Phytoremediation of an aged petroleum contaminated soil using endophyte infected and non-infected grasses

Phytoremediation is a promising technique for cleaning petroleum contaminated soils. In this study, the effects of two grass species (Festuca arundinacea Schreb. and Festuca pratensis Huds.), infected (E(+)) and non-infected (E(-)) by endophytic fungi (Neotyphodium coenophialum and Neotyphodium uncinatum, respectively) on the degradation of petroleum hydrocarbons in an aged petroleum contaminated soil was investigated. Plants were grown in the soil for 7 months and unplanted soil considered as control. At the end of the experiment, total and oil-degrading bacteria, dehydrogenase activity, water-soluble phenols, total petroleum hydrocarbons (TPH) and polycyclic aromatic hydrocarbons (PAHs) contents were measured in the soil. The results demonstrated that E(+) plants contained more root and shoot biomass than E(-) plants and created higher levels of water-soluble phenols and dehydrogenase activity in the soil, while there was no significant difference in bacterial counts of planted soils. Planting stimulated total and oil-degrading bacterial numbers, dehydrogenase activity and the soil content of water-soluble phenols. Regardless of endophyte infection, PAH and TPH removal in the rhizosphere of plants were 80-84 and 64-72% respectively, whereas the removals in controls were 56 and 31%, respectively. It was revealed that TPHs in retention time range of n-alkanes with C(10)-C(25) chain lengths and TPH were more degraded in the rhizosphere of E(+) plants compared to E(-) ones. Thus, grasses infected with endophytic fungi could be more efficient for removal of TPH from oil-contaminated soils.     

Migration and reclamation in Northeast China in response to climatic disasters in North China over the past 300?years

Climatic disaster-induced migration and its effects on land exploitation of new settlements is a crucial topic that needs to be researched to better understand the impact of climate change and human adaptation. This paper focuses on the process and mechanism of migrant–reclamation in Northeast China in response to climatic disasters over the past 300 years. The research used comparative analysis of key interlinked factors in this response involving drought/flood events, population, cropland area, farmer revolts, administrations establishment, and land reclamation policies. It draws the following conclusions: (1) seven peaks of migrants–reclamation in Northeast China were evident, most likely when frequent climatic disasters happened in North China, such as the drought–flood in 1851–1859, drought in 1875–1877, and drought 1927–1929; (2) six instances of policy transformation adopted to cope with extreme climatic events, including distinctive examples like changing to a firm policy prohibiting migration in 1740 and a subsequent lifting of that prohibition in 1860; and (3) the fast expansion of the northern agricultural boundary since the middle of the nineteenth century in this area benefited from a climate change trend from a cold period into a warm period. Altogether, over the past 300 years, extreme climatic disasters in North China have deepened the contradiction between the limited land resources and the rapidly increasing population and have resulted in migration and reclamation in Northeast China. Climate, policy, and reclamation constructed an organic chain of response that dominated the land use/cover change process of Northeast China.     

Pore-scale modeling of dispersion in disordered porous media

We employ a direct pore-level model of incompressible flow that uses the modified moving particle semi-implicit (MMPS) method. The model is capable of simulating both unsteady- and steady-state flow directly in microtomography images of naturally-occurring porous media. We further develop this model to simulate solute transport in disordered porous media. The governing equations of flow and transport at the pore level, i.e., Navier-Stokes and convection-diffusion, are solved directly in the pore space mapped by microtomography techniques. Three naturally-occurring sandstones are studied in this work. We verify the accuracy of the model by comparing the computed longitudinal dispersion coefficients against the experimental data for a wide range of Peclet numbers, i.e., 5×10(-2)相似文献   

Geostatistical Assessment of the Impact of World War I on the Spatial Occurrence of Soil Heavy Metals

Previous research showed a regional Cu enrichment of 6 mg kg⁻¹ in the top soil of the Ypres war zone (Belgium), caused by corrosion of WWI shell fragments. Further research was required since in addition to Cu, also As, Pb, and Zn were used during the manufacturing of ammunition. Therefore, an additional data collection was conducted in which the initial Cu data set was tripled to 731 data points and extended to eight heavy metals (As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn) which permitted (1) to evaluate the environmental impact of the heavy metals at a regional scale and (2) to assess their regional spatial occurrence by performing an optimized geostatistical modeling. The results showed no pollution at a regional scale, but sometimes locally concentrations exceeded the soil sanitation threshold, especially for Cu, Pb, and Zn. The spatial patterns of Ni and Cr were related to variations in soil texture whereas the occurrences of Cu and Pb were clearly linked to WWI activities. This difference in spatial behavior was confirmed by an analysis of coregionalization.     

Separation and determination of trace levels of aromatic amines by HPLC

Aromatic amines were analysed by normal phase and reverse phase high performance liquid chromatography employing silica gel and octadecyl silane (ODS) columns, respectively. A number of mobile phases were used. The results obtained on silica gel column were compared with those achieved on reverse phase column. Excellent results were obtained on ODS and shoulder peaks were eliminated when a mixture of methyl alcohol and sodium perchlorate was used as mobile phase.     

