Studded and unstudded winter tires in fatal road accidents in Finland

Objective: The aim of the study was to compare the safety effects of studded and unstudded winter tires based on fatal road accidents.

Methods: The data included 958 road accidents involving a passenger car or van that occurred in Finland from November to March between 1997 and 2012.

Results: Comparing the proportions of winter tire type in accidents and in general traffic showed that the overall effect of tire type on the number of accidents was not significant, although studded tires reduced fatal accidents by 10–15%. Compared to unstudded tires, studded tires reduced accidents significantly only on bald ice in 2005–2012. Drivers using unstudded tires were more experienced and their profession was more frequently related to driving. In addition, the vehicle age was lower for vehicles with unstudded tires. On the other hand, the state of repair was less pertinent for unstudded than for studded tires. These confounding factors offset their effects to some degree.

Conclusions: The risk of fatal road accidents in winter between studded and unstudded tires does not differ significantly. However, the accident risk has recently been substantially higher on bald ice for unstudded than for studded tires. The magnitude of this risk difference is difficult to determine without specific information on exposure by road surface.     

Effect of combustion condition on cytotoxic and inflammatory activity of residential wood combustion particles

Residential heating is an important local source of fine particles and may cause significant exposure and health effects in populations. We investigated the cytotoxic and inflammatory activity of particulate emissions from normal (NC) and smouldering (SC) combustion in one masonry heater. The PM_1–0.2 and PM_0.2 samples were collected from the dilution tunnel with a high-volume cascade impactor (HVCI). Mouse RAW 264.7 macrophages were exposed to the PM-samples for 24 h. Inflammatory mediators, (IL-6, TNFα and MIP-2), and cytotoxicity (MTT-test), were measured. Furthermore, apoptosis and cell cycle of macrophages were analyzed. The HVCI particulate samples were characterized for ions, elements and PAH compounds. Assays of elemental and organic carbon were conducted from parallel low volume samples. All the samples displayed mostly dose-dependent inflammatory and cytotoxic activity. SC samples were more potent than NC samples at inducing cytotoxicity and MIP-2 production, while the order of potency was reversed in TNFα production. SC-PM_1–0.2 sample was a significantly more potent inducer of apoptosis than the respective NC sample. After adjustment for the relative toxicity with emission factor (mg MJ^?1), the SC-PM emissions had clearly higher inflammatory and cytotoxic potential than the NC-PM emissions. Thus, operational practice in batch burning of wood and the resultant combustion condition clearly affect the toxic potential of particulate emissions.     

CO2 capture from coal-fired power plants based on sodium carbonate slurry; a systems feasibility and sensitivity study

In this work the feasibility of a CO₂ capture system based on sodium carbonate–bicarbonate slurry and its integration with a power plant is studied. The results are compared to monoethanolamine (MEA)-based capture systems. Condensing power plant and combined heat and power plant with CO₂ capture is modelled to study the feasibility of combined heat and power plant for CO₂ capture.Environmental friendly sodium carbonate would be an interesting chemical for CO₂ capture. Sodium carbonate absorbs CO₂ forming sodium bicarbonate. The low solubility of sodium bicarbonate is a weak point for the sodium carbonate based liquid systems since it limits the total concentration of carbonate. In this study the formation of solid bicarbonate is allowed, thus forming slurry, which can increase the capacity of the solvent. With this the energy requirement of stripping of the solvent could potentially be around 3.22 MJ/kg of captured CO₂ which is significantly lower than with MEA based systems which typically have energy consumption around 3.8 MJ/kg of captured CO₂.Combined heat and power plants seem to be attractive for CO₂ capture because of the high total energy efficiency of the plants. In a condensing power plant the CO₂ capture decreases directly the electricity production whereas in a combined heat and power plant the loss can be divided between district heat and electricity according to demand.     

A tool for estimating the contribution of water-soluble organic compounds to the particle mass and condensational growth in the atmosphere

In this theoretical investigation, we elucidated several factors governing the ability of organic, water-soluble vapours to participate into either the secondary organic aerosol formation or particle condensational growth in the atmosphere. The corresponding requirements for physico-chemical properties of the vapour were estimated. These estimates were also compared with the properties of several difunctional carboxylic acids identified in the atmosphere. Our analysis indicates that while many of the considered compounds are expected to contribute to the total particle mass in the atmosphere, their role in particle condensational growth process remains uncertain. This uncertainty emerges from the fact that the saturation ratio of an organic vapour does not alone determine its ability to act as a “nonvolatile” compound. Instead, the hygroscopic and chemical properties of the vapour, as well as the particle pH and size, have also to be taken into account.     

