Comparative mammalian cell cytotoxicity of wastewater with elevated bromide and iodide after chlorination, chloramination, or ozonation

Recycling wastewater is becoming more common as communities around the world try to better control their water resources against an increased frequency of either prolonged droughts or intense flooding. For communities in coastal areas, wastewaters may contain elevated levels of bromide(Br~-) and iodide(I~-) from seawater intrusion or high mineral content of source waters. Disinfection of such wastewater is mandatory to prevent the spread of pathogens, however little is known about the toxicity of wastewater after disinfection in the presence of Br~-and I~-. In this study we compared the induction of chronic cytotoxicity in mammalian cells in samples of municipal secondary wastewater effluent amended with elevated levels of Br~-/I~-after disinfection by chlorine, chloramines or ozone to identify which disinfection process generated wastewater with the lowest level of adverse biological response. Chlorination increased mammalian cell cytotoxicity by 5times as compared to non-disinfected controls. Chloramination produced disinfected wastewater that expressed 6.3 times more cytotoxicity than the non-disinfected controls and was 1.3 times more cytotoxic than the chlorinated samples. Ozonation produced wastewater with cytotoxicity comparable to the non-disinfected controls and was at least 4times less cytotoxic than the chlorine disinfected wastewaters. These results indicate that compared to chlorination and chloramination, ozonation of wastewater with high Br~-/Ilevels yielded the lowest mammalian cell cytotoxicity, suggesting its potential as a more favorable method to disinfect wastewater with minimizing the biological toxicity in mind.     

SIMULATION AND DECISIONMAKING: THE PLATTE RIVER BASIN IN NEBRASKA1

Substantial conflict exists over water management and allocation in the Platte River Basin of Nebraska. An interdisciplinary computer simulation model, representing the water quantity, water quality, environmental, and economic dimensions of the conflict, was developed in order to analyze the tradeoffs among allocation scenarios. Most importantly, decisionmakers and interest groups were involved in model development. Simulation results for a base case and two scenarios are presented. One scenario favors protection of instream flow for wildlife; the other favors water diversions for agriculture. Impacts of the instream flow scenario, as measured by the amount of land irrigated, groundwater levels, the amount of wildlife habitat for cranes and catfish, and net agricultural benefits did not differ greatly from those of the base case. However, impacts of the diversion scenario were substantial. On the negative side, instream flows and wildlife habitat declined an average of 39 percent; while, on the positive side, groundwater levels and net agricultural benefits each increased 6 percent. The modeling process was successful insofar as it promoted an understanding among the highly diverse interest groups of the systems nature of the Basin. One agreement on a water diversion schedule among three of the parties has been reached, partly as a result of this process. More comprehensive compromises have not yet been forged. Our experience, however, indicates that modeling success at the policymaking level depends more on the extent to which the policymakers understand the model than it does on model sophistication.     

EFFECTS OF NO-FLOW RIVER CONDITIONS ON THE PLATTE RIVER WELL FIELD1

ABSTRACT: Effects of no-flow river conditions on the quantity and quality of water in the Platte River well field of the City of Grand Island, Nebraska, were examined utilizing a finite-difference computer simulation model specifically developed for this well field. Results suggest that the effects of these no-flow periods on water quality may be most important. In particular, the no-flow periods eliminate the hydraulic barrier between the well field and an area north of the River that is contaminated with nitrate (concentrations in the 20 to 40 mg/1 NO₃-N range). They also change the direction and velocity of movement of the contaminated ground water. Simulation results indicate that contaminated ground water moves toward the well field with a velocity of 0.42 ft/d after 30 days of no-flow and 1.43 ft/d after 180 days of no-flow. Limiting no-flow conditions to 10 consecutive days would protect the well field.     

Injuries as a Result of California Earthquakes in the Past Decade

The devastating effects of earthquakes have been demonstrated repeatedly in the past decade, through moderate and major earthquakes such as the October 1987 Whittier Narrows earthquake (5.9 on the Richter scale), the October 1989 Loma Prieta earthquake (7.1) and the January 1994 Northridge earthquake (6.7). While 'official' tallies of injuries and deaths are reported for each event, the numbers vary from report to report. For Northridge, the number of injuries vary between 8,000 and 12,000; the number of deaths from 33 to 73 (Peek-Asa et al., 1997; Durkin, 1996).While official estimates are commonly reported following disasters, the study of actual numbers, types and causes of casualties has not developed. In this paper, we identify the numbers and risk factors for injuries within community-based samples across three earthquakes in urban California. We first report the numbers and types of injuries in each earthquake and then identify risk factors specifically associated with the Northridge earthquake     

Opportunities and challenges for mangrove carbon sequestration in the Mekong River Delta in Vietnam

Increasing value is attributed to mangroves due to their considerable capacity to sequester carbon, known as ‘blue carbon’. Assessments of opportunities and challenges associated with estimating the significance of carbon sequestered by mangroves need to consider a range of disciplinary perspectives, including the bio-physical science mangroves, social and economic issues of land use, local and international law, and the role of public and private finance. We undertook an interdisciplinary review based on available literature and fieldwork focused on parts of the Mekong River Delta (MRD). Preliminary estimates indicate mangrove biomass may be 70–150 t ha^?1, but considerably larger storage of carbon occurs in sediments beneath mangroves. These natural stores of carbon are compromised when mangroves are removed to accommodate anthropogenic activities. Mangroves are an important resource in the MRD that supplies multiple goods and services, and conservation or re-establishment of mangroves provides many benefits. International law and within-country environmental frameworks offer increasing scope to recognize the role that mangrove forests play through carbon sequestration, in order that these might lead to funding opportunities, both in public and private sectors. Such schemes need to have positive rather than negative impacts on the livelihoods of the many people living within and adjacent to these wetlands. Nevertheless, many challenges remain and it will require further targeted and coordinated scientific research, development of economic and social incentives to protect and restore mangroves, supportive law and policy mechanisms at global and national levels, and establishment of long-term financing for such endeavours.     

