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271.
Streams of the Pampasic plain in Southeastern South America are ecosystems affected by both water pollution and habitat alteration mainly due to agricultural activity. Water quality is influenced by the quality of habitats and both depend on land use and watershed morphology. The objective of this study was to determine the relationship between the variables of four factors: (1) the morphology of the watershed, (2) land use in the watershed, (3) river habitat, and (4) water quality of wadeable streams in Uruguay, as well as to determine the most representative variables to quantify such factors. We studied 28 watersheds grouped into three ecoregions and four principal activities, which generated seven zones with three to five streams each. Correlations between the variables of each factor allowed reducing the total number of variables from 57 to 32 to perform principal component analyses (PCA) by factor, reducing the number of variables to 18 for a general PCA. The first component was associated with water quality and elevation. The second was associated with the stream and watershed size, the third with habitat quality, and the fourth to the use of neighboring soils and objects in the channel. Our results indicate that agricultural intensity and elevation are the main factors associated with the habitat and water quality of these lowland streams. These factors must be especially considered in the development of water quality monitoring programs.  相似文献   
272.
The soils of the Brazilian Amazon exhibit large geochemical diversity reflecting the different soil formation processes in an area covering 49% of the Brazilian territory. Soil contamination by heavy metals is one of the threats to the sustainability of this Biome but establishing quality reference values (QRVs) for the region is a challenging owing to the immense territorial area of the Amazon. This study aimed to determine the natural background of heavy metals in soils from the southwestern Brazilian Amazon in order to propose QRVs for Ba, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Sb, and Zn for alluvial sedimentary soils. One hundred and twenty-eight soil samples were collected at a depth of 0.0–0.2 m in sites with minimal anthropogenic interference. Soil sample digestion was based on the EPA 3051A method and metal concentrations were determined by ICP-OES. QRVs calculated for the southwestern Brazilian Amazon are among the lowest recorded in Brazil (mg kg?1): Ba (16.5), Cd (0.1), Cr (6.9), Cu (2.8), Fe (15.4), Mn (13.4), Ni (1.7), Pb (4.4), Sb (0.9), and Zn (5.7). The low metal concentration is likely a result of the sedimentary origin of the soils. The results of this study can serve as a basis for defining public policies to investigate the environmental impacts resulting from changes in land use in areas of the Brazilian Amazon.  相似文献   
273.
Water and sediment quality was monitored at four sites of Óbidos coastal lagoon (Portugal) in February, May, July and October 2006, covering different hydrological conditions. Concentrations of nutrients and metals increased in autumn/winter, particularly in an inner branch with symptoms of eutrophication that receives a small tributary contaminated by agro-industrial activities. Moreover, concentrations of PO4 3?, Si(OH)4 and Mn (diffusive gradients of thin films (DGT)-measured) varied inversely with salinity. Additionally, that branch was monitored over 26-h in July 2006 to assess variations of water quality parameters, nutrients and metals on short timescale. During the night, O2 in water reached a minimum of 40% saturation followed by a pronounced increase of DGT-measured metals and nutrients in water column: Fe and Mn (ten times); Cr, Co, PO4 3? and Si(OH)4 (six times). Enhancements were also registered for metal/Al ratios in suspended particulate matter: Mn, Cr and Cd (four to six times); Fe, Ni and Co (1.5 times). The metal distribution coefficients calculated along the 26-h survey showed a maximum at daylight suggesting a preferential association of metals with suspended particles. Data recorded under different hydrological conditions and over the 26-h survey allowed to address the influence of external and internal sources on water quality. The results of this study highlight the importance of day/night cycles on the availability of nutrients and metals in eutrophic environments.  相似文献   
274.
The quality of the water in a uranium-ore-mining area located in Caldas (Minas Gerais State, Brazil) and in a reservoir (Antas reservoir) that receives the neutralized acid solution leaching from the waste heaps generated by uranium mining was investigated. The samples were collected during four periods (October 2008, January, April and July 2009) from six sampling stations. Physical and chemical analyses were performed on the water samples, and the data obtained were compared with those of the Brazilian Environmental Standards and WHO standard. The water samples obtained from waste rock piles showed high uranium concentrations (5.62 mg L?1), high manganese values (75 mg L?1) and low average pH values (3.4). The evaluation of the water quality at the point considered the limit between the Ore Treatment Unit of the Brazilian Nuclear Industries and the environment (Consulta Creek) indicated contamination by fluoride, manganese, uranium and zinc. The Antas reservoir showed seasonal variations in water quality, with mean concentrations for fluoride (0.50 mg L?1), sulfate (16 mg L?1) and hardness (20 mg L?1) which were low in January, evidencing the effect of rainwater flowing into the system. The concentrations for fluoride, sulfate and manganese were close or above to the limits established by current legislation at the point where the treated mining effluent was discharged and downstream from this point. This study demonstrated that the effluent discharged by the UTM affected the quality of the water in the Antas reservoir, and thus the treatments currently used for effluent need to be reviewed.  相似文献   
275.
The promotion of good indoor air quality in schools is of particular public concern for two main reasons: (1) school-age children spend at least 30% of their time inside classrooms and (2) indoor air quality in urban areas is substantially influenced by the outdoor pollutants, exposing tenants to potentially toxic substances. Two schools in Curitiba, Brazil, were selected to characterize the gaseous compounds indoor and outdoor of the classrooms. The concentrations of benzene, toluene, ethylbenzene, and the isomers xylenes (BTEX); NO2; SO2; O3; acetic acid (HAc); and formic acid (HFor) were assessed using passive diffusion tubes. BTEX were analyzed by gas chromatography–ion trap mass spectrometry and other collected gasses by ion chromatography. The concentration of NO2 varied between 9.5 and 23?µg m?3, whereas SO2 showed an interval from 0.1 to 4.8?µg m?3. Within the schools, BTEX concentrations were predominant. Formic and acetic acids inside the classrooms revealed intermediate concentrations of 1.5?µg m?3 and 1.2?µg m?3, respectively.  相似文献   
276.
This article develops a decision-making framework for environmental management that integrates technical, economic, political and legal, and ethical decision levels. It attempts to show how these decision levels can be ordained, integrated and interconnected and postulates a hierarchic concentric sphere system that proposes an environmental management model for long-term solutions. This model can be used as a check list for environmental management decision-making and also as a guide for environmental conflict resolution where environmental problems necessitate several levels of decision making. It integrates various environmental ethical positions and evaluates political decisions into a comprehensive, broadly applicable multidisciplinary approach. The objective of this decision-making model is to interconnect into a simplified sequence different levels of environmental management processes in order to account for sustainability, efficacy, efficiency and the acceptability of environmental management processes in the long term. This is done by observing when an environmental problem needs to be solved within a certain sphere of solutions and when it requires wider frameworks, how these can be established and how this process proves that solidarity is the widest and most reasonable sphere.  相似文献   
277.
Faecal coliform (FC) levels in surface water and clams (Ruditapes decussatus) and variations in environmental parameters were studied in two bivalve harvesting areas in the Alvor lagoon (southern Portugal). Land use and cover characteristics in adjacent subwatersheds were also analysed to assess their contributions as sources of faecal contamination. High FC levels in clams from the harvesting area in the most urbanized subwatershed (impervious surface coverage ≈ 10.5%) were positively associated with rainfall and with the cooler periods of the year. FC levels in clams from the least urbanized subwatershed were generally very low and did not present any detectable seasonal trend. From these results, it was concluded that the periodic deterioration of the microbiological quality of clams derives from the cumulative impact of the reservoir of faecal contamination created in urbanized areas, entering into the lagoon during storm water runoff.  相似文献   
278.
Birds of prey, owls and falcons are widely used as sentinel species in raptor biomonitoring programmes. A major current challenge is to facilitate large-scale biomonitoring by coordinating contaminant monitoring activities and by building capacity across countries. This requires sharing, dissemination and adoption of best practices addressed by the Networking Programme Research and Monitoring for and with Raptors in Europe (EURAPMON) and now being advanced by the ongoing international COST Action European Raptor Biomonitoring Facility. The present perspective introduces a schematic sampling protocol for contaminant monitoring in raptors. We provide guidance on sample collection with a view to increasing sampling capacity across countries, ensuring appropriate quality of samples and facilitating harmonization of procedures to maximize the reliability, comparability and interoperability of data. The here presented protocol can be used by professionals and volunteers as a standard guide to ensure harmonised sampling methods for contaminant monitoring in raptors.Electronic supplementary materialThe online version of this article (10.1007/s13280-020-01341-9) contains supplementary material, which is available to authorized users.  相似文献   
279.
Environmental Science and Pollution Research - This study aimed to use bioassays (single and multispecies) with organisms from different trophic levels to assess soil quality in reclaimed coal...  相似文献   
280.
Abstract

