Perfluoroalkyl carboxylates and sulfonates and precursors in relation to dietary source tracers in the eggs of four species of gulls (Larids) from breeding sites spanning Atlantic to Pacific Canada

In the present study, we identified and examined the spatial trends, sources and dietary relationships of bioaccumulative perfluorinated sulfonate (PFSA; C(6), C(8), and C(10) chain lengths) and carboxylate (PFCA; C(6) to C(15) chain lengths) contaminants, as well as precursor compounds including several perfluorinated sulfonamides, and fluorotelomer acids and alcohols, in individual eggs (collected in 2008) from four gull species [glaucous-winged (Larus glaucescens), California (Larus californicus), ring-billed (Larus delawarensis) and herring (Larus argentatus) gulls] from 15 marine and freshwater colony sites in provinces across Canada. The pattern of PFSAs was dominated by perfluorooctane sulfonate (PFOS; >89% of ΣPFSA concentration) regardless of egg collection location. The highest ΣPFSA concentrations were found in the eggs collected in the urbanized areas in the Great Lakes and the St. Lawrence River area [Big Chicken Island 308 ng/g ww, Toronto Harbour 486 ng/g ww, and Ile Deslauriers (HG) 299 ng/g ww]. Also, eggs from all freshwater colony sites had higher ΣPFSA concentrations, which were significant (p<0.05) in many cases, compared to the marine sites with the exception of the Sable Island colony in Atlantic Canada off the coast of Nova Scotia. C(6) to C(15) chain length PFCAs were detected in the eggs, although the pattern was variable among the 15 sites, where PFUnA and PFTrA dominated the pattern for most colonies. Like the ΣPFSA, the highest concentrations of ΣPFCA were found in the eggs from Big Chicken Island, Toronto Harbour, Ile Deslauriers (HG), and Sable Island, although not all freshwater sites had higher concentrations compared to marine sites. Dietary tracers [δ(15)N and δ(13)C stable isotopes (SIs)] revealed that PFSA and PFCA exposure is colony dependent. SI signatures suggested that gulls from most marine colony sites were exposed to PFCs via marine prey. The exception was the Mandarte Island colony in Pacific British Columbia, where PFSA and PFCA exposure appeared to be via terrestrial and/or freshwater prey consumption. The same was true for the freshwater sites where egg SIs suggested both aquatic and terrestrial prey consumption as the source for PFC exposure depending on the colony. Both aquatic (marine and freshwater) and terrestrial prey are likely sources of PFC exposure to gulls but exposure scenarios are colony-specific.     

Trampling Impacts on Thermotolerant Vegetation of Geothermal Areas in New Zealand

Geothermal features such as geysers, mud pools, sinter terraces, fumaroles, hot springs, and steaming ground are natural attractions often visited by tourists. Visitation rates for such areas in the Taupo Volcanic Zone of New Zealand are in the order of hundreds of thousands annually. These areas are also habitat for rare and specialized plant and microbial communities that live in the steam-heated soils of unusual chemical composition. We evaluated historical and current trampling impacts of tourists on the thermotolerant vegetation of the Waimangu and Waiotapu geothermal areas near Rotorua, and compared the results to experimental trampling at a third site (Taheke) not used by tourists. Historical tourism has removed vegetation and soil from around key features, and remaining subsoil is compacted into an impervious pavement on which vegetation recolonization is unlikely in the short term. Social tracks made by tourists were present at both tourist sites often leading them onto hotter soils than constructed tracks. Vegetation height and cover were lower on and adjacent to social tracks than further from them. Thermotolerant vegetation showed extremely low resistance to experimental trampling. This confirms and extends previous research that also shows that thallophytes and woody shrubs, life forms that dominate in thermotolerant vegetation, are vulnerable to trampling damage. Preservation of these vulnerable ecosystems must ensure that tourist traffic is confined to existing tracks or boardwalks, and active restoration of impacted sites may be warranted.     

Fluldized-Bed Combustion

The Fourth International Conference on Fluidized Bed Combustion (FBC) was held at The MITRE Corporation in McLean, VA, December 9 to 11, 1975. With attendees from Great Britain, West Germany, Japan, Canada, and Sweden, the conference apparently fulfilled its international scope and intent.

