全文获取类型
收费全文 | 12022篇 |
免费 | 74篇 |
国内免费 | 24篇 |
专业分类
安全科学 | 181篇 |
废物处理 | 910篇 |
环保管理 | 1718篇 |
综合类 | 1217篇 |
基础理论 | 3630篇 |
环境理论 | 3篇 |
污染及防治 | 2279篇 |
评价与监测 | 1171篇 |
社会与环境 | 976篇 |
灾害及防治 | 35篇 |
出版年
2023年 | 11篇 |
2022年 | 19篇 |
2021年 | 27篇 |
2020年 | 26篇 |
2019年 | 27篇 |
2018年 | 1514篇 |
2017年 | 1416篇 |
2016年 | 1250篇 |
2015年 | 190篇 |
2014年 | 83篇 |
2013年 | 237篇 |
2012年 | 560篇 |
2011年 | 1465篇 |
2010年 | 791篇 |
2009年 | 715篇 |
2008年 | 987篇 |
2007年 | 1341篇 |
2006年 | 134篇 |
2005年 | 115篇 |
2004年 | 116篇 |
2003年 | 168篇 |
2002年 | 167篇 |
2001年 | 68篇 |
2000年 | 63篇 |
1999年 | 43篇 |
1998年 | 48篇 |
1997年 | 34篇 |
1996年 | 33篇 |
1995年 | 26篇 |
1994年 | 34篇 |
1993年 | 31篇 |
1992年 | 21篇 |
1991年 | 24篇 |
1990年 | 13篇 |
1989年 | 11篇 |
1988年 | 16篇 |
1987年 | 19篇 |
1986年 | 13篇 |
1985年 | 19篇 |
1984年 | 23篇 |
1983年 | 26篇 |
1982年 | 19篇 |
1981年 | 24篇 |
1980年 | 13篇 |
1979年 | 10篇 |
1978年 | 6篇 |
1977年 | 9篇 |
1971年 | 6篇 |
1957年 | 5篇 |
1955年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 781 毫秒
791.
Purpose
The most significant application of polychlorinated biphenyls (PCBs) is in transformers and capacitors. Therefore, power plants are important suspected sources for entry of PCBs into the environment. In this context, the levels and distribution of PCBs in sediment, soil, ash, and sludge samples were investigated around Seyitömer thermal power plant, Kütahya, Turkey. Moreover, identity and contribution of PCB mixtures were predicted using the chemical mass balance (CMB) receptor model.Methods
United States Environmental Protection Agency methods were applied during sample preparation, extraction (3540C), cleanup (3660B, 3665A, 3630C), and analysis (8082A).Results
ΣPCB concentrations in the region ranged from not detected to 385 ng/g dry weight, with relatively higher contamination in sediments in comparison to soil, sludge, and ash samples collected from around the power plant. Congener profiles of the sediment and soil samples show penta-, hexa-, and hepta-chlorobiphenyls as the major homolog groups. The results from the CMB model indicate that PCB contamination is largely due to Clophen A60/A40 and Aroclor 1254/1254(late)/1260 release into the sediment and sludge samples around the thermal power plant.Conclusions
Since there are no other sources of PCBs in the region and the identity of PCB sources estimated by the CMB model mirrors PCB mixtures contained in transformers formerly used in the plant, the environmental contamination observed especially in sediments is attributed to the power plant. Release of PCBs over time, as indicated by the significant concentrations observed even in surface samples, emphasizes the importance of the need for better environmental management.792.
Trier X Granby K Christensen JH 《Environmental science and pollution research international》2011,18(7):1108-1120
Introduction
In this study, we explore the identity of a range of polyfluorinated surfactants (PFS) used for food contact materials, primarily to impart oil and water repellency on paper and board. PFS are of interest, as they can be precursors of poly- and perfluorinated alkyl substances (PFAS), of which several are persistent and are found worldwide in human blood and in the environment. 相似文献793.
Burskyte V Belous O Stasiskiene Z 《Environmental science and pollution research international》2011,18(5):716-726
Introduction
In 2003, the Japan International Cooperation Agency carried out a development feasibility study of Klaipeda Seaport (Lithuania). The focus in this study was the evaluation of environmental impacts of the port expansion because it is located in an ecologically sensitive area. While the Japanese researchers focused on the environmental impact analysis, they did not provide unambiguous conclusions. The problems remained unresolved and required further, more detailed consideration and deeper analysis. 相似文献794.
Stefanie Grund Eric Higley René Schönenberger Marc J-F. Suter John P. Giesy Markus Hecker Henner Hollert 《Environmental science and pollution research international》2011,18(3):446-460
Introduction
The present study was part of a comprehensive weight-of-evidence approach with the goal of identifying potential causes for the declines in fish populations, which have been observed during the past decades in the Upper Danube River. 相似文献795.
