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41.
Sung Ho Hwang Ik Mo Lee Yun Keun Lee Jeong Im Park Kwang Won Rhie Dong Uk Park Chung Sik Yoon 《Environmental monitoring and assessment》2013,185(11):8803-8808
We characterize the monthly variation in (1 → 3)-β-d-glucan concentration measured over the course of 1 year, and we evaluate the characteristics of size selection using a two-stage cyclone sampler. The (1 → 3)-β-d-glucan concentrations were measured in four bio-related laboratories. A total of 156 samples were collected using a new two-stage cyclone sampler. Analysis of (1 → 3)-β-d-glucan was performed using the kinetic Limulus amebocyte lysate assay. The study showed that airborne (1 → 3)-β-d-glucan concentrations were significantly higher in laboratory D (mean ± SD 1,105?±?1,893 pg/m3) and in the spring (5,458 pg/m3). The highest concentration of (1 → 3)-β-d-glucan occurred in the spring, particularly in May. 相似文献
42.
43.
Characteristics of aerosol types during large-scale transport of air pollution over the Yellow Sea region and at Cheongwon,Korea, in 2008 总被引:1,自引:0,他引:1
Episodes of large-scale transport of airborne dust and anthropogenic pollutant particles from different sources in the East
Asian continent in 2008 were identified by National Oceanic and Atmospheric Administration satellite RGB (red, green, and
blue)-composite images and the mass concentrations of ground level particulate matter. These particles were divided into dust,
sea salt, smoke plume, and sulfate by an aerosol classification algorithm. To analyze the aerosol size distribution during
large-scale transport of atmospheric aerosols, aerosol optical depth (AOD) and fine aerosol weighting (FW) of moderate imaging
spectroradiometer aerosol products were used over the East Asian region. Six episodes of massive airborne dust particles,
originating from sandstorms in northern China, Mongolia, and the Loess Plateau of China, were observed at Cheongwon. Classified
dust aerosol types were distributed on a large-scale over the Yellow Sea region. The average PM10 and PM2.5 ratio to the total
mass concentration TSP were 70% and 15%, respectively. However, the mass concentration of PM2.5 among TSP increased to as
high as 23% in an episode where dust traveled in by way of an industrial area in eastern China. In the other five episodes
of anthropogenic pollutant particles that flowed into the Korean Peninsula from eastern China, the anthropogenic pollutant
particles were largely detected in the form of smoke over the Yellow Sea region. The average PM10 and PM2.5 ratios to TSP
were 82% and 65%, respectively. The ratio of PM2.5 mass concentrations among TSP varied significantly depending on the origin
and pathway of the airborne dust particles. The average AOD for the large-scale transport of anthropogenic pollutant particles
in the East Asian region was measured to be 0.42 ± 0.17, which is higher in terms of the rate against atmospheric aerosols
as compared with the AOD (0.36 ± 0.13) for airborne dust particles with sandstorms. In particular, the region ranging from
eastern China, the Yellow Sea, and the Korean Peninsula to the Korea East Sea was characterized by high AOD distributions.
In the episode of anthropogenic polluted aerosols, FW averaged 0.63 ± 0.16, a value higher than that in the episode of airborne
dust particles (0.52 ± 0.13) with sandstorms, showing that fine anthropogenic pollutant particles contribute greatly to atmospheric
aerosols in East Asia. 相似文献
44.