The objectives of the conference were to review the current state of technology in FBC, to promote technical information exchange on FBC and related areas, and to generate a useful technical information base for further FBC development. Throughout the conference, the goal of commercialization was repeatedly emphasized.

Sponsored by the U.S. Energy Research and Development Administration (ERDA) and coordinated by MITRE, this meeting was the most comprehensive event in the seven year series of conferences on this subject according to attendees. ERDA, the government’s lead agency in FBC technology development, is the principal sponsor and coordinator of the National Fluidized Bed Combustion Program with the goal of advancing the commercialization time frame for FBC. Prior conferences in this series were hosted by the Environmental Protection Agency (EPA) at about two year intervals at Hueston Woods, Ohio. The last EPA conference was held in October 1972.     

Effect of interior door position on room-to-room differences in residential pollutant concentrations after short-term releases

Residential interior door positions influence the pollutant concentrations that result from short-term indoor sources, such as cigarettes, candles, and incense. To elucidate this influence, we reviewed past studies and conducted new experiments in three residences: a single-story 714 m³ ranch-style house, a 510 m³ two-story split-level house, and a 200 m³ two-story house. During the experiments, we released sulfur hexafluoride or carbon monoxide tracer gas over short periods (≤30 min) and measured concentrations in the source room and at least one other (receptor) room for various interior door opening positions. We found that closing a door between rooms effectively prevented transport of air pollutants, reducing the average concentration in the receptor room relative to the source room by 57–100% over exposure periods of 1–8 h. When intervening doors were partially or fully open, the reduction in average concentrations ranged from 3% to 99%, varying as a function of door opening width and the distance between source and receptor rooms.     

Safety climate

Safety climate, the objective measurement of attitudes and perceptions toward Occupational Health & Safety (OH&S) issues, has been largely ignored and measures such as lost time and frequency rate have been used to determine the efficacy of OH&S programs. Yet, it is clear that measuring the precursors of accidents identified in a safety climate analysis provides a powerful proactive management tool. This paper reports on safety climate factors found in clerical and service organizations in Australia. Concurrent validity studies are reported. In contradistinction to published studies, it is argued that safety climate factors are not stable across organizations. The significance of this for planning and assessing the efficacy of OH&S programs is discussed. It is concluded that although safety climate factors are not stable, the safety climate factor pattern identified in organizations provides a powerful management tool for designing OH&S programs.     

LINEAR PROGRAMMING APPLICATIONS IN WATER RESOURCES1

Applications of linear programming to water quality and water quantity problems are discussed, and a fairly comprehensive sample of recent literature in these areas is reviewed. Basic elements of linear programming are also discussed. Emphasis is placed on the elements of linear programming that make it a useful tool for analyzing water resource problems and the basic features of various water resource problems that render them amenable to meaningful analysis by linear programming.     

Assessment of space utilisation in a subtidal temperate bryozoan community

On subtidal hard substrata, Bryozoa are often very abundant, both in terms of numbers of colonies and numbers of species. To investigate how so many species are able to co-exist, often in close proximity to each other, subtidal material was dredged from an area of bryozoan-rich coarse shelly sea-bed off the south-west of the Isle of Man (British Isles) in autumn 1984 and 1985. A survey was performed on the distribution of colonies of eight common, encrusting cheilostome bryozoan species across the surfaces of four types of empty, disarticulated bivalve shells. Each species was found to be significantly commoner on certain substratum types such as rough surfaces or inner concave surfaces. Fenestrulina malusii (Audouin) showed a further, more specific, tendency to be signficantly more abundant on the grooves of the corrugated inner surfaces of left valves of Pecten maximus (L.). In general however there was much overlap in distribution and it is proposed that such large numbers of species are able to co-exist because of the evolution of different life-history strategies ensuring that each species uses the available temporally and spatially heterogenous substrata in subtly different ways; some species, for example, occupying substrata that are optimal to bryozoan growth and other species, by reaching maturity earlier, being able to inhabit more ephemeral suboptimal substrata.     

