全文获取类型
收费全文 | 709篇 |
免费 | 50篇 |
国内免费 | 176篇 |
专业分类
安全科学 | 76篇 |
废物处理 | 45篇 |
环保管理 | 55篇 |
综合类 | 349篇 |
基础理论 | 98篇 |
污染及防治 | 222篇 |
评价与监测 | 34篇 |
社会与环境 | 36篇 |
灾害及防治 | 20篇 |
出版年
2023年 | 16篇 |
2022年 | 49篇 |
2021年 | 37篇 |
2020年 | 34篇 |
2019年 | 25篇 |
2018年 | 31篇 |
2017年 | 36篇 |
2016年 | 40篇 |
2015年 | 47篇 |
2014年 | 41篇 |
2013年 | 61篇 |
2012年 | 68篇 |
2011年 | 64篇 |
2010年 | 45篇 |
2009年 | 46篇 |
2008年 | 44篇 |
2007年 | 46篇 |
2006年 | 27篇 |
2005年 | 19篇 |
2004年 | 21篇 |
2003年 | 16篇 |
2002年 | 25篇 |
2001年 | 21篇 |
2000年 | 5篇 |
1999年 | 9篇 |
1998年 | 12篇 |
1997年 | 10篇 |
1996年 | 8篇 |
1995年 | 6篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1991年 | 5篇 |
1989年 | 2篇 |
1988年 | 5篇 |
1987年 | 2篇 |
1984年 | 1篇 |
1982年 | 2篇 |
1973年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有935条查询结果,搜索用时 859 毫秒
511.
Distribution of perfluorochemicals between sera and milk from the same mothers and implications for prenatal and postnatal exposures 总被引:1,自引:0,他引:1
Kim SK Lee KT Kang CS Tao L Kannan K Kim KR Kim CK Lee JS Park PS Yoo YW Ha JY Shin YS Lee JH 《Environmental pollution (Barking, Essex : 1987)》2011,159(1):169-174
The levels of six perfluorocarboxylates (PFCAs), four perfloroalkylsulfonates (PFASs), and one sulfonamide were measured in paired samples of maternal serum, umbilical cord serum, and breast milk. The maternal and cord sera were strongly correlated with each other for all measured compounds (r > 0.5 and p < 0.01). Nevertheless, there was a significant difference in compound composition profile between the two sera matrices, with a more depletion of the longer chain compounds in cord serum. The transfer efficiency values from maternal to cord serum (TFCS/MS) decreased by 70% with each increasing unit of -CF2 chain within a PFCA group, and for perfluorooctanesulfonate (PFOS), by a half compared to perfluorooctanoate (PFOA). In contrast to the strong correlation in concentrations between the two sera matrices, the pattern of compounds in breast milk differed considerably with those in sera. Accordingly, compound- and matrix-specific transfer must be considered when assessing prenatal and postnatal exposure. 相似文献
512.
为了控制污水脱氮中N2O排放,在不同曝气强度下研究了好氧硝化段同时硝化反硝化(SND)系统的N2O排放特性,并采用PCR—DGGE技术分析微生物群落特征。结果发现,随着曝气强度的增强,系统总氮去除率下降,但脱氮中N2O—N所占比例则上升,实验中从低到高3个曝气强度下,总氮去除率分别为80.01%、65.28%和58.62%,脱氮中N2O—N所占的比例为1.89%、7.84%和9.20%。PCR—DGGE分析显示,和低曝气强度下相比中、高曝气强度下系统微生物群落发生明显变化,但中曝气强度和高曝气强度下系统微生物群落表现出较高相似性。这表明,不同曝气强度下系统N2O排放受到氮素转化和微生物群落变化的影响。适宜曝气强度不仅提高总氮去除率,还可有效控制N2O排放。 相似文献
513.
514.
515.
钛基氧化物涂层电极在污水处理方面的实验研究 总被引:1,自引:0,他引:1
用涂刷热分解氧化法研究制作了3种钛基金属氧化物涂层电极:SnO2-Sb2O3-CeO2/SnO2-Sb2O3/Ti、SnO2-Sb2O3-CoO2/SnO2-Sb2O3/Ti和SnO2-Sb2O3-CoO2/IrO2/Ti,用于处理生活污水,筛选出了处理效果最好的电极:SnO2-Sb2O3-CeO2/SnO2-Sb2O3/Ti电极。通过SnO2-Sb2O3-CeO2/SnO2-Sb2O3/Ti电极处理生活污水的静态实验,研究了电解时间、电流密度等因素对电解效果的影响,得出该电极较佳的运行参数是:极板间距1 cm、电流密度10 mA/cm2、电解时间2 h,此时,COD、NH3-N、总磷、总氮、SS和大肠菌群的去除率分别为94.0%、99.8%、51.8%、70.8%、100%和100%;并用该参数进行了动态实验,连续运行60 d,得到了稳定的出水水质数据。 相似文献
516.
