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151.
Previous work in this laboratory has confirmed that the bacteria Mycobacterium sp. strain RJGII.135 and Sphingomonas yanoikuyae strain B1 and the green alga Selanastrum capricornutum strain UTEX 1648 degrade benzo[a]pyrene (BaP) to various BaP intermediates. S. capricornutum was first grown with BaP for 4 days. The organic extract of this media was then introduced into separate cultures of strain RJGII.135 and strain B1; separate cultures were grown with BaP for comparison. Cultures grown with BaP and those grown with the algal/BaP extract showed similar mineralization patterns. The quantity of total metabolites formed was greater in bacterial cultures grown with the algal/BaP extract than those grown with BaP alone. For strain RJGII.135, only 27% of the original BaP remained in cultures grown with the algal/BaP extract; 59% remained in cultures grown with BaP. For strain B1, only 6% of the original BaP remained in cultures grown with the algal/BaP extract; 38% remained in cultures grown with BaP. These results indicate that strategies utilizing organisms together may be necessary in being able to degrade large, recalcitrant polycyclic aromatic hydrocarbons (PAHs) such as BaP. 相似文献
152.
We collected and analyzed 955 individual fish (six species) for sexual differences in PCB bioaccumulations from a southeastern, USA reservoir. Using 2-way ANCOVAs, we found significant differences in fillet PCB concentrations between sexes for channel catfish (Ictalurus punctatus), largemouth bass (Micropterus salmoides) and spotted bass (Micropterus punctulatus). Striped bass (Morone saxatilus), black crappie (Pomoxis nigromaculatus) and freshwater drum (Aplodinotus grunniens) did not display differences between sexes in PCB concentrations. We suspect that sexual differences may be due to biological differences in reproduction, relative motility and lipid deposition. For one species (striped bass), sexual differences in PCB concentrations were inconsistent with a study in the Hudson River suggesting that sexual differences in bioaccumulations can change across ecosystems. Two species which did show sexual differences, largemouth bass and channel catfish, are often chosen as representative species (e.g., "piscivore" and "benthivore") in contaminant monitoring in many USA states indicating human consumption and risk management decisions would be improved if an equal number of male and female fish were included in composite PCBs analysis. This could reduce variability in fish PCBs data from which consumption advisories are based. 相似文献
153.
The need for accurate carbon budgeting, climate change modelling, and sustainable resource management has lead to an increase
in the number of large area forest monitoring programs. Large area forest monitoring programs often utilize field and remotely
sensed data sources. Sampling, via field or photo plots, enables the collection of data with the desired level of categorical
detail in a timely and efficient manner. When sampling, the aim is to collect representative detailed data enabling the statistical
reporting upon the characteristics of larger areas. As a consequence, approaches for investigating how well sample data represent
larger areas (i.e., the sample neighbourhood and the population) are desired. Presented in this communication is a quantitative
approach for assessing the nature of sampled areas in relation to surrounding areas and the overall population of interest.
Classified Landsat data is converted to forest/non-forest categories to provide a consistent and uniform data set over a 130,000 km2 study region in central British Columbia, Canada. From this larger study area 322 2 × 2 km photo plots on a 20 × 20 km systematic
grid are populated with composition and configuration information for comparison to non-sampled areas. Results indicate that
typically, within the study area, the spatial pattern of forest within a photo plot is representative of the forest patterns
found within primary and secondary neighbourhoods and over the entire population of the study. These methods have implications
for understanding the nature of data used in monitoring programs worldwide. The ability to audit photo and field plot information
promotes an increased understanding of the results developed from sampling and provides tools identifying locations of possible
bias. 相似文献
154.
