Tensile Behavior of Thermoplastic Films from Wheat Flours as Function of Raw Material Baking Properties

The production of bioplastics directly from wheat flour has been demonstrated to be reliable, but scarce knowledge is available on how flour characteristics may affect the performance of thermoplastic films. In this work, we first established the most suitable recipe and process for the production of extruded films and then we used eight single-cultivar wheat flours with different baking technological properties to assess how they affect the mechanical properties of thermoplastic films. The results have shown that flours from soft grain cultivars offered more rigid and deformable films than flours from hard grain cultivars. For similar hardness, the alveographic P/L ratio of the dough was inversely related to rigidity and directly related to deformability of plastic films, while the deformation energy of the dough (W) played a role only for great differences of it. The subsequent fabrication of blends between each of the flours that yielded the best film properties and polycaprolactone (PCL) at different proportions indicated that a wheat flour/PCL ratio (TWF/PCL) of 75/25 offered the most suitable films for further application. Our results are likely to be useful for improving the plasticization of flour, in that selection of wheat flours could be tailored on the properties desired for the bioplastic films.     

Hair mercury levels in an urban population from southern Italy: fish consumption as a determinant of exposure

Mercury levels in hair of a general population, 237 adults aged between 35-45, in Naples, Italy, were assessed. The subjects were asked to fill in a questionnaire about age, gender, body weight, height, body mass index (BMI), fish consumption, number, surface and area of dental amalgam fillings. Total mercury (THg) concentrations in human hair ranged from 0.221 to 3.402 microg/g and the mean value for the subjects under study was 0.638 microg/g. Study participants were divided into three groups in accordance with fish consumption and dental amalgam: ANF (amalgam and no fish); NAF (no amalgam but with fish) and AAF (amalgam and fish). Significant differences in THg were found in the three groups (p<0.05). A multiple linear regression analysis showed a weak but significant correlation of THg content in hair with respect to gender and age, but almost no association was found between THg and dental fillings. Conversely, a strong correlation was obtained between THg and fish consumption regardless of the group evaluated. Finally, mercury levels in hair exceeded the levels corresponding to the EPA reference dose (RfD) of 0.1 microg Hg/kg body weight per day (1 microg Hg/g hair) in 6% of the population (4% men and 2% women). However, the THg limits in our subjects were not exceeded according to the WHO guidelines, which use a benchmark dose of 0.23 microg Hg/kg bw/day (14 microg Hg/g maternal hair).     

A correlation study between multiple sclerosis and type 1 diabetes incidences and geochemical data in Europe

Complex multifactorial disorders usually arise in individuals genetically at risk in the presence of permissive environmental factors. For many of these diseases, predisposing gene variants are partly known while the identification of the environmental component is much more difficult. This study aims to investigate whether there are correlations between the incidence of two complex traits, multiple sclerosis and type 1 diabetes, and some chemical elements and compounds present in soils and stream sediments in Europe. Data were obtained from the published literature and analyzed by calculating the mean values of each element and of disease incidence for each Country, respectively, 17 for multiple sclerosis and 21 for type 1 diabetes. Correlation matrices and regression analyses were used in order to compare incidence data and geochemical data. R correlation index and significance were evaluated. The analyses performed in this study have revealed significant positive correlations between barium and sodium oxide on one hand and multiple sclerosis and diabetes incidences on the other hand that may suggest interactions to be evaluated between silicon-rich lithologies and/or marine environments. The negative correlations shown by cobalt, chromium and nickel (typical of silicon-poor environment), which in this case can be interpreted as protective effects against the two diseases onset, make the split between favorable and protective environments even more obvious. In conclusion, if other studies will confirm the involvement of the above elements and compounds in the etiology of these pathologies, then it will be possible to plan strategies to reduce the spread of these serious pandemics.     

