IDENTIFICATION OF DISSOLVED-CONSTITUENT SOURCES IN MINE-SITE GROUND WATER USING BATCH MIXING1

ABSTRACT: Batch-mixing experiments were used to help identify lithologic and mineralogic sources of increased concentrations of dissolved solids in water affected by surface coal mining in northwestern Colorado. Ten overburden core samples were analyzed for mineral composition and mixed with distilled water for 90 days until mineral-water equilibrium was reached. Between one day and 90 days after initial contact, specific conductance in the sample mixtures had a median increase of 306 percent. Dissolved-solids concentrations ranged from 200 to 8,700 mg/L in water samples extracted from the mixtures after 90 days. Mass. balance simulations were conducted using the geochemical models BALANCE and WATEQF to quantify mineral-water interactions occurring in five selected sample mixtures and in water collected from a spring at a reclaimed mine site. The spring water is affected by mineral-water interactions occurring in all of the lithologic units comprising the overburden. Results of the simulations indicate that oxidation of pyrite, dissolution of dolomite, gypsum, and epsomite, and cation-exchange reactions are the primary mineral-water interactions occurring in the overburden. Three lithologic units in the overburden (a coal, a sandstone, and a shale) probably contribute most of the dissolved solids to the spring water. Water sample extracts from mixtures using core from these three units accounted for 85 percent of the total dissolved solids in the 10 sample extracts. Other lithologic units in the overburden probably contribute smaller quantities of dissolved solids to the spring water.     

REMOVAL OF FLOODWATER SEDIMENTS BY A CLEARCUT TUPELO-CYPRESS WETLAND1

ABSTRACT: A palustrine water tupelo (Nyssa aquatica L.)-baldcy-press (Taxodium distichum (L.) Rich.) swamp in southwestern Alabama was subjected to three types of disturbance, including helicopter logging, rubber-tired skidder logging simulation, and helicopter logging followed by an herbicide application. An adjacent undisturbed stand served as a control area. Post-harvest collection of sedimentation data revealed that the herbaceous and woody vegetation regrowth within the helicopter and skidded clearcut areas trapped more sediments than did the control or herbicide treatment areas. Clearcutting, followed by plant regrowth, improved the wet-land's capacity to remove sediments from overbank flow flood waters.     

The use of Landsat multispectral scanner data for the analysis and management of flooding on the river Severn,England

Remote sensing has emerged as one of the major techniques for the analysis and delineation of large floods. This analysis can provide data invaluable for the hydrological management of large river systems. A need for information on the extent of floodplain inundation for the lower reaches of the largest river in the UK was met by a search through Landsat images of floods and the analysis of the best example recorded. Automated classification of the Landsat imagery of this flood on the river Severn in 1977 was used to provide estimates of the extent and spatial distribution of inundation. Flood images were generated using the Plessey IDP 3000 image processor, and the maps derived accorded well with aerial photography and qualitative flood information. Three distinct floodplain environments were delineated and flood images produced by different spectral bands compared. Specific questions prompted by flood hazard management and concerning the processes and extent of flooding were answered by the Landsat data analysis. Management of the flood risk of large rivers is expensive and remote sensing data is a relatively cheap and effective way of monitoring control works and providing data for the prediction of the effects of future hydrological works. Remote sensing is a practical way in which spatial information concerning the behavior of large dynamic systems can be obtained both quickly and relatively cheaply.     

Community opinion concerning airport noise-abatement alternatives

In the present study we examined (1) community opinion of airport noise-abating alternatives and (2) the influence of perceived control on attitudes concerning noise-abatement policies and annoyance toward aircraft noise. We proposed that residents who perceive themselves as having little control over aircraft noise exposure would express higher levels of annoyance than residents who believe they have some degree of control. Furthermore, residents with low levels of perceived control would be less favorable toward proposed noise-abatement alternatives. Survey results collected from 239 households within the 65 CNEL contour of a community airport in Southern California support these hypotheses. Findings indicate strong public support for noise abatement and strong opposition to land-use alternatives. In addition, residents' perceptions of control in the airport planning and management process are significantly related to their annoyance with noise and their opinions about noise management policies.     

Kinetics and mechanism of oxidation of tetrachloroethylene with permanganate

The kinetics, reaction pathways and product distribution of oxidation of tetrachloroethylene (PCE) by potassium permanganate (KMnO4) were studied in phosphate-buffered solutions under constant pH, isothermal, completely mixed and zero headspace conditions. Experimental results indicate that the reaction is first-order with respect to both PCE and KMnO4 and has an activation energy of 9.3+/-0.9 kcal/mol. The second-order rate constant at 20 degrees C is 0.035+/-0.004 M(-1) s(-1), and is independent of pH and ionic strength (I) over a range of pH 3-10 and I approximately 0-0.2 M, respectively. The PCE-KMnO4 reaction may proceed through further oxidation and/or hydrolysis reaction pathways, greatly influenced by the acidity of the solution, to yield CO2(g), oxalic acid, formic acid and glycolic acid. Under acidic conditions (e.g., pH 3), the further oxidation pathway will dominate and PCE tends to be directly mineralized into CO2 and chloride. Under neutral (e.g., pH 7) and alkaline conditions (e.g., pH 10), the hydroxylation pathway dominates the reaction and PCE is primarily transformed into oxalic acid prior to complete PCE mineralization. Moreover, all chlorine atoms in PCE are rapidly liberated during the reaction and the rate of chloride production is very close to the rate of PCE degradation.     