Accumulation of Cd,Cu and Zn in shoots of maize (<Emphasis Type="Italic">Zea mays</Emphasis> L.) exposed to 0.8 or 20 nM Cd during vegetative growth and the relation with xylem sap composition

This work focuses on the exposure of maize plants to nanomolar concentrations of Cd, which is relevant for agricultural soils cropped with food and feed plants. Maize plants were cultivated in nutrient solution at 0.8 or 20 nM Cd during the vegetative growth stages. No significant hormesis or toxic effects of Cd were observed on maize growth, but a decrease in the allocation of Cd to shoots between the 0.8 and 20 nM Cd exposures revealed that the plants already responded to these low concentrations of Cd according to a shoot Cd excluder strategy. The Cd, Cu and Zn concentrations in shoots decreased with time as the result of an early decrease in the root/shoot ratio and of a decrease in the coefficient of allocation to aboveground for Zn and Cd at 20 nM. As a consequence, shoots of young plants were richer in micronutrients Cu and Zn but also in toxic Cd. The rate of delivery of Cd, Cu and Zn from xylem sap was successfully used to predict the time course of concentrations of Cd, Cu and Zn in the shoot. However, it overestimated the actual concentrations of Cd in the shoot, presumably because the reallocation of this trace element from shoots back to roots was not taken into account.     

Glutathione as a matrix for the synthesis of CdS nanocrystallites

GSH-capped CdS nanocrystallites were synthesized by reacting Cd(II)-GSH with aqueous sodium sulfide using specific initial sulfide/Cd(II) ratios. Spectroscopic analyses of fractions obtained from a size exclusion column showed varying absorption spectra indicating a significant dispersion in size-distribution of nanocrystallites at lower sulfide/Cd(II) ratios. However, size distribution of the nanocrystallites was narrower at initial sulfide/Cd(II) ratios that exceeded 1.0. An ethanol precipitation procedure was used to remove free Cd(II)-GSH complexes and selectively isolate GSH-capped nanocrystallites in a very narrow size range. Size exclusion chromatography indicated similar chemical compositions and overlapping spectral profiles of ethanol-precipitated samples suggesting apparent uniformity in both the size and the cap content. All of the GSH-capped CdS nanocrystallites with varying cap contents degraded p-nitrophenol upon irradiation at 366 nm. However, photocatalytic degradation of p-nitrophenol was significantly higher in samples with higher sulfide/Cd ratio and less capping material. The addition of H2O2 enhanced levels of photo-oxidation of p-nitrophenol.     

Co-development of an integrated assessment framework to evaluate the effectiveness and impact of selected nature-based water treatment technologies in Sri Lanka,The Philippines,and Vietnam

Water quality is a critical challenge in Asia in the context of growing industrialization, urbanization, and climate change. Nature-based solutions (NbS) could play an important role in reducing urban water pollution, while generating multiple co-benefits that could make cities more liveable and resilient. In this regard, a number of pilot and demonstration projects have been set up to explore their potential across cities in Asia. Their effectiveness and impacts, however, have not been adequately documented, thus how they can be sustained, replicated and up-scaled remain poorly understood. This study aims to contribute to addressing this challenge by co-developing an integrated assessment framework and employing it to understand how existing evaluations of NbS in the region can be improved. It focuses specifically on a set of nature-based solutions that have been employed for water treatment across six cities in Southeast Asia (two in each Sri Lanka, the Philippines, and Vietnam), namely, floating wetlands, constructed wetlands and maturation ponds. The study also suggests specific methodologies for capturing a set of core indicators considered relevant for assessing the effectiveness and capturing the multi-faceted impacts of the examined NbS.     

Household solid waste generation and characteristic in a Mekong Delta city,Vietnam

This study was undertaken to evaluate the quantity and composition of household solid waste to identify opportunities for waste recycling in Can Tho city, the capital city of the Mekong Delta region in southern Vietnam. Two-stage survey of 100 households was conducted for dry season and rainy season in 2009. Household solid waste was collected from each household and classified into 10 physical categories and 83 subcategories. The average household solid waste generation rate was 285.28 g per capita per day. The compostable and recyclable shares respectively accounted for 80.02% and 11.73%. The authors also analyzed the relations between some socioeconomic factors and household solid waste generation rates by physical categories and subcategories. The household solid waste generation rate per capita per day was positively correlated with the population density and urbanization level, although it was negatively correlated with the household size. The authors also developed mathematical models of correlations between the waste generation rates of main physical categories and relevant factors, such as household size and household income. The models were proposed by linear models with three variables to predict household solid waste generation of total waste, food waste, and plastic waste. It was shown that these correlations were weak and a relationship among variables existed. Comparisons of waste generation by physical compositions associated with different factors, such as seasonal and daily variation were conducted. Results presented that the significant average differences were found by the different seasons and by the different days in a week; although these correlations were weak. The greenhouse gas baseline emission was also calculated as 292.25 g (CO₂ eq.) per capita per day from biodegradable components.     

Peracetic Acid Sanitation on Arugula Microgreens Contaminated with Surface-Attached and Internalized Tulane Virus and Rotavirus

Food and Environmental Virology - Hydroponic production of vegetables is becoming more common, especially in regions with unfavorable climate for year-round crop production. However, if viruses are...