The modelling of pool vaporization

This paper describes a mathematical model which calculates the time dependencies of the flow rate and composition of the vapour emerging from a pool. A large variety of accidental cases can be covered: continuous or instantaneous spills, on confined or unconfined ground, ideal or non-ideal liquid mixtures in boiling or evaporating conditions. The boiling, when present, is modelled through an equation system comprising the Rachford-Rice relation and the energy balance of the pool, which is assumed to be well-mixed. In the case of a volatile pool, interfacial mass rates are determined taking into account the Stefan flux, and the thermal resistance inside the liquid phase is also considered. In all situations, the energy balance includes the contribution of ground, sun and air. Known experimental data have been used to validate the model.     

Soil erosion tolerance and water runoff control: minimum environmental standards

Council Regulations (EC) No 1257/1999 and the EU Soil Thematic Strategy give great importance to soil and land conservation to develop knowledge driven governance for rural development. In the hilly areas of Italy cultivated intensively, and especially in the ones devoted to viticulture, agricultural practices determine high loss of soil with consequent degradation of the soil resource. In addition to it, offsite effects of soil erosion can be unsustainable, due to sediment transfer to the channel network and infrastructures. In order to achieve a sustainable rural development there is a need for tools and instruments to allow European regional administrations, to develop, implement, manage and monitor rural development plans. To counteract the environmental threats intensified by agricultural activity, the environmental functions “soil erosion control” and “water runoff control” were investigated in the Chianti area by using GIS. To determine the EMR (Environmental Minimum Requirements) values for soil erosion the “regeneration” capability of soils was considered, and the value of estimated soil loss was compared with the value of soil reformation. A scenario analysis was also performed to evaluate the effectiveness of the agroenvironmental measure “grass cover” in reducing erosion. The concept of tolerable erosion based on soil productivity and soil reformation rate only is reductive and off-site effects of soil erosion should be also taken into account. For this reason, it was proposed to extend the concept of hydrogeological risk to soil erosion by implementing the notion of soil erosion tolerance (T) with the new concept of environmental risk of soil erosion (ERSE). The new ERSE index takes into account all the in- and off-farm externalities of soil erosion. For this reason, it can be considered an aggregated environmental indicator that enables policy makers to evaluate the impacts of soil erosion by following an holistic approach.     

Inertization of hazardous dredging spoils

Vitrification and production of ceramics materials starting from sediment excavated from Venice lagoon is described. This sediment is classified as toxic waste because contains several heavy metal ions and organic pollutants and was successfully vitrified at 1200-1350 degrees C. Twenty weight percentage of glass cullet, coming from a community glass recycling program, was added to the raw materials, previously calcined at 900 degrees C, as a way of adjusting the variations of composition of the individual sediment batches. Chemical durability (leaching) tests showed that the optimized glass compositions are inert, and thus not only volume reduction but also inertization of the waste was obtained by this process. Moreover, the economics of the entire process was analysed. The valorization of the waste was accomplished by the subsequent processing of the glass derived from the inertization. Glass ceramic materials were produced by viscous phase sintering of pressed glass powders which crystallized during the densification process. Sintered glass ceramic products had good mechanical characteristics (HV = 7.5 GPa, bending strength 150 +/- 8 MPa), making them suitable for applications in the building industry.     

Solid waste management in urban areas: Development and application of a decision support system

A decision support system (DSS) developed to assist the planner in decisions concerning the overall management of solid waste at a municipal scale is described. The DSS allows to plan the optimal number of landfills and treatment plants, and to determine the optimal quantities and the characteristics of the refuse that has to be sent to treatment plants, to landfills and to recycling. The application of the DSS is based on the solution of a constrained non-linear optimization problem. Various classes of constraints have been introduced in the problem formulation, taking into account the regulations about the minimum requirements for recycling, incineration process requirements, sanitary landfill conservation, and mass balance. The cost function to be minimized includes recycling, transportation and maintenance costs. The DSS has been tested on the municipality of Genova, Italy, and the results obtained are presented.     

Tributyltin chloride disrupts aortic vascular reactivity and increases reactive oxygen species production in female rats

Environmental Science and Pollution Research - Organotin compounds, such as tributyltin (TBT), are environment contaminants that induce bioaccumulation and have potential toxic effects on marine...