Tennessee's Novice Driver Safety Project: a program to increase parental involvement

Graduated licensing has been implemented in many U.S. states to reduce teenage driver crash involvement. The goal is to introduce teenagers gradually to driving before allowing full, unrestricted licensure. Tennessee, one of the states that introduced graduated licensing, implemented a program to influence both driving by teenagers during the learner stage and restrictions imposed by parents after licensure. In addition to a standard welcome letter, booklets and reminder cards were mailed to parents of teenagers who had just obtained their learner's permits. The booklets and cards were designed to assist parents in becoming more actively involved in their children's driving experiences. The effects of three different approaches (welcome letter only, letter plus booklet, and letter plus booklet plus reminder cards) on parental involvement, teenage crashes, and teenage citations were assessed based on telephone interviews with parents. Although the parents said the booklets and reminder cards were helpful and should continue to be sent to other parents, there were no discernible effects on teenage practice driving and reported parental involvement during the learner stage. Nor was there any measurable influence on restrictions imposed by parents after licensure. It is unknown whether the standard welcome letter affected parental involvement, but overall supervised driving exceeded the state requirements by a substantial margin.     

Adjusting irrigation abstraction to minimise the impact on stream flow in the East of Scotland

Abstractions of surface and groundwater for irrigation in Scotland are currently subject to control in only two small catchments. Under the terms of the EU Water Framework Directive, it will be necessary to introduce new legislation to control abstractions elsewhere. To help in the development of appropriate policy for Scotland a study has been carried out to examine the significance of irrigation and the effectiveness of different types of control strategies in terms of the economics of potato cropping and stream hydrology in Scotland. This paper presents the findings of the hydrological study and highlights some of the spatial and temporal issues that need to be considered in the selection of control mechanisms, if they are to be successful in achieving objectives for environmental improvement.The study was focussed on two catchments in the east of Scotland, the Tyne and West Peffer. The effectiveness of several different abstraction control strategies was examined to see how stream flows in the catchment would be modified by their implementation. The results of the study demonstrated that the West Peffer catchment in particular is significantly affected by irrigation abstractions. Control mechanisms based on allowable monthly abstraction volumes and flow-based abstraction bans would be of considerable help in restoring stream flows to their natural levels, but would modify the hydrological regime in slightly different ways. A spatial analysis of stream flows demonstrated that implementation of controls based on a single monitoring point may be ineffective at maintaining acceptable levels of flow throughout the catchment and that this may require a tighter control at the monitoring point.     

Chemical extraction methods to assess bioavailable arsenic in soil and solid media

Soil ingestion by children is an important pathway in assessing public health risks associated with exposure to arsenic-contaminated soils. Soil chemical methods are available to extract various pools of soil arsenic, but their ability to measure bioavailable arsenic from soil ingestion is unknown. Arsenic extracted by five commonly used soil extractants was compared with bioavailable arsenic measured in vivo by immature swine (Sus scrofa) dosing trials. Fifteen contaminated soils that contained 233 to 17 500 mg kg(-1) arsenic were studied. Soil extractants were selected to dissolve surficially adsorbed and/or readily soluble arsenic (water, 1 M sodium acetate, 0.1 M Na2HPO4/0.1 M NaH2PO4) and arsenic in Fe and Mn oxide minerals (hydroxylamine hydrochloride, ammonium oxalate). The mean percent of total arsenic extracted was: ammonium oxalate (53.6%) > or = hydroxylamine hydrochloride (51.7%) > phosphate (10.5%), acetate (7.16%) > water (0.15%). The strongest relationship between arsenic determined by soil chemical extraction and in vivo bioavailable arsenic was found for hydroxylamine hydrochloride extractant (r = 0.88, significant at the 0.01 probability level). Comparison of the amount of arsenic extracted by soil methods with bioavailable arsenic showed the following trend: ammonium oxalate, hydroxylamine hydrochloride > in vivo > phosphate, acetate > water. The amount of arsenic dissolved in the stomach (potentially bioavailable) is between surficially adsorbed (extracted by phosphate or acetate) and surficially adsorbed + nonsurficial forms in Fe and Mn oxides (extracted by hydroxylamine hydrochloride or ammonium oxalate). Soil extraction methods that dissolve some of the amorphous Fe, such as hydroxylamine hydrochloride, can be designed to provide closer estimates of bioavailable arsenic.