The future for electrocoagulation as a localised water treatment technology

Electrocoagulation is an electrochemical method of treating polluted water whereby sacrificial anodes corrode to release active coagulant precursors (usually aluminium or iron cations) into solution. Accompanying electrolytic reactions evolve gas (usually as hydrogen bubbles) at the cathode. Electrocoagulation has a long history as a water treatment technology having been employed to remove a wide range of pollutants. However electrocoagulation has never become accepted as a 'mainstream' water treatment technology. The lack of a systematic approach to electrocoagulation reactor design/operation and the issue of electrode reliability (particularly passivation of the electrodes over time) have limited its implementation. However recent technical improvements combined with a growing need for small-scale decentralised water treatment facilities have led to a re-evaluation of electrocoagulation. Starting with a review of electrocoagulation reactor design/operation, this article examines and identifies a conceptual framework for electrocoagulation that focuses on the interactions between electrochemistry, coagulation and flotation. In addition detailed experimental data are provided from a batch reactor system removing suspended solids together with a mathematical analysis based on the 'white water' model for the dissolved air flotation process. Current density is identified as the key operational parameter influencing which pollutant removal mechanism dominates. The conclusion is drawn that electrocoagulation has a future as a decentralised water treatment technology. A conceptual framework is presented for future research directed towards a more mechanistic understanding of the process.     

Residence and place image

Data are presented for a particular population on its perception of English and Welsh local authority areas in terms of desirability for residence. The method employed permits a distinction between positive and negative judgements as well as a measure of the differing degree to which areas figure in the mind at all. It is established that the areas are seen in terms of a sharply differentiated hierarchy of preference and that there is considerable variation in the extent to which areas are “visible”. In aggregate negative judgements predominate and the most frequently expressed attitude is strong dislike. Places in the south‐west are popular as are some places in the north. London Boroughs are unpopular although in varying degrees. The most favoured place is Cornwall and the least favoured is Wolverhampton. It is argued that perceptions studied in the “direct” way used here are important to complement those employing an “oblique” method in which criteria of choice are assumed or established by social survey and then used to create a profile of preference against which places can be measured and ranked.     

ATFITUDES TOWARDS ARTIFICIAL WETLANDS IN ONTARIO FOR STORMWATER CONTROL AND WATERFOWL HABITAT1

ABSTRACT: The objective was to survey individuals from different interest groups in Ontario to ascertain attitudes towards the use of artificial wetlands for stormwater management and to provide waterfowl habitat. In total, 166 questionnaires were distributed and 124 cempleted returns were received. The results of the survey show that the provision of wetlands as waterfowl habitats in the context of stormwater impoundments is severely limited and is not considered an important management option. The overwhelming rejection of this integrated approach seems to be due to a lack of understanding and its comparative newness. Some of the perceived problems and concerns could be addressed by improvements in the design of the artificial wetlands. The design and implementation of an artificial wetland prototype as part of an education program in Ontario is recommended. A few research opportunities also are outlined.     

PULSED TRICKLING EFFECTS ON SOIL MOISTURE DISTRIBUTION1

ABSTRACT Laboratory experiments were conducted to study effects of trickle emitter discharge rate on the distribution of soil moisture in a silty-clay loam soil. Both pulsed and continuous irrigation treatments were studied. A simulation model was used to evaluate the results obtained in the laboratory. The agreement between the predicted and measured soil moisture distribution patterns was quite good. For both pulsed and continuous applications, increasing trickle discharge rate resulted in a decrease in the horizontal component and an increase in the vertical component of the wetted soil profile. Compared to the continuous treatments, pulsed applications resulted in significant reduction in water loss below the root zone. Pulsed applications rates can replace continuous small discharge rates to reduce irrigation water runoff problems on heavy soils and with restricted infiltration allow the use of larger emitter orifices to decrease potential clogging of the trickle system.     

The Characterisation of Settled Dust by Scanning Electron Microscopy and Energy Dispersive X-ray Analysis

Settled dust has been collected inside the main foyers ofthree University buildings in Wolverhampton City Centre,U.K. Two of the three buildings are located in a streetcanyon used almost exclusively by heavy duty dieselvehicles. The dust was collected on adhesive carbonspectro-tabs to be in a form suitable for analysis byscanning electron microscope and energy dispersive X-rayanalysis. Using these analytical techniques, individualparticle analysis was undertaken for morphology andchemistry. Seasonal variations and variations due tolocation were observed in both the morphologicalmeasurements and chemical analysis. Many of the differencesappear attributable to the influence of road traffic, inparticular, the heavy duty diesel vehicles, travellingalong the street canyon.     