Evaluation of the in-situ aerobic cometabolism of chlorinated ethenes by toluene-utilizing microorganisms using push-pull tests

A series of transport, biostimulation, and activity push-pull tests were performed under induced and natural gradient conditions in a trichloroethene (TCE) and cis-dichloroethene (c-DCE) contaminated aquifer. Transport tests demonstrated the feasibility of injecting and recovering complex solute mixtures from the aquifer. During the biostimulation tests, decreases in toluene concentration and the production of o-cresol as an intermediate oxidation product indicated the presence of toluene-utilizing microorganisms. Activity tests demonstrated that the stimulated microbial community had the ability to transform injected c-DCE and trans-dichloroethene (t-DCE) at similar zero-order rates. Injected isobutene was oxidized to isobutene oxide, which indicated that a toluene ortho-monooxygenase enzyme system was likely responsible for the observed c-DCE and t-DCE transformations. c-DCE zero-order transformation rates in drift push-pull tests were similar to those obtained from traditional push-pull tests (about 0.1 microM/h). Analysis of drift test data using first-order kinetic analysis resulted in similar conclusions as those obtained using zero-order kinetic analyses. When 1-butyne, an inhibitor of toluene ortho-monooxygenase, was added to injected test solutions, the oxidation of toluene, and the transformation of isobutene, c-DCE, and t-DCE were inhibited. The results illustrate how a series of push-pull tests can be used in combination to detect, quantify and confirm in-situ cometabolic microbial transformations.     

Indoor/Outdoor relationships, trends, and carbonaceous content of fine particulate matter in retirement homes of the Los Angeles Basin

Hourly indoor and outdoor fine particulate matter (PM2.5), organic and elemental carbon (OC and EC, respectively), particle number (PN), ozone (O3), carbon monoxide (CO), and nitrogen oxide (NOx) concentrations were measured at two different retirement communities in the Los Angeles, CA, area as part of the Cardiovascular Health and Air Pollution Study. Site A (group 1 [G1]) was operated from July 6 to August 20, 2005 (phase 1 [P1]) and from October 19 to December 10, 2005 (P2), whereas site B (group 2 [G2]) was operated from August 24 to October 15, 2005 (P1), and from January 4 to February 18, 2006 (P2). Overall, the magnitude of indoor and outdoor measurements was similar, probably because of the major influence of outdoor sources on indoor particle and gas levels. However, G2 showed a substantial increase in indoor OC, PN, and PM2.5 between 6:00 and 9:00 a.m., probably from cooking. The contributions of primary and secondary OC (SOA) to measured outdoor OC were estimated from collected OC and EC concentrations using EC as a tracer of primary combustion-generated OC (i.e., "EC tracer method"). The study average outdoor SOA accounted for 40% of outdoor particulate OC (40-45% in the summer and 32-40% in the winter). Air exchange rates (hr(-1)) and infiltration factors (Finf; dimensionless) at each site were also determined. Estimated Finf and measured particle concentrations were then used in a single compartment mass balance model to assess the contributions of indoor and/or outdoor sources to measured indoor OC, EC, PM2.5, and PN. The average percentage contributions of indoor SOA of outdoor origin to measured indoor OC were approximately 35% (during G1P1 and G1P2) and approximately 45% (for G2P1 and G2P2). On average, 36% (G2P1) to 44% (G1P1) of measured indoor OC was composed of outdoor-generated primary OC.     

An improved optimization model for predicting Pb recovery efficiency from residual of liberator cells: a hybrid of support vector regression and modified tunicate swarm algorithm

Journal of Material Cycles and Waste Management - In this study, a hybrid of support vector regression and a modified tunicate swarm algorithm (SVR-MTSA) strategy is developed to optimize the...     

Effect of oil pollution on function of sandy soils in protected deserts and investigation of their improvement guidelines (case study: Kalmand area,Iran)

Soil pollution is one of the most dangerous sorts of environmental pollutions because of waste materials, fossil fuels, etc. Unfortunately in developing countries, there are very few arrangements to prevent soil pollution due to the fossil fuels and to improve polluted soil. In this research, influences of gas oil on properties of Kalmand protected area’s sandy soil near Yazd, Iran, were studied. It was found that gas oil constituted 5.25% of soil weight in the refueling station in the region. Therefore, cleaning and strengthening of the soil by adding cement rather than expensive and complicated methods were the most important goals of this research. First, the influence of gas oil on soil properties was studied, and to improve the soil, different percentages of ordinary portland cement were added to the polluted sand to study the improved soil properties using laboratory tests. It was found that unconfined compressive strength, cohesion, and angle of internal friction of sample with 16% cement and 8% gas oil after 28 days of curing were higher than those of the specimen of 6% cement and 14% gas oil, at 4.6, 5.4, and 1.3 times, respectively. Moreover, based on falling head tests it was observed that permeability of the stabilized specimens decreased substantially. From SEM tests, fewer voids were observed in the stabilized samples, which led to less pollutant penetration into the soil. According to EDX, although dangerous elements in the contaminated specimen made up 3.99% of the specimen total weight, addition of cement introduced considerable amounts of elements that are vital for pozzolanic reactions. Therefore, it can be concluded that addition of cement to the gas oil-polluted soil not only can improve geotechnical properties of the soil and reduce its permeability, but also is very efficient for environmental issues.     

Electrospinning production of nanofibrous membranes

Environmental Chemistry Letters - Electrospinning has attracted a worldwide interest as a technique for the production of nanofibrous membranes with diameter ranging 2 nm to several...