Volatile organic compounds (VOCs) have been determined to be human risk factors in urban environments, as well as primary contributors to the formation of photochemical oxidants. Ambient air quality measurements of 54 VOCs including hydrocarbons, halogenated hydrocarbons and carbonyls were conducted in or near 13 urban locations in the United States during September 1996 to August 1997. Air samples were collected and analyzed in accordance with US Environmental Protection Agency-approved methods. The target compounds most commonly found were benzene, toluene, xylene and ethylbenzene. These aromatic compounds were highly correlated and proportionally related in a manner suggesting that the primary contributors were mobile sources in all the urban locations studied. Concentrations of total hydrocarbons ranged between 1.39 and 11.93 parts per billion, by volume (ppbv). Ambient air levels of halogenated hydrocarbons appeared to exhibit unique spatial variations, and no single factor seemed to explain trends for this group of compounds. The highest halogenated hydrocarbon concentrations ranged from 0.24 ppbv for methylene chloride to 1.22 ppbv for chloromethane. At participating urban locations for the year of data considered, levels of carbonyls were higher than the level of the other organic compound groups, suggesting that emissions from motor vehicles and photochemical reactions strongly influence ambient air concentrations of carbonyls. Of the most prevalent carbonyls, formaldehyde and acetaldehyde were the dominant compounds, ranging from 1.5-7.4 ppbv for formaldehyde, to 0.8-2.7 ppbv for acetaldehyde. 相似文献
Objective: We conducted a cohort study of recent wartime veterans to determine the postservice mortality risk due to motor vehicle accidents (MVAs).
Methods: Veterans were identified from the Defense Manpower Data Center records. Deployment to te Iraq or Afghanistan war zone was determined from the Contingency Tracking System. Vital status of 317,581 deployed and 964,493 nondeployed veterans was followed from their discharge dates between 2001 to 2007 until earlier of date of death or December 31, 2009. Underlying causes of death were obtained from the National Death Index Plus.
Results: Based on 9,353 deaths (deployed, 1,650; nondeployed, 7,703), of which 779 were MVA deaths as drivers (166; 613), both cohorts had 25 to 24% lower mortality risk from all causes but had 44 to 45% higher risk of MVA deaths relative to the U.S. general population. The higher MVA mortality risk was not associated with deployment to the war zone. After controlling for age, sex, race, marital status, branch of service, and rank, the risk for deployed veterans was comparable to that of nondeployed veterans (hazard ratio = 0.91; 95% confidence interval, 0.77–1.09).
Conclusions: Veterans exhibit significantly higher risk of MVA deaths compared to the U.S. general population. However, deployment to the Iraq or Afghanistan war was not associated with the excess risk. 相似文献
Aerosol composition change between dust storm and non duststorm periods is studied using the TSP (Total SuspendedParticulate) data measured at Gosan, Korea between 1992 and1999. The concentrations of elements measured between 1993and 1996 and those of ions between 1992 and 1999 duringdust storms are compared with those during non-dust stormperiods in spring (March, April, and May). Among theanalyzed ions, the concentrations of crustal species(potassium, calcium, magnesium, and chloride) andanthropogenic species (nitrate and non-sea salt (nss)-sulfate) increased when dust storm occurs while those ofammonium and sodium did not increase. Among the analyzedelements, the concentrations of crustal species (Fe, Al,Ca, Ti, and Zn) increased when dust storm occurs whilethose of anthropogenic species (Mn, V, Ni, Cu, Cd, and Cr)did not increase. The only anthropogenic element of whichconcentration increased during dust storm periods was Pb.It was found that the concentrations of nitrate and nss-sulfatewere highest during spring. Also, the ratio of theyearly average concentrations of nitrate to nss-sulfateincreases, probably due to the emission trend change innortheast Asia, especially, in China. 相似文献