Renewable Resources and Enzymatic Processes to Create Functional Polymers: Adapting Materials and Reactions from Food Processing

We are exploiting materials and concepts from food science to create functionalized, environmentally friendly derivatives of the biopolymer chitosan, a byproduct of seafood processing. Functional groups are grafted onto chitosan using tyrosinase, the enzyme responsible for food browning. The functionalizing groups studied include low-molecular-weight phenols derived from natural sources and high-molecular-weight proteins. The approach of using low-molecular-weight phenols to functionalize chitosan is illustrated with arbutin, a natural phenol found in pears. Results demonstrate that tyrosinase initiates reactions that lead to the conversion of arbutin–chitosan solutions into gels. These gels can be rapidly broken by treatment with the chitosan-hydrolyzing enzyme chitosanase, demonstrating that the chitosan derivatives remain biodegradable. We briefly review other studies in which low-molecular-weight natural phenols are enzymatically grafted onto chitosan to confer functional properties. The creation of co-polymers is illustrated by results in which tyrosinase is used to couple gelatin onto chitosan. Gelatin is a proteinaceous byproduct of meat production. The tyrosinase-generated gelatin–chitosan conjugates have been observed to offer interesting rheological and thermal properties. These results demonstrate the potential for using renewable resources and enzymatic processing to create environmentally friendly polymers with useful functional properties.     

MAKING SMARTER ENVIRONMENTAL MANAGEMENT DECISIONS1

ABSTRACT: This paper outlines a sound, practical approach for making more informed decisions about environmental policy choices. It emphasizes the importance of using a structured decision process to specify and organize values, use these values to create alternatives, and assess tradeoffs to help achieve a desired balance across key objectives. Although these decision making steps are based on common sense, they are often neglected or poorly carried out as part of the complex evaluations of natural resource options. We discuss several reasons for this frequent neglect of decision making principles and provide examples from recent water use planning projects to demonstrate some of the benefits of using a structured, decision focused approach: new and better solutions, increased and more productive participation by stakeholders, and greater defensibility and acceptance of the resource management evaluation process and its conclusions.     

EFFECTS OF CLIMATE CHANGE ON WATER RESOURCES IN THE DELAWARE RWER BASIN1

ABSTRACT: The effects of potential climate change on water resources in the Delaware River basin were determined. The study focused on two important water-resource components in the basin: (1) storage in the reservoirs that supply New York City, and (2) the position of the salt front in the Delaware River estuary. Current reservoir operating procedures provide for releases from the New York City reservoirs to maintain the position of the salt front in the estuary downstream from freshwater intakes and ground-water recharge zones in the Philadelphia metropolitan area. A hydrologic model of the basin was developed to simulate changes in New York City reservoir storage and the position of the salt front in the Delaware River estuary given changes in temperature and precipitation. Results of simulations indicated that storage depletion in the New York City reservoirs is a more likely effect of changes in temperature and precipitation than is the upstream movement of the salt front in the Delaware River estuary. In contrast, the results indicated that a rise in sea level would have a greater effect on movement of the salt front than on storage in the New York City reservoirs. The model simulations also projected that, by decreasing current mandated reservoir releases, a balance can be reached wherein the negative effects of climate change on storage in the New York City reservoirs and the position of the salt front in the Delaware River estuary are minimized. Finally, the results indicated that natural variability in climate is of such magnitude that its effects on water resources could overwhelm the effects of long-term trends in precipitation and temperature.     

Pollution,place, and premature death: evidence from a mid-sized city

ABSTRACT

Neighborhood life expectancy varies by as much as 10 years across the City of Louisville. In 2013, the Greater Louisville Project funded by local government, businesses, and foundations, argued these differences had little to do with environmental factors. The Greater Louisville Project (2013) study argued that these neighborhood differences could be attributed 40% to socio-economic factors (with a major emphasis on education), 10% to physical environment, 30% to health behaviors, and 20% to access to medical care. To test these claims, we construct our own model of neighborhood variation in years of potential life lost (YPLL) by adding two variables testing environmental degradation. We operationalise two separate measures of environmental contamination: proximity to EPA designated brownfield sites and proximity to chemical factories in an industrial park in the neighborhood known as “Rubbertown”. We conduct several regression analyses, which show a relationship between proximity to environmental contaminants and an increase in neighborhood YPLL. Our beta weights challenge the claims made by the Greater Louisville Project, which minimize the impact nearness to environmental contaminants has on reductions in life expectancy in Louisville neighborhoods.