Tree leaf biomarkers for atmospheric nitrogen deposition

The aim of this paper was to investigate the effects of nitrogen (N) deposition on tree N cycling and identify potential biomarkers for N deposition. Between April and October 2002 extensive fieldwork was undertaken at Mardley Heath in Hertfordshire. This woodland, located adjacent to the A1(M) motorway, is exposed to high levels of atmospheric nitrogen oxides from the traffic. Measurements of δ¹⁵N, in vivo nitrate reductase (NR) activity, tissue, xylem and surface nitrate concentrations as well as N concentration and growth were made along a 700-m transect at 90° to the motorway. The δ¹⁵N data show that oxidised N from the road traffic is taken up by nearby trees and is incorporated into plant tissues. Our measurements of NR activities suggest elevated rates close to the motorway. However, xylem sap, leaf tissue and leaf surface nitrate concentrations showed no differences between the roadside location and the most distant sampling point from the motorway. Taken together the δ¹⁵N and nitrate reductase data suggest uptake and assimilation of N through the foliage. We conclude that for this lowland deciduous woodland, tissue, xylem and surface measurements of nitrate are unreliable biomarkers for N deposition whereas δ¹⁵N, growth measurements and integrated seasonal NR might be useful. The results also point to the benefit of roadside tree planting to screen pollution from motor vehicles.     

Corn residue level and manure application timing effects on phosphorus losses in runoff

Growing interest in corn (Zea mays L.) silage utilization on Wisconsin dairy farms may have implications for nutrient losses from agricultural lands. Increasing the silage cutting height will increase residue cover and could reduce off-site migration of sediments and associated constituents compared with conventional silage harvesting. We examined the effects of residue level and manure application timing on phosphorus (P) losses in runoff from no-till corn. Treatments included conventional corn grain (G) and silage (SL; 10- to 15-cm cutting height) and nonconventional, high-cut (60-65 cm) silage (SH) subjected to different manure application regimes: no manure (N) or surface application in fall (F) or spring (S). Simulated rainfall (76 mm h(-1); 1 h) was applied in spring and fall for two years (2002-2003), runoff from 2.0- x 1.5-m plots was collected, and subsamples were analyzed for dissolved reactive phosphorus (DRP), total phosphorus (TP), and P mass distribution in four particle size classes. Total P and DRP loads were inversely related to percent residue cover, but both TP and DRP concentrations were unaffected by residue level. Manure application increased DRP concentrations in spring runoff by two to five times but did not significantly affect DRP loads, since higher concentrations were offset by lower runoff volumes. Spring manure application reduced TP loads in spring runoff by 77 to 90% compared with plots receiving no manure, with the extent of reductions being greatest at the lower residue levels (<24%). The TP concentration in sediments increased as particle size decreased. Manure application increased the TP concentration of the 0- to 2-microm fraction by 79 to 125%, but elevated the 2- to 10- and 10- to 50-microm fractions to a lesser extent. Recent manure additions were most influential in enriching transported sediments with P. By itself, higher residue cover achieved by high-cutting silage was often insufficient to lower P losses; however, the combination of manure application and higher residue levels significantly reduced P losses from corn fields harvested for silage.     

THE LODGING VELOCITY FOR EMERGENT AQUATIC PLANTS IN OPEN CHANNELS1

ABSTRACT: The growth of aquatic plants in open‐channels has many adverse environmental effects including, but not limited to, impeding the transport of water, hindering navigation, increasing flood elevations, increasing sediment deposition, and degrading water quality. Existing control strategies include physical removal and chemical treatment. Physical removal is only a temporary solution and chemical treatment is unacceptable if the water will be consumed by humans. The hydrodynamic method can wash out the encroached aquatic plants by keeping flow velocity higher than the critical velocity required to bend and rupture (lodge) their stems. This approach is a promising, physically‐based, efficient, economic, and permanent solution for this problem. However, the success of this approach requires the accurate prediction of the critical lodging velocity. This paper presents an analytic study of the lodging velocity for the submerged portion of aquatic plants of narrow leaved emergent stems that are wider at bottom than the top. Based on the principles of engineering materials and the theory of turbulent flow, a semi‐empirical formula is derived for the prediction of the critical lodging velocity. It indicates that the lodging of aquatic plants is controlled not only by flow conditions but also the geometric and mechanical characteristics of the plants. These analytic results provide a satisfactory explanation of the lodging phenomena observed in the field and are verified by the available experimental data.     