Wetherbee GA Gay DA Brunette RC Sweet CW 《Environmental monitoring and assessment》2007,131(1-3):49-69
The National Atmospheric Deposition Program/Mercury Deposition Network (MDN) provides long-term, quality-assured records of
mercury in wet deposition in the USA and Canada. Interpretation of spatial and temporal trends in the MDN data requires quantification
of the variability of the MDN measurements. Variability is quantified for MDN data from collocated samplers at MDN sites in
two states, one in Illinois and one in Washington. Median absolute differences in the collocated sampler data for total mercury
concentration are approximately 11% of the median mercury concentration for all valid 1999–2004 MDN data. Median absolute
differences are between 3.0% and 14% of the median MDN value for collector catch (sample volume) and between 6.0% and 15%
of the median MDN value for mercury wet deposition. The overall measurement errors are sufficiently low to resolve between
NADP/MDN measurements by ±2 ng·l−1 and ±2 μg·m−2·year−1, which are the contour intervals used to display the data on NADP isopleths maps for concentration and deposition, respectively. 相似文献
155.
Certified reference materials (CRMs) are an essential part of the quality assurance (QA) necessary for the reliable analytical measurement of nutrients in seawater. The CRMs currently available for these analyses are not matrix matched to marine samples. QUASIMEME routinely produces test materials for the nutrients in seawater and nutrients in estuarine water and low-salinity open water Laboratory Performance Studies (LPS) that are both homogeneous and stable. QUASIMEME, in conjunction with Eurofins Scientific, Denmark have produced two reference materials (RMs). The homogeneity testing and preliminary stability studies were carried out by QUASIMEME, and the results are presented in this article. Participants of the QUASIMEME LPS who demonstrated satisfactory long-term performance for the analysis of nutrients in seawater and nutrients in estuarine water and low-salinity open water were invited to take part in the certification exercise. Twenty laboratories returned data, a summary of which is also presented. The certification and long-term stability testing and additional data analysis were carried out by Eurofins Scientific, Denmark, and are outwith the scope of this article and not reported here. Eurofins Scientific, Denmark have marketed these RMs as part of their range of VKI Reference Materials (further information is available from eurofins@eurofins.dk). 相似文献
156.
Rowell FJ Sykes D Grieveson L Theaker B Sundar L Cumming RH 《Journal of environmental monitoring : JEM》2007,9(1):33-43
We describe the development and validation of a portable system comprising an air sampler coupled to an automated flow injection analysis device. The system is able to monitor airborne concentrations of subtilisin-type enzymes in the workplace atmosphere on a continuous basis. Sampling is in two stages: using a sampling head that is designed to mimic human respiration at approx. 1 m s(-1) at a sampling rate of 600 l min(-1). In the second stage, the captured particles are deposited by impaction from the air stream onto the inner surface of a cyclone that is continuously washed with a jet of buffer solution. Deposited particles are then washed into a reservoir from which samples are taken every 5-6 min and injected automatically into a continuous flow injection analysis system. Proteolytic enzyme in the sample passes through a bioreactor maintained at about 40 degrees C. This contains a cellulose solid phase matrix on which is covalently immobilised Texas Red-labelled gelatin as substrate. The passing enzyme partially digests the substrate releasing fluorophore that is detected down stream in a flow cell coupled to a fluorimeter. The system is calibrated using enzyme standards and the intensity of the resulting peaks from the ex-air samples is converted to airborne concentrations using a mathematical model programmed into a PC. The system has a limit of detection of 4.8 ng m(-3) and a dynamic range of 5-60 ng m(-3). The within assay precision (RSD) is 6.3-9.6% over this range. The within batch precision is 20.3% at 20 ng m(-3) and the corresponding between batch value is 19.5%. The system has been run for periods up to 8 h in the laboratory and for up to 4 h at a factory site and the values obtained compared with time-averaged values obtained from a conventional Galley sampler and in-house analysis when reasonable agreement of the results was observed. The stability of the system over 21 days of continuous use with standards injected periodically was studied. Linearity was observed for all the standard plots throughout. At the end of 21 days, after a total exposure equivalent to 2395 ng ml(-1) of Savinase, the signal due to the 5.0 ng ml(-1) standard was still easily detectable. 相似文献
157.
