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41.
The determination of alkanolamines and glycols in groundwater and subsurface environments is essential for environmental assessment, remediation and monitoring for selected industrial sites. Monoethanolamine (MEA), ammonium, sodium, magnesium and calcium detection was performed using cation exchange chromatography (IC) with suppressed conductivity detection. Acetate, chloride, nitrite, nitrate, phosphate, sulfate and oxalate were monitored employing anion exchange chromatography with suppressed conductivity. Detection of ethylene glycol (MEG) and triethylene glycol (TEG) and ethanol was carried out using ion exclusion chromatography with pulsed amperometric detection. Effective determination of MEA, MEG and TEG in complex groundwater matrices without compound transformation offered improved monitoring capabilities. This study presents robust analytical tools for MEA, MEG and TEG determination in biodegradation studies. Using ion chromatography offered significant advantages for the analyses of groundwater samples and laboratory bioreactor monitoring. 相似文献
42.
Henne Paul D. Bigalke Moritz Büntgen Ulf Colombaroli Daniele Conedera Marco Feller Urs Frank David Fuhrer Jürg Grosjean Martin Heiri Oliver Luterbacher Jürg Mestrot Adrien Rigling Andreas Rössler Ole Rohr Christian Rutishauser This Schwikowski Margit Stampfli Andreas Szidat Sönke Theurillat Jean-Paul Weingartner Rolf Wilcke Wolfgang Tinner Willy 《Regional Environmental Change》2018,18(1):205-221
Regional Environmental Change - Planning for the future requires a detailed understanding of how climate change affects a wide range of systems at spatial scales that are relevant to humans.... 相似文献
43.
44.
Numerical dating of the Eckfeld maar fossil site, Eifel, Germany: a calibration mark for the Eocene time scale 总被引:1,自引:0,他引:1
Sediments of the Eckfeld maar (Eifel, Germany) bear a well-preserved Eocene fauna and flora. Biostratigraphically, Eckfeld
corresponds to the Middle Eocene mammal reference level MP (Mammals Paleogene) 13 of the ELMA (European Land Mammal Age) Geiseltalian.
In the maar crater, basalt fragments were drilled, representing explosion crater eruption products. By 40Ar/39Ar dating of the basalt, for the first time a direct numerical calibration mark for an Eocene European mammal locality has
been established. The Eckfeld basalt inverse isochron date of 44.3±0.4 Ma suggests an age for the Geiseltalian/Robiacian boundary
at 44 Ma and, together with the 1995 time scale of Berggren et al., a time span ranging from 49 to 44 Ma for the Geiseltalian
and from 44 to 37 Ma for the Robiacian, respectively. Additional 40Ar/39Ar dating on a genetically related basalt occurrence close to the maar confirms a period of volcanism of ca. 0.6 m.y. in the
Eckfeld area, matching the oldest Eocene volcanic activity of the Hocheifel volcanic field.
Received: 27 December 1999 / Accepted in revised form: 6 April 2000 相似文献
45.
Julie K. Jensen Peter E. Holm Morten B. Larsen Ole K. Borggaard 《Environmental pollution (Barking, Essex : 1987)》2009,157(3):931-937
Growth performance and heavy metal uptake by willow (Salix viminalis) from strongly and moderately polluted calcareous soils were investigated in field and growth chamber trials to assess the suitability of willow for phytoremediation. Field uptakes were 2-10 times higher than growth chamber uptakes. Despite high concentrations of cadmium (≥80 mg/kg) and zinc (≥3000 mg/kg) in leaves of willow grown on strongly polluted soil with up to 18 mg Cd/kg, 1400 mg Cu/kg, 500 mg Pb/kg and 3300 mg Zn/kg, it is unsuited on strongly polluted soils because of poor growth. However, willow proved promising on moderately polluted soils (2.5 mg Cd/kg and 400 mg Zn/kg), where it extracted 0.13% of total Cd and 0.29% of the total Zn per year probably representing the most mobile fraction. Cu and Pb are strongly fixed in calcareous soils. 相似文献
46.