Degradation of 1,2-dichloroethane from wash water of ion-exchange resin using Fenton’s oxidation

Background, aim, and scope  

Chlorinated volatile organic compounds (CVOCs), widely used in industry as solvents and chemical intermediates in the production of synthetic resins, plastics, and pharmaceuticals, are highly toxic to the environment and public health. Various studies reported that Fenton’s oxidation could degrade a variety of chlorinated VOCs in aqueous solutions. In acidic conditions, ferrous ion catalyzes the decomposition of H₂O₂ to form a powerful ^•OH radical. In this study, wastewater from wash of ion-exchange resin containing typical CVOC, 1,2-dichloroethane, was treated using Fenton’s oxidation. To reduce environmental load and processing costs of wastewater, Fenton process as a simple and efficient treatment method was applied to degrade 1,2-dichloroethane of wash water.     

Human dietary intake of organochlorines from Baltic herring: implications of individual fish variability and fisheries management

This study examines the extent to which Finnish human dietary intake of organochlorines (PCDD/Fs and PCBs) originating from Northern Baltic herring can be influenced by fisheries management. This was investigated by estimation of human intake using versatile modeling tools (e.g., a herring population model and a bioenergetics model). We used a probabilistic approach to account for the variation in human intake of organochlorines originating from the variation among herring individuals. Our estimates were compared with present precautionary limits and recommendation for use. The results show that present consumption levels and frequencies of herring give a high probability of exceeding recommended intake limits of PCDD/Fs and PCBs. Furthermore, our results clearly demonstrate that in the risk management of dioxinlike organochlorines, regulating fishing (in this case increasing fishing pressure) is a far less effective way to decrease the risk than regulating the consumption of herring. Increased fishing would only slightly decrease organochlorine concentrations of herring in the Finnish fish market.     

Nitrogen Oxide Emissions of Boilers in Finland

This article discusses nitrogen oxide emissions from various types of boilers in Finland. The boilers have been classified into 61 classes according to their size, combustion technique, and main fuel. A specific emission coefficient (ng NO₂/J = mg NO₂/MJ) for each class has been determined, based on literature surveys and actual measurements. The total NO_X emission has been calculated for each class, using the emission coefficient and energy statistics. The effect of various techniques for emission reduction has also been investigated. The development of NO_X emissions has been estimated for both the case where no preventing actions have been taken and for four defined cases where alternative reduction measures are assumed

The total NO_X emission from energy production in Finland was 107,000 tons NO₂ in 1987. Seventy-five percent of this amount originated in boilers larger than 1 MWfuel effect (input effect), and the rest in smaller boilers and industrial processes. The most important boiler classes from the NO_X emission’s point of view were coal-fired boilers, with an emission of approximately 38,000 tons NO₂, peat-fired boilers and boilers fired with a mixture of fuels, emitting approximately 12,000 tons NO₂ each.

By 2005, the total NO_X emission from energy production would increase 50 percent to approximately 160,000 tons if left uncontrolled. The emission level would be 140,000 tons if primary reduction techniques are applied, and 110,000 tons NO₂, if catalytic NO_X reduction devices are installed in boilers larger than 300 MW.     

Winter food utilisation by sympatric mysids in the Baltic Sea,studied by combined gut content and stable isotope analyses

We studied the winter dietary characteristics of two sympatric mysid species, Mysis mixta and M. relicta, which exploit both benthic and pelagic habitats during diel vertical migrations. Samples collected before and after the ice-covered period in the northern Baltic Sea were investigated using both stomach content analyses and stable isotope analyses of carbon and nitrogen. Both of the mysid species were omnivorous during winter and utilised both benthic and pelagic food sources. The main food source before the ice period was calanoid copepods (40 and 36% for M. mixta and M. relicta, respectively), and after ice-out calanoid copepods (23%) and zooplankton resting eggs (23%) for M. mixta and diatoms (44%) and calanoids (25%) for M. relicta. Their patterns of food utilisation broadly followed seasonal fluctuations in the abundance of the main prey groups. Although pelagic food availability is low in winter both mysid species utilised pelagic prey widely. We also show that when combining these different diet analysis methods it is important to take into account the time lag in isotopic signatures, otherwise the obtained results do not correspond but instead show the feeding history at different times.