Time dependent sorption behavior of dinotefuran,imidacloprid and thiamethoxam

Dinetofuran (DNT), imidacloprid (IMD) and thiamethoxam (THM) are among the neonicotinoid insecticides widely used for managing insect pests of agricultural and veterinary importance. Environmental occurrence of neonicotinoid in post-application scenario poses unknown issues to human health and ecology. A sorption kinetic study provides much needed information on physico-chemical interaction of neonicotinoid with soil material. In this research study, time-dependent sorption behavior of DNT, IMD and THM in vineyard soil was studied. Sorption kinetics studies were conducted over a period of 96 hours with sampling duration varying from 0, 2, 4, 8, 12, 24, 60 and 96 hours. All three neonicotinoids exhibited very low sorption potential for the soil investigated. Overall percent sorption for all three neonicotinoids was below 20.04 ± 2.03% with highest percent sorption being observed for IMD followed by DNT and THM. All three neonicotinoids are highly soluble with solubility increasing with IMD < THM < DNT. Although, DNT has the highest solubility among all three neonicotinoids investigated, it exhibited higher percent sorption compared to THM, indicating factors other than solubility influenced the sorption kinetics. Low sorption potential of neonicotinoids indicates greater leaching potential with regard to groundwater and surface water contamination.     

A. L. Young,The history,use, disposition and environmental fate of Agent Orange

Environmental Science and Pollution Research -     

Modelling the reworking effects of bioturbation on the incorporation of radionuclides into the sediment column: implications for the fate of particle-reactive radionuclides in Irish Sea sediments

A microcosm laboratory experiment was conducted to determine the impact of biological reworking by the ragworm Nereis diversicolor on the redistribution of particle-bound radionuclides deposited at the sediment-water interface. Over the course of the 40-day experiment, as much as 35% of a ¹³⁷Cs-labelled particulate tracer deposited on the sediment surface was redistributed to depths of up to 11 cm by the polychaete. Three different reworking models were employed to model the profiles and quantify the biodiffusion and biotransport coefficients: a gallery-diffuser model, a continuous sub-surface egestion model and a biodiffusion model. Although the biodiffusion coefficients obtained for each model were quite similar, the continuous sub-surface egestion model provided the best fit to the data. The average biodiffusion coefficient, at 1.8 ± 0.9 cm² y⁻¹, is in good agreement with the values quoted by other workers on the bioturbation effects of this polychaete species. The corresponding value for the biotransport coefficient was found to be 0.9 ± 0.4 cm y⁻¹. The effects of non-local mixing were incorporated in a model to describe the temporal evolution of measured ⁹⁹Tc and ⁶⁰Co radionuclide sediment profiles in the eastern Irish Sea, influenced by radioactive waste discharged from the Sellafield reprocessing plant. Reworking conditions in the sediment column were simulated by considering an upper mixed layer, an exponentially decreasing diffusion coefficient, and appropriate biotransport coefficients to account for non-local mixing. The diffusion coefficients calculated from the ⁹⁹Tc and ⁶⁰Co cores were in the range 2-14 cm² y⁻¹, which are consistent with the values found by other workers in the same marine area, while the biotransport coefficients were similar to those obtained for a variety of macrobenthic organisms in controlled laboratories and field studies.     

Facilitating Integrated Resource and Environmental Management: Australian and Canadian Perspectives

It is widely believed that improved resource and environmental management outcomes would occur if those responsible took a longer term view, considered whole systems rather than their components in isolation, and co-ordinated and integrated their activities with each other. There has been substantial action in many countries to achieve these ideals but with mixed success. Why has it not been possible to have a more co-ordinated and integrated approach to resource and environmental management (IREM)? We briefly review various conceptual issues regarding the purpose and character of IREM. The core of the paper is analysis of the factors contributing to success or failure, including the requirement that IREM, in practice, must be based on a careful analysis of the need and scope for integration in a given context, the significance of leadership, information access, and the links with other planning and management activities. Obstacles arising from these and other shortcomings, including the focus regarding what IREM involves, bureaucratic resistance, adverse financial arrangements and property rights problems, are also discussed. The paper concludes with five recommendations as to how to enhance integrated resource and environmental management dealing with need, scope and context, best management practice, information accessibility and integration, financial arrangements,and strengthening local and regional planning capacity.     