The Israeli–Hezbollah conflict in the summer of 2006, although brief, had a lasting impact on the region and prompted an intense humanitarian response. The conflict raised challenging questions for the United Nations (UN) about how to assist a middle‐income yet extremely vulnerable population in a context where global and local relations are highly politicised. This paper focuses on two key questions that emerged from the humanitarian response. First, how can humanitarian agencies, and particularly the UN, improve the protection of civilians, and was what they did in Lebanon enough? Second, how can humanitarian agencies create partnerships with local actors and still remain true to core humanitarian principles when local actors are fiercely divided along confessional lines and influenced by external actors, and when some, such as Hezbollah, are parties to the conflict? This paper argues that despite the importance of protection and partnerships to the humanitarian response, their role in the UN emergency response still falls short. 相似文献
158.
Essential and non-essential element concentrations in two sleeper shark species collected in arctic waters 总被引:1,自引:0,他引:1
McMeans BC Borgå K Bechtol WR Higginbotham D Fisk AT 《Environmental pollution (Barking, Essex : 1987)》2007,148(1):281-290
A number of elements/metals have increased in arctic biota and are of concern due to their potential toxicity. Most studies on elements in the Arctic have focused on marine mammals and seabirds, but concentrations in the Greenland shark (Somniosus microcephalus) and Pacific sleeper shark (Somniosus pacificus), the only two shark species known to regularly inhabit arctic waters, have never been reported. To address this data gap, concentrations and patterns of 25 elements were analyzed in liver of Greenland sharks collected about Cumberland Sound (n=24) and Pacific sleeper sharks collected about Prince William Sound (n=14). Several non-essential elements differed between species/locations, which could suggest geographical exposure differences or ecological (e.g., diet) differences between the species. Certain essential elements also differed between the two sleeper sharks, which may indicate different physiological requirements between these closely related shark species, although information on such relationships are lacking for sharks and fish. 相似文献
159.
Houghton DC 《Environmental monitoring and assessment》2007,135(1-3):253-264
Over 300,000 caddisfly specimens representing 249 species were collected from nearly 250 sites throughout Minnesota during
2000 and 2001 to determine the effects of human disturbance on the composition of caddisfly trophic functional groups at the
landscape level. Canonical correspondence analysis determined that stream width was the most important variable influencing
functional group composition in regions of the state with relatively low disturbance, and that differences in the caddisfly
fauna between sizes of streams generally followed trends predicted by the river continuum concept. In regions of the state
with moderate disturbance, both stream width and the percentage of disturbed habitat upstream of a site were important variables
influencing functional group composition. In highly disturbed regions, no variables corresponded to changes in the composition
of caddisfly functional groups. Instead, ecosystems were homogeneous: fine-particle filtering collectors dominated in all
sizes of streams. The observed aquatic ecosystem homogenization is attributed mostly to input of fine-particle organic and
inorganic sediment from extensive agriculture. 相似文献
160.
We compared the effects of natural and anthropogenic watershed disturbances on methyl mercury (MeHg) concentration in bulk
zooplankton from boreal Shield lakes. MeHg in zooplankton was monitored for three years in nine lakes impacted by deforestation,
in nine lakes impacted by wildfire, and in twenty lakes with undisturbed catchments. Lakes were sampled during spring, mid-
and late summer. MeHg in zooplankton showed a seasonal trend: concentrations were the lowest in spring, then peaked in mid-summer
and decreased in late summer. Over the three study years, MeHg concentrations observed in mid-summer in zooplankton from forest
harvested lakes were significantly higher than in reference and fire-impacted lakes, whereas differences between these two
groups of lakes were not significant. The pattern of distribution of MeHg in zooplankton during the different seasons paralleled
that of dissolved organic carbon (DOC), which is known as a vector of Hg from watershed soils to lake water. Besides DOC,
MeHg in zooplankton also showed a positive significant correlation with epilimnetic temperature and sulfate concentrations.
An inter-annual decreasing trend in MeHg was observed in zooplankton from reference and fire-impacted lakes. In forest harvested
lakes, however, MeHg concentrations remained higher and nearly constant over three years following the impact. Overall these
results indicate that the MeHg pulse observed in zooplankton following deforestation by harvesting is relatively long-lived,
and may have repercussions to the accumulation of MeHg along the food chain. Therefore, potential effects of deforestation
on the Hg contamination of fish should be taken into account in forest management practices. 相似文献