In this study, the characteristics of total water-soluble organic carbon (WSOC) and isolated WSOC fractions were examined to gain a better understanding of the pathway of organic aerosol production. 24 h PM(2.5) samples were collected during the summer (July 28-August 28, 2009) at an urban site in Korea. A glass column filled with XAD7HP resin was used to separate the filtered extracts into hydrophilic (WSOC(HPI)) and hydrophobic (WSOC(HPO)) fractions. The origins of air mass pathways arriving at the sampling site were mostly classified into three types, those originating over the East Sea of Korea that passed over the eastern inland urban and industrial regions (type I); those from the marine (western/southwestern/southern marine) and passed over the national industrial complex regions (type II); and those from northeastern China that passed through North Korea and metropolitan areas of South Korea (type III). Measurements showed an increase in the average WSOC fraction of total OC from the type II to III air mass (53 to 64%) periods. Also, higher SO(4)(2-)/SO(x) (=SO(2) + SO(4)(2-)) was observed in the type III air mass (0.70) than those in the types I (0.49) and II (0.43). According to the average values of WSOC/OC and SO(4)(2-)/SO(x), measurements suggest that the aerosols collected during the type III air mass period were more aged or photo-chemically processed than those during the types I and II air mass periods. The relationship between the SO(4)(2-)/SO(x) and WSOC/OC (R(2) = 0.64) suggests that a significant fraction of the observed WSOC at the site could be formed by an oxidation process similar to SO(4)(2-) aerosols, probably the oxidation process using OH radicals, or in-cloud processing. The photochemical production of WSOC(HPO) was also observed to significantly contribute to the total OC. 相似文献
45.
The present study evaluates the toxicity of 34 propargylic alcohols, including primary, primary homo-, secondary, and tertiary alcohols, based on their effects on phytoplankton. A closed-system algal toxicity test was applied because the closed-system technique presents more realistic concentration-response relationships for the above compounds than the conventional batch tests. The green alga, Pseudokirchneriella subcapitata, was the test organism and final yield and growth rate were chosen as the test endpoints. Among all the propargylic alcohols tested, 1-pentyn-3-ol is the most toxic compound with its EC50 equal to 0.50 mg L(-1), which can be classified as a "R50" compound (very toxic to aquatic organisms, EC50/LC50 < 1 mg L(-1)), following the current practice for classification of chemicals in the European Union (EU). There are several other compounds including 2-decyn-1-ol, 3-decyn-1-ol, 1-hexyn-3-ol, 3-butyn-2-ol, and 3-hexyne-2,5-diol, which deserve more attention for their possible adverse impact on the aquatic environment, because these alcohols can be classified as "R51" compounds (toxic to aquatic organisms, EC50/LC50 between 1 and 10 mg L(-1)). Compared to the base-line toxicity relationship (narcosis QSAR) derived previously, tertiary propargylic alcohols can be identified as nonpolar narcotic chemicals, while secondary alcohols and primary alcohols with low molecular weight generally exhibit obvious excess toxicity in relation to the base-line toxicity. Finally, quantitative structure-activity relationships were established for deriving a preliminary estimation of the toxicity of other propargylic alcohols. 相似文献
46.
Sumin Lee Min-Gu Lee Jinwon Park 《Journal of Material Cycles and Waste Management》2018,20(3):1553-1561
The catalytic upgrading pyrolysis of pine sawdust was performed at 500 °C with various metal oxides to improve the quality of the bio-oil. The aim of this study was to investigate the potential of the metal oxides instead of traditional zeolites for catalytic upgrading pyrolysis with the analysis of Gas Chromatograph/Mass Spectrometer. In this study, the used catalysts were Calcium-oxide, Magnesium oxide, Titanium dioxide, and Zeolite (Si/Al?=?80). The influence of catalysts on products yields and compositions were investigated. Most metal oxides can enhance the bio-gas with the bio-oil yields decreased. The metal oxides led to a decrease of Acids, Aldehydes, Ketones and an increase of Furfural, Cresols, Catechols in Furans and Phenolics. Among the catalysts, the MgO catalysts was the most effective to convert the high molecular into lights ones (6.65% Cresols) with yield of 20.48% for Furfural. The deoxygenation reaction in bio-oil was suggested to convert oxygenated compounds into the low molecular weight of the materials (6.39% Guaiacols). Thus, the used metal oxides can improve the quality of bio-oil by decreasing undesirable compounds as well as increasing the desirable compounds with low oxygen contents via deoxygenation reaction. 相似文献
47.