Winter Hydrology and NO3− Concentrations in a Forested Watershed: A Detailed Field Study in the Adirondack Mountains of New York1

Abstract: More than 85% of NO₃^? losses from watersheds in the northeastern United States are exported during winter months (October 1 to May 30). Interannual variability in NO₃^? loads to individual streams is closely related to interannual climatic variations, particularly during the winter. The objective of our study was to understand how climatic and hydrogeological factors influence NO₃^? dynamics in small watersheds during the winter. Physical parameters including snow depth, soil temperature, stream discharge, and water table elevation were monitored during the 2007‐2008 winter in two small catchments in the Adirondack Mountains, New York State. Snowpack persisted from mid‐December to mid‐April, insulating soils such that only two isolated instances of soil frost were observed during the study period. NO₃^? export during a mid‐winter rain‐on‐snowmelt event comprised between 8 and 16% of the total stream NO₃^? load for the four‐month winter study period. This can be compared with the NO₃^? exported during the final spring melt, which comprised between 38 and 45% of the total four‐month winter NO₃^? load. Our findings indicate that minor melt events were detectable with changes in soil temperature, streamflow, groundwater level, and snow depth. But, based on loading, these events were relatively minor contributors to winter NO₃^? loss. A warmer climate and fluctuating snowpack may result in more major mid‐winter melt events and greater NO₃^? export to surface waters.     

Concerns, dispositions and behaviors of aggressive drivers: what do self-identified aggressive drivers believe about traffic safety?

INTRODUCTION: The purpose of this investigation was to identify beliefs, driving personality dispositions, and behaviors that distinguish self-defined aggressive drivers from non-aggressive drivers. METHOD: Telephone surveys were used to identify self-reported aggressive drivers (n=305) who were compared to non-aggressive drivers (n=1,715) concerning their beliefs, driving behaviors, and self-described driving dispositions. RESULTS: Aggressive drivers, compared to non-aggressive drivers, were less concerned about speeding, aggressive driving, and cell phone use while driving, yet were more likely to have had an encounter with another aggressive driver. They were also more likely to report that they had driven when they knew they had too much to drink, yet they felt less likely that they would be stopped by the police. CONCLUSION: Aggressive drivers display many dispositions that define them as high risk drivers and public information/motivational campaigns alone will likely be ineffective with this group of drivers. Strategies that combine visible enforcement with widespread publicity campaigns appear to be necessary.     

Phosphorus transport through subsurface drainage and surface runoff from a flat watershed in east central Illinois, USA

A long-term water quality monitoring program was established to evaluate the effects of agricultural management practices on water quality in the Little Vermilion River (LVR) watershed, IL. This watershed has intensive random and irregular subsurface drainage systems. The objective of this study was to assess the fate and transport of soluble phosphorus (soluble P) through subsurface drainage and surface runoff. Four sites (sites A, B, C, and E) that had subsurface and surface monitoring programs were selected for this study. Three of the four study sites had corn (Zea mays L.) and soybeans (Glycine max L.) planted in rotations and the other site had seed corn and soybeans. Subsurface drainage and surface runoff across all sites removed an average of 16.1 and 2.6% of rainfall, respectively. Annual flow-weighted soluble P concentrations fluctuated with the precipitation, while concentrations tended to increase with high precipitation coupled with high application rates. The long-term average flow-weighted soluble P concentrations in subsurface flow were 102, 99, 194, and 86 microg L(-1) for sites A, B, C, and E, respectively. In contrast, the long-term average flow-weighted soluble P concentrations in surface runoff were 270, 253, 534, and 572 microg L(-1) for sites As, Bs, Cs, and Es, respectively. These values were substantially greater than the critical values that promote eutrophication. Statistical analysis indicated that the effects of crop, discharge, and the interactions between site and discharge and crop and discharge on soluble P concentrations in subsurface flow were significant (alpha = 0.05). Soluble P mass loads in surface runoff responded to discharge more consistently than in the subsurface flow. Subsurface flow had substantially greater annual average soluble P mass loads than surface runoff due to greater flow volume.     