INTEGRATING LANDSCAPE ASSESSMENT AND HYDROLOGIC MODELING FOR LAND COVER CHANGE ANALYSIS1

ABSTRACT: Significant land cover changes have occurred in the watersheds that contribute runoff to the upper San Pedro River in Sonora, Mexico, and southeast Arizona. These changes, observed using a series of remotely sensed images taken in the 1970s, 1980s, and 1990s, have been implicated in the alteration of the basin hydrologic response. The Cannonsville subwatershed, located in the Catskill/Delaware watershed complex that delivers water to New York City, provides a contrast in land cover change. In this region, the Cannonsville watershed condition has improved over a comparable time period. A landscape assessment tool using a geographic information system (GIS) has been developed that automates the parameterization of the Soil and Water Assessment Tool (SWAT) and KINEmatic Runoff and EROSion (KINEROS) hydrologic models. The Automated Geospatial Watershed Assessment (AGWA) tool was used to prepare parameter input files for the Upper San Pedro Basin, a subwatershed within the San Pedro undergoing significant changes, and the Cannonsville watershed using historical land cover data. Runoff and sediment yield were simulated using these models. In the Cannonsville watershed, land cover change had a beneficial impact on modeled watershed response due to the transition from agriculture to forest land cover. Simulation results for the San Pedro indicate that increasing urban and agricultural areas and the simultaneous invasion of woody plants and decline of grasslands resulted in increased annual and event runoff volumes, flashier flood response, and decreased water quality due to sediment loading. These results demonstrate the usefulness of integrating remote sensing and distributed hydrologic models through the use of GIS for assessing watershed condition and the relative impacts of land cover transitions on hydrologic response.     

Computational modeling and analysis of thoracolumbar spine fractures in frontal crash reconstruction

Abstract

Objective: This study aimed to reconstruct 11 motor vehicle crashes (6 with thoracolumbar fractures and 5 without thoracolumbar fractures) and analyze the fracture mechanism, fracture predictors, and associated parameters affecting thoracolumbar spine response.

Methods: Eleven frontal crashes were reconstructed with a finite element simplified vehicle model (SVM). The SVM was tuned to each case vehicle and the Total HUman Model for Safety (THUMS) Ver. 4.01 was scaled and positioned in a baseline configuration to mimic the documented precrash driver posture. The event data recorder crash pulse was applied as a boundary condition. For the 6 thoracolumbar fracture cases, 120 simulations to quantify uncertainty and response variation were performed using a Latin hypercube design of experiments (DOE) to vary seat track position, seatback angle, steering column angle, steering column position, and D-ring height. Vertebral loads and bending moments were analyzed, and lumbar spine indices (unadjusted and age-adjusted) were developed to quantify the combined loading effect. Maximum principal strain and stress data were collected in the vertebral cortical and trabecular bone. DOE data were fit to regression models to examine occupant positioning and thoracolumbar response correlations.

Results: Of the 11 cases, both the vertebral compression force and bending moment progressively increased from superior to inferior vertebrae. Two thoracic spine fracture cases had higher average compression force and bending moment across all thoracic vertebral levels, compared to 9 cases without thoracic spine fractures (force: 1,200.6 vs. 640.8 N; moment: 13.7 vs. 9.2?Nm). Though there was no apparent difference in bending moment at the L1–L2 vertebrae, lumbar fracture cases exhibited higher vertebral bending moments in L3–L4 (fracture/nonfracture: 45.7 vs. 33.8?Nm). The unadjusted lumbar spine index correctly predicted thoracolumbar fracture occurrence for 9 of the 11 cases (sensitivity?=?1.0; specificity?=?0.6). The age-adjusted lumbar spine index correctly predicted thoracolumbar fracture occurrence for 10 of the 11 cases (sensitivity?=?1.0; specificity?=?0.8). The age-adjusted principal stress in the trabecular bone was an excellent indicator of fracture occurrence (sensitivity?=?1.0; specificity?=?1.0). A rearward seat track position and reclined seatback increased the thoracic spine bending moment by 111–329%. A more reclined seatback increased the lumbar force and bending moment by 16–165% and 67–172%, respectively.

Conclusions: This study provided a computational framework for assessing thoracolumbar fractures and also quantified the effect of precrash driver posture on thoracolumbar response. Results aid in the evaluation of motor vehicle crash–induced vertebral fractures and the understanding of factors contributing to fracture risk.     