Chung Duc Tran Stefan Petrus Salhofer 《Journal of Material Cycles and Waste Management》2018,20(1):110-126
E-waste management in Vietnam poses real challenges such as the lack of specific e-waste legislation, the strong involvement of “craft villages” and the missing of monitoring data. Many issues (e.g., pollution level, generated waste, health of workers and resident living at recycling sites) lead to the limited access to these craft villages. Thus, there is no comprehensive picture on e-waste management in Vietnam available today. This research focuses on the current situation of e-waste management. Sources of e-waste, collection and treatment in Vietnam are investigated by utilizing most available sources of information (published journals, unpublished works from projects and reports from institutes, ministry) together with the interviewed data from experts, collectors, workers and especially, biggest traders in the field. Based on this information, the processes applied in Vietnam, both in the formal and informal sector, have been analyzed systematically in terms of inputs, outputs, potential emissions and related risks for workers. From these aspects, a comparison in terms of legal frameworks, collection and treatment at both formal and informal sector between Vietnam and other countries in Asian region was undertaken. Thus, major challenges of e-waste management and relatively comprehensive image of e-waste management and treatment in Vietnam have been identified. 相似文献
48.
Dongwoo Kang Min-Gu Lee Yunsung Yoo Jinwon Park 《Journal of Material Cycles and Waste Management》2018,20(3):1562-1573
In this research, absorbents for CO2 capture were prepared by blending 30 wt% potassium carbonate, 3 wt% of a rate promoter, and 1 wt% of a corrosion inhibitor. Pipecolic acid, sarcosine, and diethanolamine were chosen as rate promoter candidates. Based on a rate promoter screening test for CO2 loading capacity and absorption rate, pipecolic acid and sarcosine were selected to be used as rate promoters. 1,2,3-benzotriazole and ammonium thiocyanate were chosen as corrosion inhibitors, and they were mixed with a 30 wt% potassium carbonate-based absorbent mixture containing one of the rate promoters. The absorption rates for four absorbent solutions (30 wt% potassium carbonate?+?3 wt% pipecolic acid?+?1 wt% 1,2,3-benzotriazole, 30 wt% potassium carbonate?+?3 wt% pipecolic acid?+?1 wt% ammonium thiocyanate, 30 wt% potassium carbonate?+?3 wt% sarcosine?+?1 wt% 1,2,3-benzotriazole, and 30 wt% potassium carbonate?+?3 wt% sarcosine?+?1 wt% ammonium thiocyanate) were measured, tabulated, and graphically displayed. These types of absorbents can be used for capturing CO2 under high temperature and pressure conditions, such as those found in coal-fired power plants. 相似文献
49.
Se-Won Park Jang-Soo Lee Won-Seok Yang Md Tanvir Alam Yong-Chil Seo Sang-Yeop Lee 《Journal of Material Cycles and Waste Management》2018,20(2):823-831
Gasification experiments for sawdust were conducted using a fixed bed reactor at 900 °C by varying the secondary oxidant injection ratio to determine the optimal conditions for tar removal along with the enhancement of gasification efficiency. Secondary oxidant was injected as an oxidant at the top zone of the gasifier in varying ratios of 10–30% of the total amount of oxidant. This method was based on the primary method of tar removal and gasification efficiency improvement by thermal cracking of tar. Various gasification performance parameters were evaluated and tar content was estimated by measuring the fluctuation of weight of the activated carbon filter. The results showed that the concentration of tar in the producer gas decreased by injecting the secondary oxidant, even though syngas yield decreased. The recycling potential of the char produced in the gasification experiments was also assessed with the purpose of utilizing char as an adsorbent by determining its surface area and pore volume. The results demonstrated that the char produced from the gasification experiment had similar quality to that of the activated carbon used in this experiment. 相似文献
50.
Sangbok Lee Myoung Hwan Park 《International journal of occupational safety and ergonomics》2018,24(2):165-170
This study investigates differences between male and female public office workers’ satisfaction levels, sick building syndrome (SBS) symptoms and musculoskeletal disorder (MSD) complaints in workplace and office environments. Questionnaire surveys were performed in 30 offices from 15 public institutions. Male and female workers of the same age were coupled and selected from each office, gathering a total of 120 male and 120 female subjects. The results show that differences exist between genders in noise and lighting satisfaction levels, SBS-related symptoms (eye, nose, skin) and MSD complaints of hand/wrist/finger, while there is no difference in overall satisfaction level of office environments. The study also suggests that office design for public office workers should take into account gender differences in preventing MSDs and also SBS. The findings of this study are expected to serve as basic data for designing effective public office environments. 相似文献