Projections of hospitalised fall-related injury in NSW, Australia: impacts on the hospital and aged care sectors

Projections of the number, rate and cost of fall-related hospitalised injuries for individuals aged 65 years and older in New South Wales (NSW), Australia were estimated to 2051 for two scenarios: (1) demographic change only using 2008 admission rates; and (2) modelled change using negative binominal regression taking into account current trends in admission rates. Based on demographic change alone, the number and cost of fall injury hospitalisations among older people is expected to increase almost three-fold by 2051. Transfers to permanent residential aged care will also increase 3.2 fold. However, if the fall-related hospitalisation rate sustains its current trend, these increases are projected to be more than ten-fold by 2051. Even with demographic change alone, there will be a significant impact on the resources required to care for older people suffering a fall injury hospitalisation over the next forty years in NSW. The impact on the hospital and aged care sectors will be considerable unless significant improvements occur in the prevention and treatment of fall-related injury in older people.     

Estimating age from recapture data: integrating incremental growth measures with ancillary data to infer age-at-length

Estimating the age of individuals in wild populations can be of fundamental importance for answering ecological questions, modeling population demographics, and managing exploited or threatened species. Significant effort has been devoted to determining age through the use of growth annuli, secondary physical characteristics related to age, and growth models. Many species, however, either do not exhibit physical characteristics useful for independent age validation or are too rare to justify sacrificing a large number of individuals to establish the relationship between size and age. Length-at-age models are well represented in the fisheries and other wildlife management literature. Many of these models overlook variation in growth rates of individuals and consider growth parameters as population parameters. More recent models have taken advantage of hierarchical structuring of parameters and Bayesian inference methods to allow for variation among individuals as functions of environmental covariates or individual-specific random effects. Here, we describe hierarchical models in which growth curves vary as individual-specific stochastic processes, and we show how these models can be fit using capture-recapture data for animals of unknown age along with data for animals of known age. We combine these independent data sources in a Bayesian analysis, distinguishing natural variation (among and within individuals) from measurement error. We illustrate using data for African dwarf crocodiles, comparing von Bertalanffy and logistic growth models. The analysis provides the means of predicting crocodile age, given a single measurement of head length. The von Bertalanffy was much better supported than the logistic growth model and predicted that dwarf crocodiles grow from 19.4 cm total length at birth to 32.9 cm in the first year and 45.3 cm by the end of their second year. Based on the minimum size of females observed with hatchlings, reproductive maturity was estimated to be at nine years. These size benchmarks are believed to represent thresholds for important demographic parameters; improved estimates of age, therefore, will increase the precision of population projection models. The modeling approach that we present can be applied to other species and offers significant advantages when multiple sources of data are available and traditional aging techniques are not practical.     

Mercury fate in ageing and melting snow: development and testing of a controlled laboratory system

A snow cover can modify when, to what extent, and in what form atmospherically deposited mercury is released to the underlying surface media and/or back to the atmosphere. Investigations of mercury transport and transformation processes in snow packs are hampered by the difficulty in controlling experimental and melt conditions and due to the huge variability in the composition and physical structure of environmental snow packs. A method was developed that allows the detailed mechanistic investigation of mercury fate in snow that is made, aged and melted under controlled laboratory conditions. A number of control samples established that mercury in indoor air, scavenged during the snow making process, constitutes the dominant source of mercury in the artificial snow. No addition of mercury is required. The amount of mercury in fresh snow was quantitatively (102 and 106% in two experiments) recovered in the dissolved and particulate fractions of the melt water and the vessel head space, confirming a mass balance for mercury and the absence of unquantifiable mercury sources and sinks in the experimental system. In snow made from unmodified tap water, more than half of the mercury present in the snowpack was recovered from the bottom of the snow vessel after all of the snow had melted. Such late elution is indicative of mercury being mostly associated with particles that are filtered by, and retained in, the shrinking snowpack. Addition of salt to the snow-making water at an environmentally realistic pH notably shifted the distribution of mercury in the snowpack from the particulate to the dissolved phase, resulting in more than 60% of the mercury eluting in the dissolved phase of early melt water fractions.