Background, aim, and scope
Ever since the discovery of the mutagenic properties of ionizing radiation, the possibility of birth sex odds shifts in exposed human populations was considered in the scientific community. Positive evidence, however weak, was obtained after the atomic bombing of Japan. We previously investigated trends in the sex odds before and after the Chernobyl Nuclear Power Plant accident. In a pilot study, combined data from the Czech Republic, Denmark, Finland, Germany, Hungary, Norway, Poland, and Sweden between 1982 and 1992 showed a downward trend in the sex odds and a significant jump in 1987, the year immediately after Chernobyl. Moreover, a significant positive association of the sex odds between 1986 and 1991 with Chernobyl fallout at the district level in Germany was observed. Both of these findings, temporality (effect after exposure) and dose response association, yield evidence of causality. The primary aim of this study was to investigate longer time periods (1950–2007) in all of Europe and in the USA with emphasis on the global atmospheric atomic bomb test fallout and on the Chernobyl accident. To obtain further evidence, we also analyze sex odds data near nuclear facilities in Germany and Switzerland. 相似文献796.
Mohanraj R Solaraj G Dhanakumar S 《Environmental science and pollution research international》2011,18(5):764-771
Background
Airborne fine particulates (PM 2.5) and its associated polycyclic aromatic hydrocarbons (PAHs) are reportedly hazardous in urban environment due to the presence of multiple emission sources. 相似文献797.
Ben-Shlomo R Shanas U 《Environmental science and pollution research international》2011,18(8):1264-1269
Purpose
We tested the genetic diversity in wild mice (Mus musculus domesticus) inhabiting the asbestos-polluted area as a model for the long-term mutagenic effect of asbestos. Hazardous effects of deposited asbestos persist in the environment because of low rate of fiber disintegration. The upper layers of the soil in the vicinity of a former asbestos factory are nearly “saturated” with asbestos fibers and dust. Natural populations of mice dwell in this area and are constantly exposed to asbestos fibers. 相似文献798.
Occurrence of perfluorinated organic acids in the North and Baltic seas. Part 1: distribution in sea water 总被引:1,自引:0,他引:1
Theobald N Caliebe C Gerwinski W Hühnerfuss H Lepom P 《Environmental science and pollution research international》2011,18(7):1057-1069
Purpose
Due to their high water solubilities and mobilities, persistent, polar perfluorinated compounds (PFCs) such as perfluorinated carboxylates and sulfonates are likely to end up in the oceans. In part 1 of this study, their distribution in North and Baltic Sea water is reported, being of special interest because these seas are surrounded by highly industrialized countries with high population densities. 相似文献799.
Chan WH Mak YL Wu JJ Jin L Sit WH Lam JC Sadovy de Mitcheson Y Chan LL Lam PK Murphy MB 《Chemosphere》2011,84(1):117-123
Ciguatera is food poisoning caused by human consumption of reef fish contaminated with ciguatoxins (CTXs). The expanding international trade of tropical fish species from ciguatera-endemic regions has resulted in increased global incidence of ciguatera, and more than 50 000 people are estimated to suffer from ciguatera each year worldwide. The Republic of Kiribati is located in the Pacific Ocean; two of its islands, Marakei and Tarawa, have been suggested as high-risk areas for ciguatera. The toxicities of coral reef fish collected from these islands, including herbivorous, omnivorous and carnivorous fish (24% [n = 41], 8% [n = 13] and 68% [n = 117], respectively), were analyzed using the mouse neuroblastoma assay (MNA) after CTX extraction. The MNA results indicated that 156 fish specimens, or 91% of the fish samples, were ciguatoxic (CTX levels >0.01 ng g−1). Groupers and moray eels were generally more toxic by an order of magnitude than other fish species. All of the collected individuals of eight species (n = 3-19) were toxic. Toxicity varied within species and among locations by up to 10 000-fold. Cephalapholis argus and Gymnothorax spp. collected from Tarawa Island were significantly less toxic than those from Marakei Island, although all individuals were toxic based on the 0.01 ng g−1 threshold. CTX concentrations in the livers of individuals of two moray eel species (Gymnothorax spp., n = 6) were nine times greater than those in muscle, and toxicity in liver and muscle showed a strong positive correlation with body weight. The present study provides quantitative information on the ciguatoxicity and distribution of toxicity in fish for use in fisheries management and public health. 相似文献
800.
This study presents the first systematic information on the degradation patterns of clandestine drug laboratory chemicals in soil. The persistence of five compounds - parent drugs (methamphetamine, 3,4-methylenedioxymethamphetamine (MDMA)), precursor (pseudoephedrine), and synthetic by-products N-formylmethylamphetamine and 1-benzyl-3-methylnaphthalene) - were investigated in laboratory scale for 1 year in three different South Australian soils both under non-sterile and sterile conditions. The results of the degradation study indicated that 1-benzyl-3-methylnaphthalene and methamphetamine persist for a long time in soil compared to MDMA and pseudoephedrine; N-formylmethylamphetamine exhibits intermediate persistence. The role of biotic versus abiotic soil processes on the degradation of target compounds was also varied significantly for different soils as well as with the progress in incubation period. The degradation of methamphetamine and 1-benzyl-3-methylnaphthalene can be considered as predominantly biotic as no measureable changes in concentrations were recorded in the sterile soils within a 1 year period. The results of the present work will help forensic and environmental scientists to precisely determine the environmental impact of chemicals associated with clandestine drug manufacturing laboratories. 相似文献