Traffic aerosol lobar doses deposited in the human respiratory system

Aerosol pollution in urban environments has been recognized to be responsible for important pathologies of the cardiovascular and respiratory systems. In this perspective, great attention has been addressed to Ultra Fine Particles (UFPs?<?100 nm), because they efficiently penetrate into the respiratory system and are capable of translocating from the airways into the blood circulation. This paper describes the aerosol regional doses deposited in the human respiratory system in a high-traffic urban area. The aerosol measurements were carried out on a curbside in downtown Rome, on a street characterized by a high density of autovehicular traffic. Aerosol number-size distributions were measured by means of a Fast Mobility Particle Sizer in the range from 5.6 to 560 nm with a 1 s time resolution. Dosimetry estimates were performed with the Multiple-Path Particle Dosimetry model by means of the stochastic lung model. The exposure scenario close to traffic is represented by a sequence of short-term peak exposures: about 6.6?×?10¹⁰ particles are deposited hourly into the respiratory system. After 1 h of exposure in proximity of traffic, 1.29?×?10¹⁰, 1.88?×?10¹⁰, and 3.45?×?10¹⁰ particles are deposited in the head, tracheobronchial, and alveolar regions. More than 95 % of such doses are represented by UFPs. Finally, according to the greater dose estimated, the right lung lobes are expected to be more susceptible to respiratory pathologies than the left lobes.     

Automatic classification of climate change effects on marine species distributions in 2050 using the AquaMaps model

Environmental and Ecological Statistics - Habitat modifications driven by human impact and climate change may influence species distribution, particularly in aquatic environments. Niche-based...     

Comparison between remote-sensed data and in situ measurements in coastal waters: The taranto sea case

Monitoring and managing small coastal ecosystems requires a considerable understanding of the temporal dynamics of biophysical factors describing the coastal water systems. For this reason, daily observation from space could be a very efficient tool. The objective of the work described in this paper is to evaluate the contribution of remote sensing to the continuous monitoring of coastal areas. It is well known that in coastal areas, the presence of inorganic suspended sediments and coloured dissolved organic matter can make chlorophyll-concentration measurements from remote sensing difficult. To overcome these difficulties, an alternative approach to the SeaWiFS standard chlorophyll algorithm is presented, based on a semi-analytic model for sea water and on the use of MODIS data as input in a model for atmospheric effects removal. Moreover, land contamination (mixed sea–land pixels) can introduce ambiguities in sea-surface temperature measurements from remote sensing. This paper proposes the use of a hydrodynamic model as a time–space interpolator of in situ campaign data, to extensively validate the temperature values extracted from AVHRR sensor. We validated the proposed approach, using experimental field data collected over a two-year campaign in the Taranto Gulf. The results seem to indicate a good agreement between remote-sensed and in situ data.     

Effect of Cd++ on germination,growth and active principles of Datura metel L.∗

The effects of Cd⁺⁺ concentration increment in soil and/or in atmosphere, on germination, growth and alkaloid contents of Datura metel L. were investigated. We observed a significant reduction of growth following addition of Cd⁺⁺ in soil. Minor effects on growth were evident when the plants were sprayed with CdCl₂ solution (10mgCd⁺⁺/l).

Scanning electron microscope observation showed stomata widely open and conspicuous cuticular striations in the foliar epidermis of polluted plants.

GLC analysis of extracts evidenced a significant variation in active principle content among plants undergoing different treatments.     

Simulating nitrogen dynamics in agricultural soils fertilized with pig slurry and urea

Within the framework of an interregional project in the Emilia Romagna region of northern Italy, the coupled MACRO-SOILN model was chosen to estimate soil protective capacity against pollutants. The aim of our study was to evaluate the model to better identify key parameters and processes that influence N losses in agricultural soils. Nitrate N content was monitored in soil under corn (Zea mays L.) fertilized with urea and/or pig slurry, in two field experiments performed on four different soils: a Fienili clay, a Barco-like silt, a Sant'Omobono silt loam, and a La Boaria silty clay soil. Measurements were compared with model predictions. For all soils, nitrate content was underestimated on average by 24 to 88% at lower N rates; it was overestimated by 1 to 104% at higher N rates. The root mean square error (RMSE) was equal to 81.1%. Simulation of crop N uptake and soil water flow, estimation of the ammonia losses at pig slurry spreading, and N transformation parameter setting were considered as possible error sources. The calibration of crop N uptake gave rise to good model efficiency index values. The RMSE for the simulation of soil water content varied between 9.8 and 20.2%. A more accurate setting of the ammonia losses and of the feces transformation parameter values could allow the RMSE for the simulation of soil nitrate content to be reduced by no more than 10 to 15%. It is possible for the model not to include the simulation of processes that could have relevant effects on the soil N dynamics.     