Direct male-male competition can facilitate invasion of new colour types in Lake Victoria cichlids 总被引:2,自引:2,他引:0
Peter D. Dijkstra Ole Seehausen Ton G. G. Groothuis 《Behavioral ecology and sociobiology》2005,58(2):136-143
The possibility that disruptive sexual selection alone can cause sympatric speciation is currently a subject of much debate. The initial difficulty for new and rare ornament phenotypes to invade a population, and the stabilisation of the resulting polymorphism in trait and preference make this hypothesis problematic. Recent theoretical work indicates that the invasion is facilitated if males with the new phenotype have an initial advantage in male-male competition. We studied a pair of sympatric incipient species of cichlids from Lake Victoria, in which the red (Pundamilia nyererei) and blue males (P. pundamilia) vigorously defend territories. Other studies suggested that red phenotypes may have repeatedly invaded blue populations in independent episodes of speciation. We hypothesised that red coloration confers an advantage in male-male competition, assisting red phenotypes to invade. To test this hypothesis, we staged contests between red and blue males from a population where the phenotypes are interbreeding morphs or incipient species. We staged contests under both white and green light condition. Green light effectively masks the difference between red and blue coloration. Red males dominated blue males under white light, but their competitive advantage was significantly diminished under green light. Contests were shorter when colour differences were visible. Experience of blue males with red males did not affect the outcome of a contest. The advantage of red over blue in combats may assist the red phenotype to invade blue populations. The apparently stable co-existence of red and blue incipient species in many populations of Lake Victoria cichlids is discussed.Communicated by C. St. Mary 相似文献
47.
Kirstin?Anderson?HansenEmail authorView authors OrcID profile Alyssa?Maxwell Ursula?Siebert Ole?N?sbye?Larsen Magnus?Wahlberg 《Die Naturwissenschaften》2017,104(5-6):45
In-air hearing in birds has been thoroughly investigated. Sound provides birds with auditory information for species and individual recognition from their complex vocalizations, as well as cues while foraging and for avoiding predators. Some 10% of existing species of birds obtain their food under the water surface. Whether some of these birds make use of acoustic cues while underwater is unknown. An interesting species in this respect is the great cormorant (Phalacrocorax carbo), being one of the most effective marine predators and relying on the aquatic environment for food year round. Here, its underwater hearing abilities were investigated using psychophysics, where the bird learned to detect the presence or absence of a tone while submerged. The greatest sensitivity was found at 2 kHz, with an underwater hearing threshold of 71 dB re 1 μPa rms. The great cormorant is better at hearing underwater than expected, and the hearing thresholds are comparable to seals and toothed whales in the frequency band 1–4 kHz. This opens up the possibility of cormorants and other aquatic birds having special adaptations for underwater hearing and making use of underwater acoustic cues from, e.g., conspecifics, their surroundings, as well as prey and predators. 相似文献
48.
Accidents produce external pressures on companies leading to new regulations and renegotiation of enforcement of regulations. Our perspective is institutional with a focus on the extended dialogue among regulators and the industry. The empirical focus is offshore oil and gas production, deep sea and coastal fisheries, and maritime transportation with a segment of older bulk carriers. The findings are that structural characteristics of both the industries and the regulatory regime determine the interactions between the regulated and the regulator. The paper illustrates that in industrial sectors where hazards and risks are visible and of public interest, it is easier to implement regulations through outside pressure from regulators and other stakeholders such as internationally organised unions. 相似文献
49.
Chemically chlorinated organic matter as well as natural background humic acids contain significant amounts of organically bound halogens that must be determined for assessment of environmental pollution. In this work the use of ion chromatography (IC) and inductively coupled plasma mass spectrometry (ICP-MS) is proposed for the determination of total organic Cl, Br and I concentration in humic acids extracted from various forest soil horizons after a single digestion by microwave-induced combustion (MIC). Samples were pressed as pellets and combusted using 20 bar of oxygen and ammonium nitrate solution as igniter. Analytes were absorbed in diluted alkaline solution (50 mM (NH4)2CO3) and a reflux step was applied after combustion to improve analyte recoveries (5 min, microwave power of 1400 W). The accuracy was evaluated using certified reference materials (CRM) and spiked samples. Using MIC the agreement with CRM values and spike recoveries was higher than 97% for all analytes. As an advantage over conventional procedures, using MIC it was possible to digest up to eight samples in only 25 min, obtaining a single solution suitable for all halogens determination in humic acids samples by different techniques (IC and ICP-MS). The limit of detection (3σ) for Cl, Br and I obtained by IC was 1.2, 2.5 and 4.3 μg g−1 and by ICP-MS it was 1.4, 0.03 and 0.002 μg g−1, respectively. 相似文献
50.