polluted industrial barrens of the Kola Peninsula, north-western Russia. The present study was designed to find out whether long-lasting pollution impact caused selection of resistant birch genotypes, and to investigate possible trade-offs between pollution resistance and performance by exploring growth of birch seedlings in the different environments. In the reciprocal planting experiments, progenies of birches from polluted sites performed slightly better in the polluted environment (in terms of survival, leaf number, and leaf size) than progenies of birches from clean sites; and vice versa, in the clean environment progenies of birches from polluted sites performed slightly worse than progenies of birches from clean sites. However, this pattern was detected only in some of statistical tests, while the majority of comparisons showed no genotype or genotype by environment effects. Although some of the results indicate that long-lasting pollution impact may have increased pollution resistance of the affected populations by elimination of sensitive genotypes (survival selection), this conclusion should be considered tentative. The resistance did not reach the level sufficient to assure re-colonisation of polluted habitats: progenies of all trees completely died on the contaminated soils by the end of the first growth season. Therefore persistence of mountain birch populations near the strong polluters may be transient, being explained not only by higher resistance of the survivors, but also by phenotypic acclimatisation of mature trees to gradual increase in pollution.