Remediation of toxic metal contaminated soil by washing with biodegradable aminopolycarboxylate chelants

Ex situ soil washing with synthetic extractants such as, aminopolycarboxylate chelants (APCs) is a viable treatment alternative for metal-contaminated site remediation. EDTA and its homologs are widely used among the APCs in the ex situ soil washing processes. These APCs are merely biodegradable and highly persistent in the aquatic environments leading to the post-use toxic effects. Therefore, an increasing interest is focused on the development and use of the eco-friendly APCs having better biodegradability and less environmental toxicity. The paper deals with the results from the lab-scale washing treatments of a real sample of metal-contaminated soil for the removal of the ecotoxic metal ions (Cd, Cu, Ni, Pb, and Zn) using five biodegradable APCs, namely [S,S]-ethylenediaminedisuccinic acid, imminodisuccinic acid, methylglycinediacetic acid, DL-2-(2-carboxymethyl) nitrilotriacetic acid (GLDA), and 3-hydroxy-2,2′-iminodisuccinic acid. The performance of those biodegradable APCs was evaluated for their interaction with the soil mineral constituents in terms of the solution pH and metal-chelant stability constants, and compared with that of EDTA. Speciation calculations were performed to identify the optimal conditions for the washing process in terms of the metal-chelant interactions as well as to understand the selectivity in the separation ability of the biodegradable chelants towards the metal ions. A linear relationship between the metal extraction capacity of the individual chelants towards each of the metal ions from the soil matrix and metal-chelant conditional stability constants for a solution pH greater than 6 was observed. Additional considerations were derived from the behavior of the major potentially interfering cations (Al, Ca, Fe, Mg, and Mn), and it was hypothesized that use of an excess of chelant may minimize the possible competition effects during the single-step washing treatments. Sequential extraction procedure was used to determine the metal distribution in the soil before and after the extractive decontamination using biodegradable APCs, and the capability of the APCs in removing the metal ions even from the theoretically immobilized fraction of the contaminated soil was observed. GLDA appeared to possess the greatest potential to decontaminate the soil through ex situ washing treatment compared to the other biodegradable chelants used in the study.     

Detection of hazardous pollutants in chrome-tanned leather using locally developed laser-induced breakdown spectrometer

K?z?l?rmak River has been used as Ankara??s drinking water source for approximately 1.5?years. Therefore, this region??s water, sediment, and fish samples are measured for detecting the heavy metals. This is important for the current situation as well as the future in terms of potential impact. The amount of heavy metals in drinking water should be within the limited values; otherwise, the accumulation of heavy metals will cause many problems to living organisms. Especially high levels of arsenic, cadmium, nickel, mercury, etc. are very dangerous to freshwater ecosystems as for human if the water is being use as drinking water. In this study, water, sediment samples, muscle, and gills of three fish species (Capoeta tinca, Capoeta capoeta, Leuciscus cephalus) were analyzed for the presence of heavy metals such as (Al, Fe, As, Cd, Ni, Mn, Se, Si) to determine present accumulation levels and possible toxic effect. The accumulation pattern of heavy metals in the water, sediment, and fish tissue follows the sequence: Si > Fe > Al > Mn > As > Ni > Se > Cd, Fe > Al > Mn > Ni > As > Se > Cd, and Fe > Al > Mn > As > Ni > Si > Cd. In addition, the detected concentrations of heavy metals in the K?z?l?rmak and Delice Rivers are compared with other heavy metal studies in the other main rivers and lakes in Turkey.     

Potential for internal loading by phosphorus based on sequential extraction of surficial sediment in a shallow Egyptian Lake

The fractionation of phosphorus (P) in shallow Lake Maryout surficial sediments was investigated in order to understand its potential availability in relation to the eutrophication status of this lake. The rank order of P fractions was NaOH-P > HCl-P > NH₄Cl-P > BD-P. The metal oxide-bound P (NaOH-P) averaged 43% in this hypereutrophic lake and would be potentially available under low oxygen conditions. The highly available, loosely sorbed P (NH₄Cl-P) represented 20% of the sedimentary inorganic P on average, while the reductant P (BD-P) averaged 15% and is also considered highly available under low oxygen conditions. The less available calcium-bound P (HCl-P) represented 22% of sedimentary inorganic P. Lake Maryout exhibits high potential for release of P from sediment in forms available to algae, which is undesirable for eutrophication control. The range of potentially available P in tested sediments was 1,541 to 3,990 mg/kg (ppm), a very high quantity capable of supporting algal blooms independent of external loading.     

Optimization of integrated water quality management for agricultural efficiency and environmental conservation

The scarcity of water resources in Egypt has necessitated the use of various types of lower quality water. Agricultural drainage water is considered a strategic reserve for meeting increasing freshwater demands. In this study, a novel model series was applied to a drainage basin in the Nile Delta to optimize integrated water quality management for agriculture and the aquatic environment. The proposed model series includes a waste load allocation model, an export coefficient model, a stream water quality model, and a genetic algorithm. This model series offers an optimized solution for determining the required removal levels of total suspended solids (TSS), the chemical oxygen demand (COD) at point and non-point pollution sources, and the source flows that require treatment to meet a given water quality target. The model series was applied during the summer and winter to the El-Qalaa basin in the western delta of the Nile River. Increased pollutant removal and treated fractions at point and non-point sources reduced violations of the TSS standards from 732.6 to 238.9 mg/L in summer and from 543.1 to 380.9 mg/L in winter. Likewise, violations of the COD standards decreased from 112.4 mg/L to 0 (no violations) in summer and from 91.7 mg/L to no violations in winter. Thus, this model is recommended as a decision support tool for determining a desirable waste load allocation solution from a trade-off curve considering costs and the degree of compliance with water quality standards.     