Contribution of In‐Channel Processes to Sediment Yield of an Urbanizing Watershed1

Abstract: A study was conducted between September 2003 and September 2006 to obtain baseline sediment inventories and monitor sediment transport and storage along a 3.7 km length of the channel of Valley Creek within Valley Forge National Historical Park, Pennsylvania. Valley Creek is a tributary of the Schuylkill River and drains an urbanizing 60.6 km² watershed that currently has 18% impervious land cover. Numerous field methods were employed to measure the suspended sediment yield, longitudinal profile, cross‐sections, banklines, and particle size distribution of the streambed. Suspended sediment yield for the watershed was measured at a USGS gage located just upstream of the park boundary between July 2004 and July 2005, the period corresponding to field surveys of bank erosion and channel change. The estimated suspended sediment yield of 95.7 t/km²/year is representative of a year with unusually high discharge, including a storm event that produced a peak of 78 m³/s, the second highest discharge on record for the USGS gage. Based on the median annual streamflow for the 24 years of record at the USGS gage from 1983 to 2006, the median annual sediment yield is estimated to be closer to 34 t/km²/year, considerably lower than median and mean values for other sites within the region. The mass of silt, clay, and fine sand derived from bank erosion along the 3.7 km study reach during the field survey period accounts for an estimated 2,340 t, equivalent to about 43% of the suspended sediment load. The mass of fine sediment stored in the bed along the study reach was estimated at 1,500 t, with about 330 t of net erosion during the study period. Although bank erosion appears to be a potentially dominant source of sediment by comparison with annual suspended sediment load, bed sediment storage and potential for remobilization is of the same order of magnitude as the mass of sediment derived from bank erosion.     

Growing season total gaseous mercury (TGM) flux measurements over an Acer rubrum L. stand

Relaxed eddy accumulation (REA) measurements of the total gaseous mercury (TGM) flux measurements were taken over a deciduous forest predominantly composed of Red Maple (Acer rubrum L.) during the growing season of 2004 and the second half of the growing season of 2005. The magnitudes of the flux estimates were in the range of published results from other micrometeorological mercury fluxes taken above a tall canopy and larger than estimates from flux chambers. The magnitude and direction of the flux were not static during the growing season. There was a significant trend (p < 0.001), from net deposition of TGM in early summer to net evasion in the late summer and early fall before complete senescence. A growing season atmosphere-canopy total mercury (TGM) compensation point during unstable daytime conditions was estimated at background ambient concentrations (1.41 ng m^?3). The trend in the seasonal net TGM flux indicates that long term dry deposition monitoring is needed to accurately estimate mercury loading over a forest ecosystem.     

The Denver Aerosol Sources and Health (DASH) Study: Overview and Early Findings

Improved understanding of the sources of air pollution that are most harmful could aid in developing more effective measures for protecting human health. The Denver Aerosol Sources and Health (DASH) study was designed to identify the sources of ambient fine particulate matter (PM(2.5)) that are most responsible for the adverse health effects of short-term exposure to PM (2.5). Daily 24-hour PM(2.5) sampling began in July 2002 at a residential monitoring site in Denver, Colorado, using both Teflon and quartz filter samplers. Sampling is planned to continue through 2008. Chemical speciation is being carried out for mass, inorganic ionic compounds (sulfate, nitrate and ammonium), and carbonaceous components, including elemental carbon, organic carbon, temperature-resolved organic carbon fractions and a large array of organic compounds. In addition, water soluble metals were measured daily for 12 months in 2003. A receptor-based source apportionment approach utilizing positive matrix factorization (PMF) will be used to identify PM (2.5) source contributions for each 24-hour period. Based on a preliminary assessment using synthetic data, the proposed source apportionment should be able to identify many important sources on a daily basis, including secondary ammonium nitrate and ammonium sulfate, diesel vehicle exhaust, road dust, wood combustion and vegetative debris. Meat cooking, gasoline vehicle exhaust and natural gas combustion were more challenging for PMF to accurately identify due to high detection limits for certain organic molecular marker compounds. Measurements of these compounds are being improved and supplemented with additional organic molecular marker compounds. The health study will investigate associations between daily source contributions and an array of health endpoints, including daily mortality and hospitalizations and measures of asthma control in asthmatic children. Findings from the DASH study, in addition to being of interest to policymakers, by identifying harmful PM(2.5) sources may provide insights into mechanisms of PM effect.