Gas- and particle-phase distribution of polycyclic aromatic hydrocarbons in two-stroke, 50-cm3 moped emissions

Gas- and particle-phase polycyclic aromatic hydrocarbons (PAHs) concentrations evaluated in the exhaust of 10 two-stroke, 50-cm³ mopeds belonging to three different levels of emission legislation (EURO-0, EURO-1 and EURO-2) were used to assess the prevalent mechanism driving the gas/particle partitioning of PAHs in moped exhaust. Sampling was performed on a dynamometer bench both during the “cold-start” and the “hot” phases of the ECE-47 driving cycle. Gas and particulate phase PAHs were collected on polyurethane foam (PUF) plugs and 47-mm Pallflex T60A20 filters, respectively, under isokinetic conditions by using sampling probes inserted into the dilution tunnel of a Constant Volume Sampling – Critical Flow Venturi (CVS–CFV) system.The results show that semi-volatile PAHs were predominantly partitioned to the particle phase. The soluble organic fraction (SOF) of the collected particulates ranged between 72 and 98%. Measured total suspended particulate matter normalized partition coefficients (K_p) were predicted within a factor of 3–5 by assuming absorption into the organic fraction according to a model developed by Harner and Bidleman [Harner, T., Bidleman, T.F., 1998. Octanol–air partition coefficient for describing particle/gas partitioning of aromatic compounds in urban air. Environmental Science & Technology 32, 1494–1502.]. This suggests that the gas/particle partitioning in moped exhaust is mainly driven by the high fraction of organic matter of the emitted particles and that absorption could be the main partitioning mechanism of PAHs.     

Evaluating Tourist Perception of Environmental Changes as a Contribution to Managing Natural Resources in Glacierized Areas: A Case Study of the Forni Glacier (Stelvio National Park, Italian Alps)

Climate change effects are noticeably evident above the timberline where glacier and permafrost processes and mass movements drive the surface evolution. In particular, the cryosphere shrinkage is deeply changing the features and characteristics of several glacierized mountain areas of the world, and these modifications can also affect the landscape perception of tourists and mountaineers. On the one hand glacier retreat is increasing the interest of tourists and visitors in areas witnessing clear climate change impacts; on the other hand cryosphere shrinkage can impact the touristic appeal of mountain territories which, diminishing their ice and snow coverage, are also losing part of their aesthetic value. Then, to promote glacierized areas in a changing climate and to prepare exhaustive and actual proposals for sustainable tourism, it is important to deepen our knowledge about landscape perception of tourists and mountaineers and their awareness of the ongoing environmental modifications. Here we present the results from a pilot study we performed in summer 2009 on a representative glacierized area of the Alps, the Forni Valley (Stelvio National Park, Lombardy, Italy), a valley shaped by Forni, the largest Italian valley glacier. During the 2009 summer season we asked tourists visiting the Forni Valley to complete a questionnaire. This study was aimed at both describing the features and characteristics of tourists and mountaineers visiting this Alpine zone in summer and evaluating their landscape perception and their ability to recognize climate change impacts and evidence. Our results suggest that the dissemination strategies in a natural protected area have to take into account not only the main landscape features but also the sites where the information will be given. In particular considering the peculiarities of the huts located in the area, such as their different accessibility and the fact that they are included or not in a mountaineering network like that of the Italian Alpine Club. Both these factors can influence the kind of visitors to the area, thus requiring different dissemination strategies. Moreover, differences in the viewpoints from where visitors could watch and understand landscape also have to be considered. Next, in a protected area where climate change effects are evident, the dissemination strategies should be developed in close cooperation with scientists who are analyzing the area and with the support of periodic interviews which could be very useful to evaluate the effectiveness of the applied dissemination methods. Last but not least, the questionnaire should be standardized and distributed in several protected areas, thus permitting useful comparisons and the identification of common solutions for sharing in a friendly way scientific knowledge about climate change and its effects on the environment and the landscape.