An approach to integrate impact scoping with environmental impact assessment

Impact scoping is the process of identifying important issues of a proposal and focusing the environmental impact assessment (EIA) on the high-priority issues. Although impact scoping in one form or another has been inherent to EIA for some time, documentation of its development and discussion of refinements to impact scoping processes have not been forthcoming. This article traces the development of impact scoping through time and highlights the need for such processes in EIA. A focused environmental assessment (FEA) approach to impact scoping that is suitable for implementation in an EIA is presented here and advantages of its use are delineated. FEA is a three-staged process that encourages impact scoping through progressive steps including impact identification, assessment and management planning. FEA combines a suite of EIA methods including: issues matrices, impact hypotheses, valued ecosystem components, and stakeholder participation sessions to effectively integrate impact scoping with EIA.     

Resource scarcity,energy use and environmental impact: A case study of the New Bedford,Massachusetts, USA,fisheries

The commercial fishing fleet in New Bedford, Massachusetts, USA, harvests seafood on George’s Bank, home of one of the nation’s most productive fisheries. We calculated the energy return on investment (EROI) and carbon intensity of protein harvest in the New Bedford fisheries from 1968 to 1988. EROI is the ratio of the energy content of the edible fish protein harvested to the quantity of fossil fuel energy used directly in the harvesting process. Carbon intensity is the quantity of carbon dioxide (CO₂) released (from the burning of fossil fuels) per calorie of edible fish protein harvested. The results show that the EROI of protein harvest declined from 0.18 to 0.028 from 1968 to 1988, indicating that the energy used to harvest seafood increased from about 6 to 36 kcal of fuel for each kilocalorie of protein harvested. The quantity of CO₂ released per calorie of edible fish protein is a linear function of energy use and therefore increased in a similar manner. During this period there was a large increase in fishing effort (caused by the increase in the real price of seafood products, favorable tax treatment for new vessel construction, and low interest loans from the government), and a decline in several important species of fish. The results suggest that fishing pressure could be managed effectively by the regulation of fuel use by the fleet. Despite the increase in the price of many seafood products, fishermen absorbed many of the costs of increasing scarcity in the form of longer working hours and fewer men per vessel.     

Simulating endosulfan transport in runoff from cotton fields in Australia with the GLEAMS model

Endosulfan (6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-6,9methano-2,4,3-benzodioxathiepin 3-oxide), a pesticide that is highly toxic to aquatic organisms, is widely used in the cotton (Gossypium hirsutum L.) industry in Australia and is a risk to the downstream riverine environment. We used the GLEAMS model to evaluate the effectiveness of a range of management scenarios aimed at minimizing endosulfan transport in runoff at the field scale. The field management scenarios simulated were (i) Conventional, bare soil at the beginning of the cotton season and seven irrigations per season; (ii) Improved Irrigation, irrigation amounts reduced and frequency increased to reduce runoff from excess irrigation; (iii) Dryland, no irrigation; (iv) Stubble Retained, increased soil cover created by retaining residue from the previous crop or a specially planted winter cover crop; and (v) Reduced Sprays, a fewer number of sprays. Stubble Retained was the most effective scenario for minimizing endosulfan transport because infiltration was increased and erosion reduced, and the stubble intercepted and neutralized a proportion of the applied endosulfan. Reducing excess irrigation reduced annual export rates by 80 to 90%, but transport in larger storm events was still high. Reducing the number of pesticide applications only reduced transport when three or fewer sprays were applied. We conclude that endosulfan transport from cotton farms can be minimized with a combination of field management practices that reduce excess irrigation and concentration of pesticide on the soil at any point in time; however, discharges, probably with endosulfan concentrations exceeding guideline values, will still occur in storm events.     

Efficiency of energy delivery systems: I. An economic and energy analysis

Energy-return-on-investment (ERI) analysis is a variation of more traditional cost-benefit analyses, a variation that is particularly important in times of diminishing fuel resources. We present a simple set of procedures for ERI analysis and apply those procedures to central New York State, where there is a proposal for a new 870 MW_e coal-fired generating station. We compared the energy and dollar costs of building that facility with the costs of an alternative comprehensive regional program of insulation. The analysis showed that regional insulation was more efficient in conserving energy than the plant was in providing it by at least a factor of 4 in economic terms and by a factor of more than 15 when viewed as energy returned on energy invested.