Hydrogeochemical evaluation of calcareous eolianite aquifer with saline soil in a semiarid area

The aim of this study is to evaluate the groundwater geochemistry in Burg Elarab area as an example of a calcareous eolianite aquifer that is covered with saline soil in a semiarid climatic condition. To conduct this study, 37 groundwater samples were taped from the production wells in addition to two surface water samples from Mallahet Mariut Lake and Bahig Canal. To elucidate the origin of dissolved ions and the geochemical processes influencing this groundwater, combinations of geomorphological, pedological, hydrogeological, hydrochemical, and statistical approaches were considered. Results suggest that the groundwater flows from both sides of the plain to the central area. Soil type and salinity and the intruded brackish lake water are the main factors controlling the groundwater chemistry. Chemically, the groundwater samples were classified into three groups. Group 1 samples have higher salinity range and characterize the area close to Mallahet Mariut and are influenced by cation exchange processes. Group 2 samples have an intermediate salinity range, occupy most of the plain area, and receive water from direct infiltrations and mixing between different recharge sources. Group 3 samples have low salinity range and limited areal extent and characterize the groundwater flowing from the Mariut Tableland. Reverse ion exchange is the predominant process in the latter group. Calcite precipitation is a general phenomenon characterizing all the groundwater types in the study area.     

A novel framework-based cuckoo search algorithm for sizing and optimization of grid-independent hybrid renewable energy systems

Hybrid renewable energy systems (HRES) turned into an appealing choice for supplying loads in remote areas. The application of smart grid principals in HRES provides a communication between the load and generation from the HRES. Using smart grid in the HRES will optimally utilize the generating resources to reschedule the loads depending on its importance. This paper presents a new proposed design and optimization simulation program for techno-economic sizing of grid-independent hybrid PV/wind/diesel/battery energy system using Cuckoo search (CS) optimization algorithm. Using of CS will help to get the global minimum cost condition and prevent the simulation to be stuck around local minimum. A new proposed simulation program (NPSP) is acquainted using CS to determine the optimum size of each component of the HRES for the lowest cost of generated energy and the lowest value of dummy energy, at highest reliability. A detailed economic methodology to obtain the price of the generated energy has been introduced. Results showed that using CS reduced the time required to obtain the optimal size with higher accuracy than other techniques used iterative techniques, Genetic Algorithm (GA), and Particle Swarm Optimization (PSO). Numerous significant outcomes can be extracted from the proposed program that could help scientists and decision makers.     

Antenatal corticosteroids and outcomes in gastroschisis: A multicenter retrospective cohort study

Objective

In gastroschisis, there is evidence to suggest that gut dysfunction develops secondary to bowel inflammation; we aimed to evaluate the effect of maternal antenatal corticosteroids administered for obstetric reasons on time to full enteral feeds in a multicenter cohort study of gastroschisis infants.

Methods

A three center, retrospective cohort study (1992-2013) with linked fetal/neonatal gastroschisis data was conducted. The primary outcome measure was time to full enteral feeds (a surrogate measure for bowel function) and secondary outcome measure was length of hospital stay. Analysis included Mann-Whitney and Cox regression.

Results

Of 500 patients included in the study, 69 (GA at birth 34 [25-38] weeks) received antenatal corticosteroids and 431 (GA at birth 37 [31-41] weeks) did not. Antenatal corticosteroids had no effect on the rate of reaching full feeds (Hazard ratio HR 1.0 [95% CI: 0.8-1.4]). However, complex gastroschisis (HR 0.3 [95% CI: 0.2-0.4]) was associated with an increased time to reach full feeds and later GA at birth (HR 1.1 per week increase in GA [95% CI: 1.1-1.2]) was associated with a decreased time to reach full feeds.

Conclusion

Maternal antenatal corticosteroids use, under current antenatal steroid protocols, in gastroschisis is not associated with an improvement in neonatal outcomes such as time to full enteral feeds or length of hospital stay.     

Biological silicon nanoparticles improve Phaseolus vulgaris L. yield and minimize its contaminant contents on a heavy metals-contaminated saline soil

The synthesis of biological silicon nano-particles (Bio-Si-NPs) is an eco-friendly and low-cost method. There is no study focusing on the effect of Bio-Si-NPs on the plants grown on saline soil contaminated with heavy metals. In this study, an attempt was made to synthesis Bio-Si-NPs using potassium silica florid substrate, and the identified Aspergillus tubingensis AM11 isolate that separated from distribution systems of the potable water. A two-year field trial was conducted to compare the protective effects of Bio-Si-NPs (2.5 and 5.0 mmol/L) and potassium silicate (10 mmol/L) as a foliar spray on the antioxidant defense system, physio-biochemical components, and the contaminants contents of Phaseolus vulgaris L. grown on saline soil contaminated with heavy metals. Our findings showed that all treatments of Bio-Si-NPs and potassium silicate significantly improved plant growth and production, chlorophylls, carotenoids, transpiration rate, net photosynthetic rate, stomatal conductance, membrane stability index, relative water content, free proline, total soluble sugars, N, P, K, Ca²⁺, K⁺/Na⁺, and the activities of peroxidase, catalase, ascorbic peroxidase and superoxide oxide dismutase. Application of Bio-Si-NPs and potassium silicate significantly decreased electrolyte leakage, malondialdehyde, H₂O₂, O₂^??, Na⁺, Pb, Cd, and Ni in leaves and pods of Phaseolus vulgaris L. compared to control. Bio-Si-NPs were more effective compared to potassium silicate. Application of Bio-Si-NPs at the rate of 5 mmol/L was the recommended treatment to enhance the performance and reduce heavy metals content on plants grown on contaminated saline soils.