Objective: Systems that can warn the driver of a possible collision with a vulnerable road user (VRU) have significant safety benefits. However, incorrect warning times can have adverse effects on the driver. If the warning is too late, drivers might not be able to react; if the warning is too early, drivers can become annoyed and might turn off the system. Currently, there are no methods to determine the right timing for a warning to achieve high effectiveness and acceptance by the driver. This study aims to validate a driver model as the basis for selecting appropriate warning times. The timing of the forward collision warnings (FCWs) selected for the current study was based on the comfort boundary (CB) model developed during a previous project, which describes the moment a driver would brake. Drivers’ acceptance toward these warnings was analyzed. The present study was conducted as part of the European research project PROSPECT (“Proactive Safety for Pedestrians and Cyclists”).

Methods: Two warnings were selected: One inside the CB and one outside the CB. The scenario tested was a cyclist crossing scenario with time to arrival (TTA) of 4?s (it takes the cyclist 4?s to reach the intersection). The timing of the warning inside the CB was at a time to collision (TTC) of 2.6?s (asymptotic value of the model at TTA = 4?s) and the warning outside the CB was at TTC = 1.7?s (below the lower 95% value at TTA = 4?s). Thirty-one participants took part in the test track study (between-subjects design where warning time was the independent variable). Participants were informed that they could brake any moment after the warning was issued. After the experiment, participants completed an acceptance survey.

Results: Participants reacted faster to the warning outside the CB compared to the warning inside the CB. This confirms that the CB model represents the criticality felt by the driver. Participants also rated the warning inside the CB as more disturbing, and they had a higher acceptance of the system with the warning outside the CB. The above results confirm the possibility of developing wellsaccepted warnings based on driver models.

Conclusions: Similar to other studies’ results, drivers prefer warning times that compare with their driving behavior. It is important to consider that the study tested only one scenario. In addition, in this study, participants were aware of the appearance of the cyclist and the warning. A further investigation should be conducted to determine the acceptance of distracted drivers.  相似文献   
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