Yoo Jung Kim Jung-Hun Woo Young-Il Ma Suhyang Kim Jung Sik Nam Hakyoung Sung Ki-Chul Choi Jihyun Seo Jeong Su Kim Chang-Hee Kang Gangwoong Lee Chul-Un Ro Duk Chang Young Sunwoo 《Atmospheric environment (Oxford, England : 1994)》2009,43(34):5556-5566
In this study, background concentration sites of Deokjeok and Gosan, which were deemed suitable for monitoring the impact of long-range transported air pollutants, were selected. An investigation of the source types of pollutants, their locations, and relative quantitative contributions to the particulate concentrations at both sites using appropriate methodologies to make initial estimations was conducted. Episodic measurements of PM2.5, PM10, and size distribution, along with its ion and carbon components were performed from 2005 to 2007, and a comprehensive analysis of the results was conducted utilizing back trajectory analysis. As for frequency of wind direction, it was quite apparent that the two sites are heavily influenced by air masses originating from the eastern and northern regions of China. For PM2.5 and PM10, the mass concentrations from north and east China were higher than other cases, originating from the ocean. In the northerly-wind case, meteorological properties for Deokjeok and Gosan and the influence of carbon emissions from northwest Korea resulted in a changing of air mass properties during transport. As was the case with mass concentration, the highest contribution for ionic and carbon components of PM2.5 and PM10 for both sites appeared for the westerly wind case. A specially high relative contribution, greater than 1.4 times, was apparent in the secondary aerosol case because of a large influence of long-range transported pollutants from east China. Carbon components exhibited different behaviors for the northerly and westerly wind cases compared with secondary aerosol. The major reason for this discrepancy appears to be the carbon emissions from northwest Korea. 相似文献
517.
Daniel Q. Tong Rohit Mathur Daiwen Kang Shaocai Yu Kenneth L. Schere George Pouliot 《Atmospheric environment (Oxford, England : 1994)》2009,43(3):724-733
The main use of air quality forecast (AQF) models is to predict ozone (O3) exceedances of the primary O3 standard for informing the public of potential health concerns. This study presents the first evaluation of the performance of the Eta-CMAQ air quality forecast model to predict a variety of widely used seasonal mean and cumulative O3 exposure indices associated with vegetation using the U.S. AIRNow O3 observations. These exposure indices include two concentration-based O3 indices, M7 and M12 (the seasonal means of daytime 7-h and 12-h O3 concentrations, respectively), and three cumulative exposure-based indices, SUM06 (the sum of all hourly O3 concentrations ≥ 0.06 ppm), W126 (hourly concentrations weighed by a sigmoidal weighting function), and AOT40 (O3 concentrations accumulated over a threshold of 40 ppb during daylight hours). During a three-month simulation (July–September 2005), the model over predicted the M7 and M12 values by 8–9 ppb, or a NMB value of 19% and a NME value of 21%. The model predicts a central belt of high O3 extending from Southern California to Middle Atlantic where the seasonal means, M7 and M12 (the seasonal means of daytime 7-h and 12-h O3 concentrations), are higher than 50 ppbv. In contrast, the model is less capable of reproducing the observed cumulative indices. For AOT40, SUM06 and W126, the NMB and NME values are two- to three-fold of that for M7, M12 or peak 8-h O3 concentrations. The AOT40 values range from 2 to 33 ppm h by the model and from 1 to 40 ppm h by the monitors. There is a significantly higher AOT40 value experienced in the United States in comparison to Europe. The domain-wide mean SUM06 value is 14.4 ppm h, which is about 30% higher than W126, and 40% higher than AOT40 calculated from the same 3-month hourly O3 data. This suggests that SUM06 and W126 represent a more stringent standard than AOT40 if either the SUM06 or the W126 was used as a secondary O3 standard. Although CMAQ considerably over predicts SUM06 and W126 values at the low end, the model under predicts the extreme high exposure values (>50 ppm h). Most of these extreme high values are found at inland California sites. Based on our analysis, further improvement of the model is needed to better capture cumulative exposure indices. 相似文献
518.
三级人工快渗系统脱氮效果及菌种分布分析 总被引:1,自引:1,他引:0
为了更有效地去除污水中的氮类污染物,采用三级串联人工快渗系统对高氨氮生活污水进行脱氮性研究,同时进行系统内菌种分布的特征分析,从微观角度对比传统人工快渗和新式三级串联人工快渗系统中微生物分布的区别。结果表明三级串联人工快渗系统对氨氮和总氮(TN)的去除率较常规人工快渗系统分别提高5%和21%。三级串联人工快渗系统内硝化细菌和反硝化细菌总数均大于传统人工快渗系统。反硝化细菌数量的显著提高是总氮(TN)去除提高的主要原因。同时发现三级串联人工快渗系统可以有效地缓解堵塞现象的发生。 相似文献
519.
520.